Mussels document loss of bioavailable polycyclic aromatic hydrocarbons and the return to baseline conditions for oiled shorelines in Prince William Sound, Alaska

Polycyclic aromatic hydrocarbons (PAH) were measured in mussels (Mytilus trossulus) collected between 1990 and 2002 from 11 sites on the shores of Prince William Sound (PWS), Alaska, that were heavily oiled by the 1989 Exxon Valdez oil spill (EVOS). This study, utilizing the methods of the NOAA Status and Trends Mussel Watch Program, found that concentrations of PAH released from spill remnants have decreased dramatically with time and by 2002 were at or near the range of total PAH (TPAH) of 3-355 ng/g dry weight obtained for mussels from unoiled reference sites in PWS. Time-series TPAH data indicate a mean TPAH half-life in mussel tissues of 2.4 years with a range from 1.4 to 5.3, yielding an annual mean loss of bioaccumulated TPAH of 25%. The petroleum-derived TPAH fraction in mussel tissues has decreased with time, reflecting the decreasing release of EVOS residues in shoreline sediments. These results show that PAH from EVOS residues that remain buried in shoreline sediments after the early 1990s are in a form and at locations that have a low accessibility to mussels living in the intertidal zone.     

Spinel assemblages in lunar meteorites Graves Nunataks 06157 and Dhofar 1528: Implications for impact melting and equilibration in the Moon's upper mantle

Magnesium‐rich spinel assemblages occur in the two lunar vitric breccia meteorites—Dhofar (Dho) 1528 and Graves Nunataks (GRA) 06157. Dho 1528 contains up to ~0.7 mm cumulate Mg‐rich spinel crystals associated with Mg‐rich olivine, Mg‐ and Al‐rich pyroxene, plagioclase, and rare cordierite. Using thermodynamic calculations of these mineral assemblages, we constrain equilibration depths and discuss an origin of these lithologies in the upper mantle of the Moon. In contrast, small, 10 to 20 μm spinel phenocryst assemblages in glassy melt rock clasts in Dho 1528 and GRA 06157 formed from the impact melting of Mg‐rich rocks. Some of these spinel phenocrysts match compositional constraints for spinel associated with “pink spinel anorthosites” inferred from remote sensing data. However, such spinel phenocrysts in meteorites and Apollo samples are typically associated with significant amounts of olivine ± pyroxene that exceed the compositional constraints for pink spinel anorthosites. We conclude that the remotely sensed “pink spinel anorthosites” have not been observed in the collections of lunar rocks. Moreover, we discuss impact‐excavation scenarios for the spinel‐bearing assemblages in Dhofar 1528 and compare the bulk rock composition of Dho 1528 to strikingly similar compositions of Luna 20 samples that contain ejecta from the Crisium impact basin.     

On the long-term motion of Pluto

A modified periodic orbit of the third kind is introduced that is closely related to periodic orbits of the third kind as defined by Poincaré. It is shown that Pluto librates about the periodic orbit with apparent stability. This further explains the librational motion of the resonant argument of Pluto and the avoidance of a Pluto-Neptune close approach as found by Cohen and Hubbard and the long-term motion of Pluto and the librational motion of the perihelion as found by Williams and Benson. With libration about a periodic orbit, the numerical solution of Williams and Benson can be extrapolated to longer times in the past and future.     

EVIDENCE OF HIGH COSMIC DUST CONCENTRATIONS IN LATE PLEISTOCENE POLAR ICE (20,000–14,000 YEARS BP)

Dust filtered from the lower portion of the Camp Century ice core (77°10'N, 61°08'W) has been analyzed for the presence of the cosmic dust indicators iridium and nickel using the neutron activation analysis technique. This study was carried out to test the hypothesis that the climatic change toward the end of the Last Ice Age was triggered by an incursion of nebular material into the Solar System. The analytical results are consistent with this hypothesis. Concentrations of Ir and Ni in the ice were one to two orders of magnitude higher during the latter portion of the Last Ice Age (19,700-14,200 years BP) as compared with current levels. Ir and Ni levels in 6 out of 8 samples suggest a total cosmic dust influx rate of about 0.5?3 times 10⁷ tons/yr to the Earth's surface as compared with about 1?7 x× 10⁵ tons/yr for the current influx. Elemental concentrations in 6 of the 8 dust samples ranged from 6? 96 ppb for Ir and < 60 to 3200 ppm for Ni. It is concluded that a major fraction of this invading dust would have been of submicron size in which case the concentration of light scattering particles would have been sufficient to significantly alter the light transmission properties of the Solar System and substantially affect the Earth's climate. These results mark the first time that cosmic dust deposition rates have been estimated for prehistoric times using the polar ice record.     

