Production and detection of carbon dioxide on Iapetus

Cassini VIMS detected carbon dioxide on the surface of Iapetus during its insertion orbit. We evaluated the CO₂ distribution on Iapetus and determined that it is concentrated almost exclusively on Iapetus’ dark material. VIMS spectra show a 4.27-μm feature with an absorption depth of 24%, which, if it were in the form of free ice, requires a layer 31 nm thick. Extrapolating for all dark material on Iapetus, the total observable CO₂ would be 2.3 × 10⁸ kg.Previous studies note that free CO₂ is unstable at 10 AU over geologic timescales. Carbon dioxide could, however, be stable if trapped or complexed, such as in inclusions or clathrates. While complexed CO₂ has a lower thermal volatility, loss due to photodissociation by UV radiation and gravitational escape would occur at a rate of 2.6 × 10⁷ kg year⁻¹. Thus, Iapetus’ entire inventory of surface CO₂ could be lost within a few decades.The high loss/destruction rate of CO₂ requires an active source. We conducted experiments that generated CO₂ by UV radiation of simulated icy regolith under Iapetus-like conditions. The simulated regolith was created by flash-freezing degassed water, crushing it into sub-millimeter sized particles, and then mixing it with isotopically labeled amorphous carbon (¹³C) dust. These samples were placed in a vacuum chamber and cooled to temperatures between 50 K and 160 K. The samples were irradiated with UV light, and the products were measured using a mass spectrometer, from which we measured ¹³CO₂ production at a rate of 2.0 × 10¹² mol s⁻¹. Extrapolating to Iapetus and adjusting for the solar UV intensity and Iapetus’ surface area, we calculated that CO₂ production for the entire surface would be 1.1 × 10⁷ kg year⁻¹, which is only a factor of two less than the loss rate. As such, UV photochemical generation of CO₂ is a plausible source of the detected CO₂.     

Reconciling the centimeter- and millimeter-wavelength ammonia absorption spectra under jovian conditions: Extensive millimeter-wavelength measurements and a consistent model

Over 1000 laboratory measurements of the 2-4 mm-wavelength opacity of ammonia have been made under simulated jovian atmospheric conditions using a high-precision laboratory system developed at Georgia Tech. These laboratory measurements of the opacity of ammonia were made of various gas mixtures of hydrogen (∼77.5-85.5%), helium (∼12.5-13.5%), and ammonia (1-10%) at pressures between 1 and 3 bars and temperatures between 200 and 300 K. Laboratory measurements were also made of the opacity of pure ammonia at pressures between 0.05 and 1 bar and temperatures between 200 and 300 K. Using these millimeter-wavelength measurements and close to 2000 cm-wavelength measurements made by Hanley et al. (2009), a new consistent model has been developed to accurately characterize the absorption spectra of ammonia in a hydrogen/helium atmosphere in the 1 mm to 30 cm wavelength range. This model can be used in the 1-30 cm wavelength range at pressures up to 20 bars and temperatures from 200 to 500 K and in the 1 mm to 1 cm wavelength range at pressures up to 3 bars and temperatures from 200 to 300 K. These measurements and the accompanying model will enable better interpretation of the centimeter- and millimeter-wavelength emission spectra of the jovian planets.     

Asteroid 21 Lutetia at 3 μm: Observations with IRTF SpeX

We present observations of Asteroid 21 Lutetia collected 2003–2008 using the SpeX instrument on the NASA Infrared Telescope Facility (IRTF) covering 2–4 μm. We also reevaluate NSFCam observations obtained in 1996 (Rivkin, A.S., Lebofsky, L.A., Clark, B.E., Howell, E.S., Britt, D.T. [2000]. Icarus 145, 351–368). Taken together, these show deeper 3-μm band depths (of order 3–5%) in the southern hemisphere of Lutetia, and shallower band depths (of order 2% or less) in the north. Such variation is consistent with observations at shorter wavelength by previous workers (Nedelcu, D.A. et al. [2007]. Astron. Astrophys. 470, 1157–1164; Lazzarin, M. et al. [2010]. Mon. Not. R. Astron. Soc. 408, 1433–1437), who observed hemispheric-level variations from C-like spectra to X-like spectra.While the shallowness of absorption bands on Lutetia hinders identification of its surface composition, goethite appears plausible as a constituent in its southern hemisphere (Beck, P., Quirico, E., Sevestre, D., Montes-Hernandez, G., Pommerol, A., Schmitt, B. [2011]. Astron. Astrophys. 526, A85–A89). Mathematical models of space weathered goethite are most consistent with Lutetia’s southern hemisphere spectrum, but more work and further observations are necessary to confirm this suggestion.     

Non-LTE radiative transfer for sub-millimeter water lines in Comet 67P/Churyumov-Gerasimenko

