Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Fractal analysis of mingled/mixed magmas: an example from the Upper Pollara eruption (Salina Island, southern Tyrrhenian Sea, Italy)

Upper Pollara eruption products (13 ka, Salina Island, Italy) include both homogeneous and heterogeneous pumices resulting from mixing/mingling processes between an HK andesite and a high-SiO₂ rhyolite. Representative samples of heterogeneous pumices are collected and analyzed in order to check the correspondence between glass composition and morphological features of the mingling/mixing structures. Image analysis techniques are applied and eight grey color ranges (classes) are extracted from high-resolution scans of pumice. Class 1 (lighter colors) and class 8 (darker colors) show end-member glass compositions, i.e. HK andesite and high-SiO₂ rhyolite, respectively. These two classes show spot- to cluster-like morphological structures. Intermediate classes show an HK dacitic to rhyolitic composition and a banding- to fold-like morphology. Fractal analysis by box-counting of the boundary pattern of eight grey classified images is performed over a length scale of 0.028–1.8 cm. Fractal dimension D is between 1.01 and 1.84. Coupled fractal analysis and geochemical data reveal that D increases as the degree of magma interaction (homogenization) increases. This feature well fits the results from numerical models on the convective mixing of fluids driven by thermal convection. We conclude that the increase of D observed in the Upper Pollara samples reflects the transition from fractal mixing to homogenization. End-member magmas (HK andesite and high-SiO₂ rhyolite) represent isolated mixing regions, while homogenized magmas represent active mixing regions. In the analyzed pumices, isolated and active mixing regions coexist at scales between 10⁻⁴ and 10⁻² m. Morphological and compositional features of the Upper Pollara pumices result from turbulence.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

断裂构造的遥感研究方法综述

断裂构造是一种基本的构造型式。断裂构造遥感研究是高新探测技术与地球科学的有机结合 ,是断裂构造常规研究方法的有益补充和向纵深拓展的必然趋势。该文从总体思路、具体内容、操作方法等各个不同角度系统地论述了断裂构造遥感研究的现状和发展趋势 ,并在断裂构造信息提取、光谱特征分析、空间结构分析 (包括分形分析 )等方面提出了一些观点。     

New unspiked K–Ar ages of volcanic rocks of the central and western sector of the Aeolian Islands: reconstruction of the volcanic stages

A geochronological study of the Filicudi, Salina, Lipari and Vulcano Islands (Aeolian Archipelago) using the unspiked potassium–argon technique provides new age data which, combined with stratigraphic correlation, better constrain the temporal evolution of volcanism. The unspiked K–Ar age of the oldest exposed lavas on Filicudi, 219±5 ka, is significantly younger than the previous estimation of 1.02 Ma. In the general context of Aeolian volcanism, this new date suggests that the volcanism of the western sector of the Aeolian Archipelago is younger than previously thought. Geochronological data point out on the rapid transition from calc–alkaline to potassic volcanism. The distribution of the K–Ar ages within the Salina–Lipari–Vulcano group shows that the volcanism started on Lipari and propagated over time northward on Salina and southward on Vulcano. Geochronological and geophysical data suggest that the onset of volcanism in the central sector of the Aeolian Arc may be due to a mantle upwelling structure located below Lipari. A change in the style of the eruptions occurred in the Salina–Lipari–Vulcano system at about 100 ka from the present. Low-energy magmatic eruptions occurred between 188 and about 100 ka. From about 100 ka to the present, higher-energy eruptions and low-energy events due to magma–water interaction also occurred. This change in the style of activity, together with the appearance of evolved products (i.e. rhyolites) during the last 50 ka, is consistent with the formation of magmatic reservoirs located at shallower depth with respect to those of the 188–100-ka period. The new geochronological data and available petrological models reveal that a change in the deep source of the primary magmas occurred in a relatively short time interval.     

