Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.     

Apophis: the Story Behind the Scenes

On December 20, 2004 the Minor Planet Center issued the Minor Planet Electronic Circular (MPEC) 2004-Y25 announcing the discovery of a new Near Earth Asteroid (NEA) with designation 2004 MN₄. Only two days later, when the Christmas holidays were about to begin, it was already apparent that this asteroid, currently known as Apophis, would be notorious: our close-approach monitoring system, CLOMON2, was already showing a Virtual Impactor (VI) in 2029 reaching the level 2 in the Torino Scale, the first asteroid to reach that level since our monitoring system had been operational. However, this was just the beginning of what it was to come in the subsequent days. In this paper we will give an overview of the NEODyS-CLOMON2 system and provide the details on how Apophis’ collision scenario evolved, the way NEODyS’ team handled it and the crazy 2004’ Christmas holidays we had due to this unexpected guest.     

A summary of sulfur dioxide emission rate measuremnts from Guatemalan volcanoes

Measurements of the sulfur dioxide (SO₂) emission rate from three Guatemalan volcanoes provide data which are consistent with theoretical and laboratory studies of eruptive and shallow magma chamber processes. In particular, unerupted magma makes a major contribution to the measured SO₂ emission rates at Santiaguito, a continuously erupting dacitic volcanic dome. Varying shallow magma convection rates can explain the variations in SO₂ emission rates at Santiaguito. At Fuego, a basaltic volcano currently in repose, SO₂ emission rate measurements are consistent with a high level magma body that is crystallizing and releasing volatiles. At Pacaya, a continuously erupting basaltic volcano, recent SO₂ emission rate measurements support laboratory simulation studies of strombolian eruptions; these studies indicate that the majority of gas escapes during eruptions and little gas escapes between eruptions.Average SO₂ emission rates over the last 20 years for Santiaguito, Fuego and Pacaya are 80, 160 and 260 Mg/d, respectively. On a global scale, these three volcanoes account for 1% of the annual global volcanic output of SO₂. Santiaguito and Pacaya, together, emit 6% of the total annual SO₂ emitted by continuously erupting volcanoes.Even though SO₂ measurements at these volcanoes have been made infrequently and by different investigators, the collective data help to establish a useful baseline by which to judge future changes. A more complete record of SO₂ emission rates from these volcanoes could lead to a better understanding of their eruption mechanisms and reduce the impact of their future eruptions on Guatemalan society.     

Study of Metal Distribution in Raw and Screened Swine Manure

The growth of industrial swine production over the last few years has led to a growth in concern over effluents generated by the activity. Several elements, mainly toxic metals, can be present in swine wastewater and can have a serious environmental impact. It is important, therefore, to know the metal concentration before the discharge of wastewater. In this work the temporal metal distribution in swine manure and its potential reduction using coarse (2 mm) and fine (<0.45 μm) liquid‐solid separation techniques were investigated. In order to do this, different swine manure sample preparation methods for Al, Ba, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr and Zn determination by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were tested. The acid mixtures used to digest the manure sample significantly affected the metal recovery. Good analyte recoveries were observed with nitric acid/hydrogen peroxide mixtures or nitric acid/perchloric acid mixtures. Sulfuric acid/hydrogen peroxide mixtures produced inconsistent results and poor recoveries, mainly for Ba and Pb. It was observed that metal concentrations in swine manure varied greatly with time, up to one order of magnitude, due to changes in swine production such as feed and animal numbers. Metals concentrations observed in the raw wastewater exceeded Brazilian limits for discharge into water bodies and recommendations for agricultural use. Results obtained from the liquid‐solid separation study showed that metals in the raw swine manure were not removed with coarse screening. However, the major fraction of metals were removed by filtration (0.45 μm), with the exception of Na, K and Sr. Thus, the use of liquid‐solid separation techniques that capture the fine solid fractions (and associated metals) from raw manure can have a favorable impact on the environment and contribute to swine production wastewater treatment.     