Charge-coupled device imaging spectroscopy of Mars. 1. Instrumentation and data reduction/analysis procedures

This paper describes the collection, reduction, and analysis of 0.4–1.0 m Mars imaging spectroscopy data obtained during the 1988 and 1990 oppositions from Mauna Kea Observatory and provides a general outline for the acquisition and analysis of similar imaging spectroscopy data sets. The U.H. 2.24-m Wide Field Grism CCD Spectrograph was used to collect 13 three-dimensional image cubes covering 90% of the planet south of 50°N in the 0.4–0.8 m region (/=245 at 0.6 m) and covering 55% of the planet south of 50°N in the 0.5–1.0 m region (/=293 at 0.75 m). Spectra extracted from these image cubes reveal the detailed character of the martian near-UV to visible spectrum. Images at red wavelengths reveal the classical albedo markings at 100–500 km spatial resolution while images at blue wavelengths show little surface feature contrast and are dominated by condensate clouds/hazes and polar ice. Many of the data acquisition, reduction, and analysis steps discussed here are new or unique to imaging spectroscopy data sets. These techniques exploit the information contained within the spatial domain of data such as these, thus allowing more traditional point-spectral analysis techniques to be expanded into an imaging format.     

Industry participation in stock assessment: the New Zealand SNA1 snapper (Pagrus auratus) fishery

We describe industry funded contributions to the assessment of the SNA1 snapper (Pagrus auratus) fishery during the 1990s and discuss the advantages and disadvantages of industry funded research. We also provide background on the history of fisheries management in New Zealand, on the current assessment and management processes, and on the SNA1 snapper fishery. In the SNA1 fishery, the contributions of industry and the cooperation with Government scientists has resulted in high quality assessments. In our opinion, the advantages of industry funded research out weigh the disadvantages and suggest that industry funded assessments are highly desirable and should be an integral part of any management system.     

Diatoms grow faster using ammonium in rapidly flushed eutrophic Dokai Bay,Japan

The importance of the nitrogen source for phytoplankton growth in a highly eutrophic embayment, Dokai Bay, was investigated. The DIN concentration often exceeded 100 μM of which 40–70% was NH₄ ⁺. During two incubation experiments, the natural assemblage of mainly diatoms took up NH₄ ⁺ instead of NO₃ ⁻. The growth of two Skeletonema species isolated in Dokai Bay were significantly faster on NH₄ ⁺ (1.86 and 1.27 div. d⁻¹ respectively) than on NO₃ ⁻ (1.55 and 1.04 div. d⁻¹ respectively). Our results indicated that these diatoms could grow faster by using NH₄ ⁺ compared to NO₃ ⁻ in this eutrophic bay.     

The oxygen isotope composition of water masses within the North Sea

Based on measurements of the ¹⁸O isotope composition of 247 samples collected over a 3-year period we have assessed the oxygen isotope composition of water masses in the North Sea. This is the first δ¹⁸O data set that covers the entire North Sea basin. The waters lie on a mixing line: δ¹⁸O (‰_VSMOW) = −9.300 + 0.274(S) with North Atlantic sub-polar mode water (SPMW) and surface waters, and Baltic Sea water representing the saline and freshwater end members respectively. Patterns exhibited in surface and bottom water δ¹⁸O distributions are representative of the general circulation of the North Sea. Oxygen-18 enriched waters from the North Atlantic enter the North Sea between Scotland and Norway and to a lesser extent through the English Channel. In contrast, oxygen-18 depleted waters mainly inflow from the Baltic Sea, the rivers Rhine and Elbe, and to a lesser degree, the Norwegian Fjords and other river sources. Locally the δ¹⁸O–salinity relationship will be controlled by the isotopic composition of the freshwater inputs. However, the range of local freshwater compositions around the North Sea basin is too narrow to characterise the relative contributions of individual sources to the overall seawater composition. This dataset provides important information for a number of related disciplines including biogeochemical research and oceanographic studies.     

Resource partitioning by two large planktivorous fishes Micromesistius australis and Macruronus magellanicus in the Southwest Atlantic

The ontogenetic, seasonal, bathymetric and regional variations in the feeding spectrum of 922 specimens of southern blue whiting Micromesistius australis and 512 specimens of hoki Macruronus magellanicus were studied on the Falkland Islands’ shelf (Southwest Atlantic) between November 1999 and April 2003. A total of 49 different prey items were found in the stomach contents of the two species, with the hyperiid Themisto gaudichaudii and Euphausiacea being amongst the most important prey. Although the species composition did not change over fish size, the proportions of individual prey items in their diets did, with an increase in T. gaudichaudii and Euphausiacea with increasing fish size in southern blue whiting. The opposite occurred in hoki. Seasonal variations in the diet were found to mirror the seasonal abundance of prey around the Falkland Islands for the two species. Intra-specific differences in the diet of both predators reflected the distribution of prey, which in turn was determined by the water structure in the two regions sampled, leading to very different diets. In the limited time that the two species occupied the same space there was little or no competition resulting in almost total segregation of their trophic niches in space and time.