The atmosphere of Io from Pioneer 10 radio occultation measurements

The occultation of the Pioneer 10 spacecraft by Io (JI) provided an opportunity to obtain two S-band radio occultation measurements of its atmosphere. The dayside entry measurements revealed an ionosphere having a peak density of about 6 × 10⁴ elcm^?3 at an altitude of about 100 km. The topside scale height indicates a plasma temperature of about 406 K if it is composed of Na⁺ and 495 K if N₂⁺ is principal ion. A thinner and less dense ionosphere was observed on the exit (night side), having a peak density of 9 × 10³ elcm^?3 at an altitude of 50 km. The topside plasma temperature is 160 K for N₂^? and 131 K for Na⁺. If the ionosphere is produced by photoionization in a manner analogous to the ionospheres of the terrestrial planets, the density of neutral particles at the surface of Io is less than 10¹¹?10¹² cm³, corresponding to a surface pressure of less than 10^?8 to 10^?9 bars. Two measurements of its radius were also obtained yielding a value of 1830 km for the entry and 192 km for the exit. The discrepancy between these values may indicate an ephemeris uncertainty of about 45 km. The two measurements yield an average radius of 1875 km, which is not in agreement with the results of the Beta Scorpii stellar occultation.     

A distinctive type of ascending prominence — ‘fountain’

Cinematographic observations of solar prominences made at Mauna Loa during the past couple of years suggest that there is a well-defined sub-class of ascending prominences characterized by closed-system transference of chromospheric material along an arch or loop (up one leg and down the other); meanwhile the entire prominence envelope steadily rises upward and expands through the corona. We denote these prominences as fountains. Several examples are described. Fountains appear to be well contained by coronal magnetic fields. Their total kinetic energy is in the order of 10³⁰ erg but dissipation is typically quite slow (over time periods like 100 min) so that the correlative disturbances (radio bursts, coronal transients, chromopsheric brightenings, etc.) are generally unspectacular or non-existent.This research was started when E. T.-H. was still on the staff of the High Altitude Observatory.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Diffuse cosmic gamma-ray background in the 28 ke V-4.1 MeV range from Kosmos 461 observations

Diffuse cosmic background and atmospheric gamma-radiation in the range 28 keV-4.1 MeV were studied with a scintillation spectrometer on board of the Kosmos 461 satellite. Separation of the cosmic and atmospheric components was made possible through a reliable determination of the geomagnetic dependences of albedo gamma-radiation: The spectrum of diffuse background in the energy range covered cannot be fitted with a common law. At energies below 400 keV the spectrum follows a power-law $$I = (5.6 \pm 0.5) \times 10^{ - 3} E^{ - (2.80 \pm 0.05)} cm^{ - 2} s^{ - 1} sr^{ - 1} MeV^{ - 1} .$$ Starting from 400 keV, this power-law breaks down; the spectrum revealing a clearly pronounced shoulder. Extrapolation of the power-law spectrum to higher energies shows that the gamma-ray component responsible for the change in the shape of the spectrum is quite strong, becoming predominant in the diffuse background in the range 1–100 MeV. The intensity of excess radiation is maximum in the region of 700–800 keV reaching ～1.8×10^?2 cm^?2s^?1sr^?1 MeV^?1. The shape of the high energy component spectrum of the diffuse background constructed using the data of Kosmos 461 and SAS-2 is in agreement with the hypotheses of the cosmological origin of the radiation.     

Relict magnesian calcite oolite and subsidence of the Amazon shelf

Oolitic sediments occur over large portions of the outer continental shelf off northernmost Brazil and southern French Guiana. Carbon-14 dates, stable isotope values and analogies with similar deposits from other areas in the world indicate that the ooids were formed in shallow water (possibly protected hypersaline environments) during low stands of sea level. In contrast to both modern ooids and other relict ooids, however, the Amazon shelf ooids are composed entirely of magnesian calcite (12 mol % MgCO₃) and possess radial crystal microstructures. A comparison of water depths and ages of the Amazon ooids with the generally accepted eustatic sea level curve indicates that the Amazon shelf subsided more than 100 m 16-21 thousand years ago. Prior to and subsequent to the subsidence, however, the outer shelf remained relatively stable.     