The reconstruction of a glacial lake outburst flood using HEC-RAS and its significance for future hazard assessments: an example from Lake 513 in the Cordillera Blanca,Peru

In April 2010, an ice/rockfall into Lake 513 triggered a glacial lake outburst flood (GLOF) along the Chucchun River in the Cordillera Blanca of Peru. This paper reconstructs the hydrological characteristics of this as yet undocumented event using a 1D flood model prepared with HEC-RAS. The principle model inputs were obtained during detailed field surveys of surface characteristics and topography within the river and across the adjacent floodplain; a total of 120 cross-sections were surveyed. These inputs were refined further by eyewitness accounts and additional geomorphological observations. The flood modelling has enabled us to constrain the extent of the water surface and its elevation at each cross-section in addition to defining the peak discharge (580 m³ s^?1). These modelling results show good agreement with other information about the flood including: flood marks and minimum flood levels; the lake displacement wave height; the extent of the flooded area; and the travel time from Lake 513 to the confluence with the Santa River. This demonstrates that the model offers a reliable reconstruction of the basic hydrological characteristics of the GLOF. It provides important information about the flood intensity and significantly improves our ability to model future flood scenarios along both the studied river and within neighbouring catchments. The flood hazard, defined by the flood depth during peak discharge, shows that the majority of the damaged infrastructure (houses, bridges, and a drinking water treatment plant) was only subjected to low or medium flood intensities (defined by a maximum water depth of less than 2 m). These low flood intensities help to explain why the flooding caused comparatively minor damage despite the significant public attention it attracted.     

Precision A.C. bridge set for measuring magnetic susceptibility of rocks and its anisotropy

Summary A bridge set for measuring the magnetic susceptibility of rocks and its anisotropy is described. The classical transformer bridge has been supplemented with an auxiliary compensating arm for balancing the bridge without any mechanical infringement of the measuring coils. By employing this principle and the appropriate methods a sensitivityof 4 × 10 ^–8 SI units (3 × 10 ^–9 e.m.u./cm³) has been achieved for a sample of 8 cm³ in volume. In addition to its high sensitivity the device has a considerable accuracy, which makes it suitable for susceptibility anisotropy measurements even of samples with a very low susceptibility and only slight anisotropy. Well-reproducible results have been achieved for samples with a mean susceptibility of the order of10 ^–5 SI units with an anisotropy degree of only about 1.05.Institute of Applied Geophysics.     

Changes in phytoplankton production and upwelling intensity off A Coruña (NW Spain) for the last 28 years

Ocean Dynamics - The analysis of a 28-year-long (1989–2016) series of monthly measurements of chlorophyll concentrations and primary production rates at a shelf station off A Coruña (NW...     

Behaviour of the SMF method for the numerical integration of satellite orbits

The SMF algorithms were recently developed by the authors as a multistep generalization of the ScheifeleG-functions one-step method. Like the last, the proposed codes integrate harmonic oscillations without truncation error and the perturbing parameter appears as a factor of that error when integrating perturbed oscillations. Therefore they seemed to be convenient for the accurate integration of orbital problems after the application of linearizing transformations, such as KS or BF. In this paper we present several numerical experiments concerning the propagation of Earth satellite orbits, that illustrate the performance of the the SMF method. In general, it provides greater accuracy than the usual standard algorithms for similar computational cost.     

Precursory seismicity of the 1994 eruption of Popocatépetl Volcano,Central Mexico

Popocatépetl Volcano is located in the central Mexican Volcanic Belt, within a densely populated region inhabited by over 20 million people. The eruptive history of this volcano indicates that it is capable of producing a wide range of eruptions, including Plinian events. After nearly 70 years of quiescence, Popocatépetl reawakened in December 21, 1994. The eruptive activity has continued up until the date of this submission and has been characterized by a succession of lava dome growth-and-destruction episodes, similar to events that have apparently been typical for Popocatépetl since the fourteenth century. In this regime, the episodes of effusive and moderately explosive activity alternate with long periods of almost total quiescence. In this paper we analyze five years of volcano-tectonic seismicity preceding the initial eruption of the current episode. The evolution of the V-T seismicity shows four distinct stages, which we interpret in terms of the internal processes which precede an eruption after a long period of quiescence. The thermal effects of a magma intrusion at depth, the fracturing related to the slow development of magma-related fluid pathways, the concentration of stress causing a protracted acceleration of this process, and a final relaxation or redistribution of the stress shortly before the initial eruption are reflected in the rates of V-T seismic energy release. A hindsight analysis of this activity shows that the acceleration of the seismicity in the third stage asymptotically forecast the time of the eruption. The total seismic energy release needed to produce an eruption after a long period of quiescence is related to the volume of rock that must be fractured so imposing a characteristic threshold limit for polygenetic volcanoes, limit that was reached by Popocatépetl before the eruption.