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841.
Water in boninite glass and coexisting orthopyroxene: concentration and partitioning 总被引:3,自引:0,他引:3
Patrick F. Dobson Henrik Skogby George R. Rossman 《Contributions to Mineralogy and Petrology》1995,118(4):414-419
Spectroscopic measurements of water in glass inclusions in pyroxene from boninite samples from the Bonin Islands conclusively
document the high (2.8–3.2 wt %) primary water contents of boninite magmas. Associated quenched glass from pillow lava rims
have slightly lower (2.2–2.4 wt %) water contents, suggesting that minor amounts of degassing occurred between the time of
melt entrapment in the orthopyroxenes and subsequent eruption on the sea floor. Some zonation of molecular water contents
in pillow rim glasses was observed. OH contents of the host orthopyroxene phenocrysts were also measured, allowing for the
calculation of partition coefficients for water between boninite melt and orthopyroxene. These values (0.003–0.004) for water
partitioning between orthopyroxene and mafic melts may help constrain petrogenetic models of mantle-derived magmas.
Received: 20 September 1993 / Accepted: 26 June 1994 相似文献
842.
The ability to properly manage the oxidation of pyritic minerals and associated acid mine drainage is dependent upon understanding
the chemistry of the disposal environment. One accepted disposal method is placing pyritic-containing materials in the groundwater
environment. The objective of this study was to examine solubility relationships of Al and Fe minerals associated with pyritic
waste disposed in a low leaching aerobic saturated environment. Two eastern oil shales were used in this oxidizing equilibration
study, a New Albany Shale (unweathered, 4.6 percent pyrite), and a Chattanooga Shale (weathered, 1.5 percent pyrite). Oil
shale samples were equilibrated with distilled-deionized water from 1 to 180 d with a 1∶1 solid-to-solution ratio. The suspensions
were filtered and the clear filtrates were analyzed for total cations and anions. Ion activities were calculated from total
concentrations. Below pH 6.0, depending upon SO
4
2−
activity, Al3+ solubility was controlled by AlOHSO4 (solid phase) for both shales. Initially, Al3+ solubility for the New Albany Shale showed equilibrium with amorphous Al(OH)3. The pH decreased with time, and Al3+ solubility approached equilibrium with AlOHSO4(s). Below pH 6.0, Fe3+ solubility appeared to be regulated by a basic iron sulfate solid phase with the stoichiometric composition of FeOHSO4(s). The results of this study indicate that below pH 6.0, Al3+ solubilities, are limited by basic Al and Fe sulfate solid phases (AlOHSO4(s) and FeHSO4(s)). The results from this study further indicate that the acidity in oil shale waters is produced from the hydrolysis of Al3+ and Fe3+ activities in solution. These results indicate a fundamental change in the stoichiometric equations used to predict acidity
from iron sulfide oxidation. The results of this study also indicate that water quality predictions associated with acid mine
drainage can be based on fundamental thermodynamic relationships. As a result, waste management decisions can be based on
waste-specific/site-specific test methods. 相似文献
843.
Badrinath-Gangotri plutons (Garhwal, India): petrological and geochemical evidence for fractionation processes in a high Himalayan leucogranite 总被引:1,自引:0,他引:1
Bruno Scaillet Christian France-Lanord Patrick Le Fort 《Journal of Volcanology and Geothermal Research》1990,44(1-2)
The Gangotri leucogranite is the western end of the Badrinath granite, one of the largest bodies of the High Himalayan Leucogranite belt (HHL). It is a typical fine grained tourmaline + muscovite ± biotite leucogranite. The petrography shows a lack of restitic phases. The inferred crystallization sequence is characterized by the early appearance of plagioclase, quartz and biotite and by the late crystallization of the K-feldspar. This suggests that, in spite of being of near minimum melt composition, the granite probably had long crystallization or melting interval, in agreement with previous experimental studies. Tourmaline and muscovite have a mainly magmatic origin. Even though the major element composition is homogeneous, there are several geochemical trends (when CaO decreases there is an increase in Na2O, Rb, Sn, U, B, F and a decrease in K2O, Fe2O3, TiO2, Sr, Ba, Zr, REE, Th) which are best explained by a fractionation process with early crystallizing phases. Experimental solubility models for zircon and monazite in felsic melt support a magmatic origin for these two accessory phases as well.Rb/Sr isotope data show this granite to have, like other HHL, heterogeneous isotopic values for Sr (initial 87Sr/86Sr ratios, calculated at 20 Ma, range between 0.765 and 0.785). Therefore no mixing (i.e. no convection) occurred between the different batches of magma. In contrast 18O data show little variation (13.04% ± 0.25), implying a source with homogeneous 18O values. Differences in timing between fluid infiltration and the onset of melting, related to differences in temperature of the source, could explain why source homogenization occurred for the Gangotri and not for the Manaslu granite.The use of experimental results for solubility and the position of the accessory minerals during melting, predict a low viscosity for the melt during its extraction. This in turn explains the lack of restitic phases (major and accessory) in the granite as well as some field features (lensoid shape, pronounced magmatic layering). Based on the petrographic and isotopic studies, it is suggested that the mechanism of ascent was not diapiric but rather that the melt ascended along several fractures and the level of emplacement was partialy controlled by the density contrast between the melt and host rocks. 相似文献
844.
