Composition of the phytoplankton pigments in the surface waters along a transect from the Northwestern to the southeastern Pacific Ocean

Multidisciplinary oceanic investigation was undertaken in Aug–Sep. 2003 along a transect from Northwestern (Busan, Korea) to Southeastern Pacific (Talcahuano, Chile) to understand the physical, chemical and biological features in the surface water, and to depict their interaction with the atmosphere. Among the twenty parameters measured, we describe the physical, chemical and biological features. Physico-chemical data were analyzed in conjunction with the geographic position and yielded 7 peculiar surface water masses. The first water mass (28.4°N, 130.8°E to 21.5°N, 139.5°E) was warm and low in phosphate and nitrate content, and high in silicate. The concentration of phytoplankton pigment was one of the lowest. The second (20.4°N, 140.7°E to 2.2°S, 162.9°E) was the warmest and the least saline. Nitrate and phosphate concentration were one of the lowest. Chlorophyll a (Chl a) concentration was the lowest among the surface waters. The third (3.4°S, 164.0°E to 14.5°S, 173.3°E) was warm. Nitrate concentration was the lowest. CHL-a, peridinin (Perid), violaxanthin (Viola), zeaxanthin (Zea), chlorophyll-b (Chl b) and β-CAR were abundant. The fourth (18.6°S, 177.5°E to 31.8°S, 123.9°W) was saline and poor in nutrient concentration. The contributions of 19′-butanoyloxyfucoxanthin (But-fuco), 19′-hexanoyloxyfucoxanthin (Hex-fuco), and CHL b to CHL a were non-negligible. The fifth (32.4°S, 122.1°W to 33.8°S, 117.2°W) was relatively cold and well oxygenated. Concentration of Fuco, But-fuco, Hex-fuco and Chl b was high. The sixth (34.2°S, 115.4°W to 37.4°S, 92.1°W) was cold, well oxygenated and enriched with phosphate and nitrate. Concentration of phytoplankton pigment was, however, one of the lowest. The seventh, located off the Chilean coast, from 37.2°S, 87.2°W to 36.1°S, 74.1°W was well oxygenated and highly enriched with nitrate and phosphate. Phytoplankton pigments such as Fuco, Perid, But-fico, and Hex-fuco were rich. The 7 surface water masses are partially attributed to Kuroshio Current, North Equatorial Current and North Equatorial Countercurrent, South Equatorial current, South Pacific Subtropical Gyre, South Pacific Current, Subtropical Front and Chilean coastal water. The differences in physicochemical characteristics and the history of the surface water resulted in difference in quantity and composition of the phytoplankton pigment.     

Long-term bottom water warming in the north Ross Sea

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.     

Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.     

The influence of the Sabatayn Evaporites on the hydrocarbon prospectivity of the Eastern Shabwa Basin, Onshore Yemen

The Shabwa Basin is the northeastern extension of the Marib-Al Jawf-Shabwa system of Mesozoic grabens, located onshore in the Republic of Yemen. An evaporitic sequence with an estimated maximum depositional thickness of 300 metres was deposited during the Tithonian. It is designated the Sabatayn Formation and exerts significant control on most of the play elements in the principal hydrocarbon play systems anticipated in the northeastern part of the basin. Migration of hydrocarbons from pre-salt source rocks into intra-and post-salt reservoirs is restricted by the evaporites. Localised heat flow perturbations introduced by the salt, increase the maturity of post-salt source rocks. Post and intra-salt reservoirs are structured by listric faulting on a salt detachment, salt pillowing due to post-depositional loading, by local salt dissolution and by late folding due to gravity sliding of the post-salt section on a salt detachment. Early dissolution and reprecipitation of salt is responsible for occlusion of porosity in intra-salt clastic reservoirs.     

Generation of long barotropic waves by moving baric disturbances in a system of basins connected by a channel

We consider long barotropic waves in a system of two rectangular basins connected by a channel in the case where waves are generated by the moving region of disturbances of atmospheric pressure passing above one of the basins. By using a numerical model, we compute the characteristics of the wave process for various values of the parameters of this system. The results of numerical calculations are compared with the corresponding characteristics obtained for the case of a closed basin. We also analyze the distinctive features of long-wave processes induced in the presence of the channel. Translated by Peter V. Malyshev and Dmitry V. Malyshev     

Electron microscopic observations of shale diagenesis, offshore Louisiana, USA, Gulf of Mexico

 Scanning and transmission electron microscopic analyses of shale samples from offshore Louisiana, USA, Gulf of Mexico, reveal the relationship between mineralogical and microfabric changes during burial diagenesis. The local geopressured zone begins at 2200-m depth. Above that depth the shales are smectite-rich, generally lack particle orientation, and contain appreciable pores. Below the 2200-m depth, the shales become more illite-rich with increasing burial, more crystalline, and less porous. Microfabric changes are mainly caused by compaction during burial diagenesis; mineralogical changes (smectite-to-illite) and crystal growth also play an important role in fabric alteration during deep burial diagenesis. Received: 12 May 1998 / Revision received: 14 July 1998     

Geomorphology and sedimentology of the continental shelf adjacent to Mac. Robertson Land,East Antarctica: A scalped shelf

During the Quaternary, the Mac. Robertson shelf of East Antarctica was deeply eroded by glaciers and currents exposing the underlying basement, resulting in a scalped shelf. Major geomorphic zones are: (1) high-relief, ridge and valley topography (200–1400 m); (2) smooth sea floors associated with low-energy, depositional shelf valleys and basins (400–800 m); (3) low-relief, planated banktops (100–200 m); and (4) iceberg gouged and current reworked seaward-bank margins and upper slope (200 to < 630 m). About 90% of the shelf's surface has net erosional conditions and about 10% is net depositional. The sedimentary processes and deposits may be common to large areas of the East Antarctic margin.