The European Space Agency (ESA) Rosetta spacecraft (Schulz, R., Alexander, C., Boehnhardt, H., Glassmeier, K.H. (Eds.) [2009]. “ROSETTA - ESA”) will encounter Comet 67P/Churyumov-Gerasimenko in 2014 and spend the next 18 months in the vicinity of the comet, permitting very high spatial and spectral resolution observations of the coma and nucleus. During this time, the heliocentric distance of the comet will change from ∼3.5 AU to ∼1.3 AU, accompanied by an increasing temperature of the nucleus and the development of the coma. The Microwave Instrument for the Rosetta Orbiter (MIRO) will observe the ground-state rotational transition (1₁₀-1₀₁) of H₂¹⁶O at 556.936 GHz, the two isotopologues H₂¹⁷O and H₂¹⁸O and other molecular transitions in the coma during this time (Gulkis, S. et al., [2007]. MIRO: Microwave Instrument for Rosetta Orbiter. Space Sci. Rev. 128, 561-597).The aim of this study is to simulate the water line spectra that could be obtained with the MIRO instrument and to understand how the observed line spectra with various viewing geometries can be used to study the physical conditions of the coma and the water excitation processes throughout the coma. We applied an accelerated Monte Carlo method to compute the excitations of the seven lowest rotational levels (1₀₁, 1₁₀, 2₁₂, 2₂₁, 3₀₃, 3₁₂, and 3₂₁) of ortho-water using a comet model with spherically symmetric water outgassing, density, temperature and expansion velocity at three different heliocentric distances 1.3 AU, 2.5 AU, and 3.5 AU. Mechanisms for the water excitation include water-water collisions, water-electron collisions, and infrared pumping by solar radiation.Synthetic line spectra are calculated at various observational locations and directions using the MIRO instrument parameters. We show that observations at varying viewing distances from the nucleus and directions have the potential to give diagnostic information on the continuum temperature and water outgassing rates at the surface of the nucleus, and the gas density, expansion velocity, and temperature of the coma as a function of distance from the nucleus. The gas expansion velocity and temperature affect the spectral line width and frequency shift of the line from the rest frequency, while the gas density (which is directly related to the outgassing rate) and the line excitation temperature determine the antenna temperature of the absorption and emission signal in the line profile.     

A laboratory study of the bidirectional reflectance from particulate samples

The Hapke (Hapke, B. [1981]. J. Geophys. Res. 86, 3039-3054) photometric model and its modifications are widely used to characterize telescopic, spacecraft, and laboratory observations of the bidirectional reflectance of particulate surfaces. Following work and methods laid out in a companion paper (Helfenstein, P., Shepard, M.K. [2011]. Icarus, in press), we deconstruct the Hapke model and, separating all empirical and ad hoc parameters (opposition surge, particle phase function, surface roughness), combine them into a single parameter called the surface phase function, F(α). We illustrate how to extract this function from scattering data sets acquired with the Bloomsburg University Goniometer (BUG). We show how this method can be used to rapidly and accurately characterize bidirectional reflectance data sets from laboratory and spacecraft measurements, often giving better fits to the data. We examine samples with strong color contrasts in different wavelengths. This allows us to examine the exact same surface, changing only the albedo to investigate how the amplitude and the detailed shape of the surface phase function might systematically depend on wavelength and albedo. We also examine the changes in scattering behavior that result when samples are compacted and find the surface phase function and single scattering albedo to be significantly changed. We suggest that these observations support the hypothesis that much of the scattering behavior attributed to the single particle phase function is instead cause by the surface micro-structure.     

Methane release and the carbon cycle on Mars

It has been suggested that the present release rate of methane to the Martian atmosphere could be the result of serpentinization in the deep subsurface, followed by the conversion of H₂ to CH₄ in a CO₂-rich fluid. Making this assumption, we show that the cryosphere could act as a buffer storing, under the form of micron-size methane clathrate particles, the methane delivered from below by hydrothermal fluids and progressively releasing it to the atmosphere at the top. From an extrapolation of the present CH₄ release rate back to the past, we calculate that up to several hundred millibars (～200–2000 mbar) of CO₂, resulting from the oxidation of the released CH₄, in addition to the volcanic supply (～400 mbar), should have accumulated in the atmosphere in the absence of a CO₂ sink. We reassess the capability of escape to have removed CO₂ from the atmosphere by C non-thermal escape and show that it is not significant. We suggest that atmospheric carbon is recycled to the crust through an active subsurface hydrological system, and precipitates as carbonates within the crust. During episodic periods of magmatic activity, these carbonates are decomposed to CO₂ dissolved in running water, and CO₂ can react with H₂ formed by serpentinization to build CH₄. CH₄ is then buffered in the subsurface cryosphere, above the water table, and finally released to the atmosphere, before being recycled to the subsurface hydrological system, and converted back to carbonates. We propose a typical evolution curve of the CO₂ pressure since the late Noachian based on our hypothesis. Contrary to the steady state carbon cycle at work on Earth, a progressive damping of the carbon cycle occurs on Mars due to the absence of plate tectonics and the progressive cooling of the planet.     

Double Relics in the Outskirts of A3376: Accretion Flows Meet Merger Shocks?

The case of spectacular ring-like double radio relics in the merging, rich galaxy cluster A3376 is of great interest to study non-thermal phenomena at cluster outskirts. We present the first low frequency (330 and 150 MHz) images of the double relics using the GMRT. With our GMRT 330 MHz map and the VLA 1400 MHz map (Bagchi et al. 2006), we have constructed and analyzed the distribution of spectral indices over the radio relics. We find flat spectral indices at the outer edges of both the relics and a gradual steepening of spectral indices toward the inner regions. This supports the model of outgoing merger shock waves. The eastern relic has a complex morphology and spectral index distribution toward the inner region. This will be discussed in the context of the effect of large-scale accretion flows on the outgoing merger shocks as reported in the recent simulations.     

First encounter with a live male blanket octopus: The world's most sexually size‐dimorphic large animal

The first encounter with a live male blanket octopus, Tremoctopus violaceus Chiaie, 1830, illustrates the most extreme example of sexual size‐dimorphism in a non‐microscopic animal. Females attain sizes of up to 2 m long—almost 2 orders of magnitude larger than the 2.4‐cm‐long male. Weight ratios between the sexes are at least 10 000:1 and are likely to reach 40 000:1. Sexual selection and the unique defensive strategy of carrying cnidarian stinging tentacles may both have contributed to the evolution of this extreme size‐dimorphism. Such dimorphism is not seen in any other animal remotely as large.