Alain Demant Patrick Lestrade Ruananza T Lubala Ali B Kampunzu Jacques Durieux 《Bulletin of Volcanology》1994,56(1):47-61
Three major phases are distinguished during the growth of Nyiragongo, an active volcano at the western limit of the Virunga
Range, Zaire. Lavas erupted during phase 1 are strongly undersaturated melilitites characterized by the presence of kalsilite
phenocrysts, perovskite, and the abundance of calcite in the matrix. Such lavas crop out mainly on the inner crater wall and
progressively evolve toward more aphyric melilite nephelinites well represented on the flanks of the volcano. Adventive vents
lying at the base of the cone developed along radial fracture systems and erupted olivine and/or clinopyroxene – rich melilitites
or nephelinites. Stage 2 lavas are melilite-free nephelinites. Clinopyroxene is the main phenocryst and feldspathoids are
abundant in the lavas exposed on the crater wall. These flows result from periodic overflowing of a magma column from an open
crater. Extensive fissure flows which erupted from the base of the cone at the end of this stage are related to widespread
draining out of magma which in turn induces the formation of the summit pit crater. Magmas erupted during stage 3 are relatively
aphyric melilite nephelinites and the main volcanological characteristic is the permanent lava lake observed into the pit
crater until the 1977 eruption. Fluctuations of the level of the lava lake was responsible for the development of the inner
terraces. Periodic overflowing of the lava lake from the central pit formed the nepheline aggregate lava flows. Petrography
and major element geochemistry allow the determination of the principal petrogenetic processes. Melilitites and nephelinites
erupted from the summit crater are lavas derived, via clinopyroxene fractionation, from a more primitive melt. The abundance
of feldspathoids in these lavas is in keeping with nepheline flotation. Aphyric melilite nephelinites covering the flanks
and the extensive fissure flows have a homogeneous chemical composition; rocks from the historical lava lake are slightly
more evolved. All these lavas differentiated in a shallow reservoir. Lavas erupted from the parasitic vents are mainly olivine
and/or clinopyroxene-phyric rocks. Rushayite and picrites from Muja cone are peculiar high-magnesium lavas resulting from
the addition of olivine xenocrysts to melilitic or nephelinitic melts. Fluid and melt inclusions in olivine and clinopyroxene
phenocrysts indicate a crystallization depth of 10–14 km. A model involving two reservoirs located at different depths and
periodically connected is proposed to explain the petrography of the lavas; this hypothesis is in accordance with geophysical
data.
Received: July 8, 1993/Accepted: September 10, 1993 相似文献
845.
Inadvertent release of petroleum products such as gasoline into the subsurface can initiate ground water contamination, particularly by the toxic, water-soluble and mobile gasoline components: benzene, toluene and xylenes (BTX). This study was undertaken to examine the processes controlling the rate of movement and the persistence of dissolved BTX in ground water in a shallow, unconfined sand aquifer.
Water containing about 7.6 mg/ L total BTX was introduced below the water table and the migration of contaminants through a sandy aquifer was monitored using a dense sampling network. BTX components migrated slightly slower than the ground water due to sorptive retardation. Essentially all the injected mass of BTX was lost within 434 days due to biodegradation. Rates of mass loss were similar for all monoaromatics; benzene was the only component to persist beyond 270 days. Laboratory biodegradation experiments produced similar rates, even when the initial BTX concentration varied.
A dominant control over BTX biodegradation was the availability of dissolved oxygen. BTX persisted at the field site in layers low in dissolved oxygen. Decreasing mass loss rates over time observed in the field experiment are not likely due to first-order deeradation rates, but rather to the persistence of small fractions of BTX mass in anoxic layers. 相似文献
Water containing about 7.6 mg/ L total BTX was introduced below the water table and the migration of contaminants through a sandy aquifer was monitored using a dense sampling network. BTX components migrated slightly slower than the ground water due to sorptive retardation. Essentially all the injected mass of BTX was lost within 434 days due to biodegradation. Rates of mass loss were similar for all monoaromatics; benzene was the only component to persist beyond 270 days. Laboratory biodegradation experiments produced similar rates, even when the initial BTX concentration varied.
A dominant control over BTX biodegradation was the availability of dissolved oxygen. BTX persisted at the field site in layers low in dissolved oxygen. Decreasing mass loss rates over time observed in the field experiment are not likely due to first-order deeradation rates, but rather to the persistence of small fractions of BTX mass in anoxic layers. 相似文献
846.
