The kinetics of iodide oxidation by the manganese oxide mineral birnessite

The kinetics of iodide (I⁻) and molecular iodine (I₂) oxidation by the manganese oxide mineral birnessite (δ-MnO₂) was investigated over the pH range 4.5-6.25. I⁻ oxidation to iodate proceeded as a two-step reaction through an I₂ intermediate. The rate of the reaction varied with both pH and birnessite concentration, with faster oxidation occurring at lower pH and higher birnessite concentration. The disappearance of I⁻ from solution was first order with respect to I⁻ concentration, pH, and birnessite concentration, such that −d[I⁻]/dt = k[I⁻][H⁺][MnO₂], where k, the third order rate constant, is equal to 1.08 ± 0.06 × 10⁷ M⁻² h⁻¹. The data are consistent with the formation of an inner sphere I⁻ surface complex as the first step of the reaction, and the adsorption of I⁻ exhibited significant pH dependence. Both I₂, and to a lesser extent, sorbed to birnessite. The results indicate that iodine transport in mildly acidic groundwater systems may not be conservative. Because of the higher adsorption of the oxidized I species I₂ and , as well as the biophilic nature of I₂, redox transformations of iodine must be taken into account when predicting I transport in aquifers and watersheds.     

The coating hypothesis for ammonia ice particles in Jupiter: Laboratory experiments and optical modeling

We report laboratory experiments and modeling calculations investigating the effect of a hydrocarbon coating on ammonia ice spectral signatures. Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in areas of strong vertical transport, indicating a short lifetime for the signature of ammonia absorption on condensed ammonia particles [Baines, K.H., Carlson, R.W., Kamp, L.W., 2002. Icarus 159, 74-94]. Current literature has suggested coating of ammonia ice particles by a hydrocarbon haze as a possible explanation for this paradox. The work presented here supports the inference of a coating effect that can alter or suppress ammonia absorption features. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by reflection-absorption infrared spectroscopy. We have observed the effects on the ammonia ice absorption features near 3 and 9 μm with coverage by thin layers of hydrocarbons. Modeling calculations of these multilayer thin films assist in the interpretation of the experimental results and reveal the important role of optical interference in altering the aforementioned ammonia spectral features. Mie and T-matrix scattering calculations demonstrate analogous effects for ammonia ice particles and investigate the relative effects of ammonia ice particle size, shape, and coating layer thickness on the ice particle spectral signatures.     

Geomasking sensitive health data and privacy protection: an evaluation using an E911 database

Geomasking is used to provide privacy protection for individual address information while maintaining spatial resolution for mapping purposes. Donut geomasking and other random perturbation geomasking algorithms rely on the assumption of a homogeneously distributed population to calculate displacement distances, leading to possible under-protection of individuals when this condition is not met. Using household data from 2007, we evaluated the performance of donut geomasking in Orange County, North Carolina. We calculated the estimated k-anonymity for every household based on the assumption of uniform household distribution. We then determined the actual k-anonymity by revealing household locations contained in the county E911 database. Census block groups in mixed-use areas with high population distribution heterogeneity were the most likely to have privacy protection below selected criteria. For heterogeneous populations, we suggest tripling the minimum displacement area in the donut to protect privacy with a less than 1% error rate.     

Coda Q before and after the eruptions of 13 November 1985, and 1 September 1989, at Nevado del Ruiz Volcano, Colombia

 Coda Q^–1 was calculated at Nevado del Ruiz Volcano (NRV) before and after two phreatomagmatic eruptions (November 1985, September 1989) and for a period of stability (May 1987) using a functional form for coda derived from a single scattering model (Sato 1977). Substantial changes were found before and after the eruptions. The highest value of Q^–1 was found during the November 1985 eruption, an intermediate value for the September 1989 eruption, and the lowest value for May 1987. It seems that the changes in coda Q^–1 at NRV have a still-unknown relationship with the volume or magnitude of the eruption. A relatively strong frequency dependence was found for all periods. Also Q^–1 clearly changed with time, suggesting that the scattering was strong for the eruption of November 1985 and decreased for the eruption of September 1989, and that the intrinsic absorption probably increased. This suggests the possibility that crystallization is taking place in the NRV magma. The clear change of coda Q^–1 before and after the eruptions at NRV also suggests the possibility that coda Q^–1 is a premonitory tool of activity at this volcano. Received: 25 October 1996 / Accepted: 21 January 1998     