Physical model for dynamic analysis of structures with FPS isolators

This article presents a physical model for frictional pendulum isolators (FPS) that is ready to be implemented in most commercial software. The model is capable of accounting for effects such as large deformations, sticking, and uplift and impact by sensing the normal loads in the isolators through a gap element. Sticking has been incorporated into the model by extending the Park–Wen hysteretic model to the case of large deformations. The proposed model has been tested against a theoretically ‘exact’ formulation leading to essentially identical results. To facilitate its use, the physical FPS model has been cast into a typical non‐linear structural element format, i.e. with deformation as input and restoring force as output. Examples of a building and a bridge have been chosen to show the potential of the element and to provide further insight into the earthquake response of structures with FPS isolators; in particular, in aspects such as the orientation in placement of the isolator, sticking, P? Δ, and other large deformation effects. Copyright © 2003 John Wiley & Sons, Ltd.     

Field Survey and Numerical Simulations: A Review of the 1998 Papua New Guinea Tsunami

— The Papua New Guinea (PNG) tsunami of 1998 is re-examined through a detailed review of the field survey as well as numerous numerical computations. The discussion of the field survey explores a number of possible misinterpretations of the recorded data. The survey data are then employed by a numerical model as a validation tool. A Boussinesq model and a nonlinear shallow water wave (NLSW) model are compared in order to quantify the effect of frequency dispersion on the landslide-generated tsunami. The numerical comparisons indicate that the NLSW model is a poor estimator of offshore wave heights. However, due to what appears to be depth-limited breaking seaward of Sissano spit, both numerical models are in agreement in the prediction of maximum water elevations at the overtopped spit. By comparing three different hot-start initial profiles of the tsunami wave, it is shown that the initial shape and orientation of the tsunami wave is secondary to the initial displaced water mass in regard to prediction of water elevations on the spit. These numerical results indicate that agreement between numerical prediction of runup values with field recorded values at PNG cannot be used to validate either a NLSW tsunami propagation model or a specific landslide tsunami hot-start initial condition. Finally, with the use of traditional tsunami codes, a new interpretation of the PNG runup measurements is presented.     

喜马拉雅造山带中段定结地区拆离断层

定结地区位于喜马拉雅造山带中段,发育大量的低角度伸展拆离断层,这些拆离断层中部分构成了藏南拆离系的主体。它们基本上垂直于造山带走向伸展,各拆离断层特征显著,普遍发育糜棱岩,糜棱岩类型复杂,主要有硅质糜棱岩、长英质糜棱岩、花岗质糜棱岩。在研究区的北部,拆离断层呈环状产出,构成变质核杂岩三层结构中的中间层,规模一般较大;同时拆离断层使变质核杂岩体盖层中的部分地层拆离减薄;在研究区南部拆离断层呈线状延伸很远,总体上平行造山带延伸,构成了藏南拆离系重要组成部分。部分拆离断层同韧性剪切带平行产出,形成拆离剪切的脆韧性体系。     

吐哈盆地中央构造带正反转演化特征

吐哈盆地中央构造带由火焰山构造和七克台构造组成。中央构造带形成于三叠纪晚期至侏罗纪早期,表现为伸展构造特征,生长断层上盘地层厚度明显大于下盘,并于断层上盘所在的台北凹陷形成沉降中心。晚侏罗世,由于拉萨陆块与欧亚大陆的碰撞作用导致吐哈盆地由伸展盆地转变为挤压盆地,中央构造带也于此时发生构造反转,由早期的伸展正断层转变为挤压逆断层。发生于55Ma的喜山构造事件对天山地区产生了深刻的影响,但影响时间略有滞后,大致发生在晚渐新世至早中新世,中央构造带即在此次构造事件中强烈变形,逆冲出露于地表。     

基于虚拟监控技术的机器人系统

介绍了一种虚拟现实技术(VR)与智能机器人监控技术协同作业的机器人系统，该系统使用虚拟现实技术建造具有良好交互性的人机界面，并且结合智能机器人监控技术，实现了虚拟监控操作。通过机器人系统，将虚拟操作结果作为一个整体对象投射到工作现场，完成了实际作业，并以水下机器人检查钻井平台水下部分的焊缝工作为背景，说明了本系统各种功能的实现过程。