The rate of vertical accretion was determined on two backbarrier marshes in the Mississippi River Plain, using 137Cs dating techniques. An average accretion rate of 0-55 cm yr?1 was found on Grande Terre, and 0.78 cm yr?1 on Grand Isle. Analysis of mineral organic content of the marsh profile shows that the backbarrier marshes accrete through (1) accumulation of low density organic matter, and (2) episodic deposition of high density mineral sediment probably associated with major hurricanes or storm events. The rates of vertical accretion were two to three times less than the rate of submergence due primarily to rapid subsidence in the deltaic plain, and imply that these backbarrier marshes will progressively deteriorate. 相似文献
847.
Michael Patrick Proctor 《GeoJournal》1986,12(2):167-172
Munsieville, one of the Witwatersrand's oldest locations, provides a valuable insight into the forms of control exercised over the urban black population for eight decades. Aspects of this control include restrictions on black movement, on the position and layout of black residential townships, and the taxing of the black population to finance the cost of their control. Resistance by the population to this control has included formal deputations to those in control, wilful contravention of restrictions and violence against symbols of their repression. 相似文献
848.
Hélène Cachier Patrick Buat-Menard Michel Fontugne Jacques Rancher 《Journal of Atmospheric Chemistry》1985,3(4):469-489
Atmospheric aerosol samples were collected in the Ivory Coast, primarily at Lamto (6°N, 5°W) between 1979 and 1981. The samples were analysed for total particulate carbon concentration and isotopic composition (13C/12C) by mass spectrometry. Observed concentrations were found high compared to values reported for temperate regions. Fine particulate carbon in the submicrometersize range accounted for 50 to 80% of the reported concentrations. At Lamto, both particulate carbon concentrations and isotopic ratios exhibit a large temporal variability which is shown to reflect the diversity of sources and their seasonal evolution. Natural emissions from the equatorial forest during the wet season, and biomass burning during the dry season, appear to be the major sources. The latter, though active during only a third of the year, is, on an annual basis, the most important source. Based on the data obtained at Lamto, an attempt has been made to estimate the flux of fine particulate carbon emitted from the tropical regions into the global troposphere. This flux, which is of the order of 20×1012 g C/yr, appears to be equivalent to the flux of fine particulate carbon emitted from industrial sources. These results suggest that the tropospheric burden of fine particulate carbon in lowlatitude regions is dominated by the long-range transport of carbonaceous aerosols originating from the Tropics. 相似文献
849.
Patrick McLaren 《Marine pollution bulletin》1985,16(5):191-196
On 1 March 1984, a spill of diesel fuel and gasoline on the east coast of the Queen Charlotte Islands, Canada, resulted in significant contamination of the beach. Sediment and water samples analysed for oil concentration indicated that oil moved through the beach sediments in response to the tidal cycle and the subsequent changing water table levels. Concentrations tended to be low and variable in samples collected during a flood tide as the oil was driven through the sediments to the upper beach face. On the ebb, however, concentrations increased nearly five times as oil was released from the lowering water table onto the surface of the beach face. At low tide some residual oil remained trapped in the sediments, the amount correlating with the degree of sediment sorting (i.e. sediment porosity). In spite of high wave exposure, traces of fuel remained within 300 m of the spill site after 60 days. This suggests that light, unweathered oil is not mechanically abraded and dispersed in the same manner as more weathered oil; rather the light oil is released from the beach sediments principally during an ebbing tide, and wave action probably affects the cleaning of the beach in a minor capacity. 相似文献
850.
John I. Hedges Gregory L. Cowie John R. Ertel R. James Barbour Patrick G. Hatcher 《Geochimica et cosmochimica acta》1985,49(3):701-711
Spruce, alder, and oak woods deposited in coastal sediments were characterized versus their modern counterparts by quantification of individual neutral sugars and lignin-derived phenols as well as by scanning electron microscopy, 13C NMR, and elemental analysis. The buried spruce wood from a 2500 yr old deposit was unaltered whereas an alder wood from the same horizon and an oak wood from an open ocean sediment were profoundly degraded. Individual sugar and lignin phenol analyses indicate that at least 90 and 98 wt% of the initial total polysaccharides in the buried alder and oak woods, respectively, have been degraded along with 15–25 wt% of the lignin. At least 75% of the degraded biopolymer has been physically lost from these samples. This evidence is supported by the SEM, 13C NMR and elemental analyses, all of which indicate selective loss of the carbohydrate moiety. The following order of stability was observed for the major biochemical constituents of both buried hardwoods: vanillyl and lignin structural units > syringyl lignin structural units > pectin > α-cellulose > hemicellulose. This sequence can be explained by selective preservation of the compound middle lamella regions of the wood cell walls. The magnitude and selectivity of the indicated diagenetic reactions are sufficient to cause major changes in the chemical compositions of wood-rich sedimentary organic mixtures and to provide a potentially large in situ nutrient source. 相似文献