The sources of material comprising a mass ejection coronal transient

The origin of the material which is ejected during a white light coronal transient has not been determined heretofore. Study of a disturbance on 26 and 27 August 1973, during which a slowly ascending prominence and a more rapid accompanying coronal transient were simultaneously observed, helps to resolve this question. Prominence images obtained in Hα 6563 Å and in He II 304 Å are nearly identical. The mass ejection transient observed in white light (3700–7000 Å) appeared to be a loop about 1 R_⊙ higher than the top of the ascending prominence; it accelerated away from the prominence below it. These observations imply: (1) the bulk of the ejected material did not originate in the ascending prominence; (2) therefore, most of the material must have come from the low corona above the prominence, (and was at coronal temperatures during its outward passage); and (3) the total event - ascending prominence accompanied by coronal mass ejection - was far larger, more energetic, and longer lasting than would be inferred from the prominence observations alone. The transient of 26–27 August was slow and of atypical shape compared to other mass ejection transients, but we believe that these three conclusions apply to most, if not all, of the more than 60 loop-shaped coronal transients observed by the High Altitude Observatory's coronagraph during the nine-month flight of Skylab.     

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.     

Tracing nitrogen in volcanic and geothermal volatiles from the Nicaraguan volcanic front

We report new chemical and isotopic data from 26 volcanic and geothermal gases, vapor condensates, and thermal water samples, collected along the Nicaraguan volcanic front. The samples were analyzed for chemical abundances and stable isotope compositions, with a focus on nitrogen abundances and isotope ratios. These data are used to evaluate samples for volatile contributions from magma, air, air-saturated water, and the crust. Samples devoid of crustal contamination (based upon He isotope composition) but slightly contaminated by air or air-saturated water are corrected using N₂/Ar ratios in order to obtain primary magmatic values, composed of contributions from upper mantle and subducted hemipelagic sediment on the down-going plate. Using a mantle endmember with δ¹⁵N = −5‰ and N₂/He = 100 and a subducted sediment component with δ¹⁵N = +7‰ and N₂/He = 10,500, the average sediment contribution to Nicaraguan volcanic and geothermal gases was determined to be 71%. Most of the gases were dominated by sediment-derived nitrogen, but gas from Volcán Mombacho, the southernmost sampling location, had a mantle signature (46% from subducted sediment, or 54% from the mantle) and an affinity with mantle-dominated gases discharging from Costa Rica localities to the south. High CO₂/N_{2 exc.} ratios (N_{2 exc.} is the N₂ abundance corrected for contributions from air) in the south are similar to those in Costa Rica, and reflect the predominant mantle wedge input, whereas low ratios in the north indicate contribution by altered oceanic crust and/or preferential release of nitrogen over carbon from the subducting slab. Sediment-derived nitrogen fluxes at the Nicaraguan volcanic front, estimated by three methods, are 7.8 × 10⁸ mol N/a from ³He flux, 6.9 × 10⁸ mol/a from SO₂ flux, and 2.1 × 10⁸ and 1.3 × 10⁹ mol/a from CO₂ fluxes calculated from ³He and SO₂, respectively. These flux results are higher than previous estimates for Central America, reflecting the high sediment-derived volatile contribution and the high nitrogen content of geothermal and volcanic gases in Nicaragua. The fluxes are also similar to but higher than estimated hemipelagic nitrogen inputs at the trench, suggesting addition of N from altered oceanic basement is needed to satisfy these flux estimates. The similarity of the calculated input of N via the trench to our calculated outputs suggests that little or none of the subducted nitrogen is being recycled into the deeper mantle, and that it is, instead, returned to the surface via arc volcanism.     