MODAL ANALYSIS OF AIRPHOTO LINEARS,CENTRAL IDAHO

Approximately 3,000 airphoto linears from an 8,300 km² area of central Idaho are plotted, classified for azimuthal orientation, counted for frequency, and measured for length. Dominant linear orientations, weighted for length, are compared to equivalent central tendency measures for joints, dikes, and foliation. Variations in linear density are also compared to differing lithologies. Statistical analysis reveals the following: (1) the dominant lineation mode is statistically independent of the dominant foliation mode; (2) no statistically significant difference exists between the dominant lineation mode and the average directional mode of dikes; (3) no statistically significant difference exists between the dominant lineation mode and the average directional mode of joints; (4) linear frequency is statistically independent of lithology. Visual comparison of raised relief maps with the isopleth map of directionally dominant linears reveals a pronounced correspondence between those areas exhibiting strong structural control over landforms and highs on the isopleth surface.     

Molluscs as multidisciplinary models in environment toxicology

The primary goal of this paper is to stimulate discussion and promote the use of mollusc models and multidisciplinary research approaches in the field of environmental toxicology. Molluscs are effective models because they are ubiquitous, have highly conserved control and regulatory pathways that are often homologous to vertebrate systems, and are extremely sensitive to anthropogenic inputs. We have attempted to provide initial references as an avenue into the literature and as a means for researchers to expand their thoughts to regions outside of their own area of expertise. The authors are particularly interested in developing multidisciplinary international collaborative efforts.     

Topographically moderated soil water seasons impact vegetation dynamics in semiarid mountain catchments: Illustrations from the Dry Creek Experimental Watershed,Idaho, USA

Water stored in soils, in part, controls vegetation productivity and the duration of growing seasons in wildland ecosystems. Soil water is the dynamic product of precipitation, evapotranspiration and soil properties, all of which vary across complex terrain making it challenging to decipher the specific controls that soil water has on growing season dynamics. We assess how soil water use by plants varies across elevations and aspects in the Dry Creek Experimental Watershed in southwest Idaho, USA, a mountainous, semiarid catchment that spans low elevation rain to high elevation snow regimes. We compare trends in soil water and soil temperature with corresponding trends in insolation, precipitation and vegetation productivity, and we observe trends in the timing, rate and duration of soil water extraction by plants across ranges in elevation and aspect. The initiation of growth-supporting conditions, indicated by soil warming, occurs 58 days earlier at lower, compared with higher, elevations. However, growth-supporting conditions also end earlier at lower elevations due to the onset of soil water depletion 29 days earlier than at higher elevations. A corresponding shift in peak NDVI timing occurs 61 days earlier at lower elevations. Differences in timing also occur with aspect, with most threshold timings varying by 14–30 days for paired north- and south-facing sites at similar elevations. While net primary productivity nearly doubles at higher elevations, the duration of the warm-wet period of active water use does not vary systematically with elevation. Instead, the greater ecosystem productivity is related to increased soil water storage capacity, which supports faster soil water use and growth rates near the summer solstice and peak insolation. Larger soil water storage does not appear to extend the duration of the growing season, but rather supports higher growing season intensity when wet-warm soil conditions align with high insolation. These observations highlight the influence of soil water storage capacity in dictating ecological function in these semiarid steppe climatic regimes.     

Comparing generalized Pareto models fitted to extreme observations: an application to the largest temperatures in Spain

In this paper, a subsampling-based testing procedure for the comparison of the exceedance distributions of stationary time series is introduced. The proposed testing procedure has a number of advantages including the fact that the assumption of stationary can be relaxed for some specific forms of non-stationary and also that the two time series are not required to be independently-generated. For this purpose, a test based on the Kolmogorov–Smirnov and the L ₁-Wasserstein distances between generalized Pareto distributions is introduced and studied in some detail. The performance of the testing procedure is illustrated through a simulation study and with an empirical application to a set of data concerning daily maximum temperature in the 17 autonomous communities of Spain for the period 1990–2004. The autonomous communities were clustered according to the similarities of the fitted generalized Pareto models and then mapped. The cluster analysis reveals a clear distinction between the four northeast communities on the shores of the Bay of Biscay (which are the regions exhibiting milder temperatures) and the remaining regions. A second cluster corresponds to the southern Mediterranean area and the central region which corresponds to the communities with highest temperatures.