Cadmium absorption and accumulation in different parts of kidney beans, radishes and pumpkins

This study is done to measure the absorption and distribution of cadmium in different parts of kidney beans, radishes and pumpkins. Three parts of a field was chosen. In one part 65 ppm of cadmium nitrate was added to water and in the other part 130 ppm, the last part was irrigated with normal water. Samples were digested by EPA 3050 method. Cadmium concentration was measured by Unicam 919 absorption unit. Beans accumulate cadmium mostly in root (70 ppm) and a little amount is mobilized through upper parts (12–16ppm), but kidneys did not accumulate a significant amount. In radishes the roots did not accumulate a significant amount of cadmium but stems had 4 ppm and leaves had 25 ppm. Cadmium concentration in soil does not affect its concentration in different parts of pumpkins and beside the stems and leaves (4 ppm) the other parts' concentrations were insignificant. In regard to the results of this study the cadmium concentrations in edible parts of the samples (kidney beans, radish roots and pumpkin fruit) were less than the U.S. EPA standards for agriculture and human beings.     

Heterogeneous organic matter from the surface horizon of a temperate zone marsh

Abundance, bulk chemical composition and sources of the organic matter in the surface horizon of the permanently water-covered part of an intermittently water-covered marsh were investigated. Lipids, insoluble non-hydrolysable macromolecular organic matter and black carbon fractions were isolated and examined via Rock-Eval pyrolysis, elemental analysis, Fourier transform infrared spectroscopy, isotopic (δ¹³C, δ¹⁵N) methods and high resolution transmission electron microscopy. Integration of bulk Rock-Eval data, elemental and isotopic composition, together with spectroscopic features, suggested immature Type III organic matter derived mainly from C₃ vascular plants. The distribution of n-alkanes from the non-aromatic lipid fraction exhibited the importance of emergent macrophytes and terrestrial plants, as well as a moderate input of submerged/floating macrophytes to the source biomass. Mathematical deconvolution of a Rock-Eval pyrogram revealed highly heterogeneous organic matter composed of a mixture of thermally labile biopolymers (36%) at various stages of decomposition, as well as humic substances and highly refractory organic matter (64%) in the whole sample. Markedly lower heterogeneity and aliphaticity, together with a higher proportion of humic substances and highly refractory organic matter (ca. 84%) were observed in the macromolecular fraction. An abundant contribution of black carbon to the macromolecular fraction was indicated by mathematical deconvolution of the Rock-Eval pyrogram and was clearly shown by the isolation of this fraction and chemical oxidation. The black carbon fraction appeared to account for ca. half of the macromolecular fraction, the carbon in these two fractions representing 30% and 14% of the initial carbon, respectively. The electron microscopy observations directly evidenced the presence of black carbon, which was comprised of both amorphous poorly organized particles and highly ordered onion-shaped particles.     

Natural attenuation and bioremediation of Prestige fuel oil along the Atlantic coast of Galicia (Spain)

Heavy fuel oil spilled from the oil tanker Prestige in November 2002 affected hundreds of km of Spanish shoreline. We carried out a two year study at two highly contaminated sites in order to monitor natural attenuation of the residues coating shore rocks and to test the effectiveness of bioremediation with an oleophilic fertilizer (S200). The methodology included an innovative approach for oil load calculation (based on image analysis techniques), the analysis of the fate of hydrocarbons by means of chemical biomarkers and different microbiological techniques for isolating and examining hydrocarbon degraders.Considerable hydrocarbon depletion from shorelines (≈100% for light-medium linear alkanes and ≈35% for aromatics such as pyrene) was observed within the first months after the spill. However, this natural attenuation effect dramatically slowed down in the following year, although partial enhancement (especially for the aromatic fraction) was attained as a result of the application of S200 to stimulate indigenous microorganisms. In addition, one of the main outcomes of this work concerns the remarkable hydrocarbon depletion achieved at points where fresh water flowed through the shore rocks. The study of samples collected where this natural attenuation phenomenon took place made it possible to isolate heterotrophic bacteria and fungi that are likely to cooperate with cyanobacteria in hydrocarbon biodegradation. The overall results strongly advocate the implementation of new bioremediation approaches, including alternatives such as the use of natural fresh water to irrigate polluted areas.