Dissolution of well and poorly ordered kaolinites by an aerobic bacterium

Previous research by our group (e.g., [Chem. Geol. 132 (1996) 25; Geochim. Cosmochim. Acta 64 (2000) 1363]) has shown that an aerobic Pseudomonas mendocina bacterium enhances Fe(hydr)oxide dissolution in order to obtain Fe under Fe-limited conditions. The P. mendocina is incapable of utilizing Fe as a terminal electron acceptor and requires several orders of magnitude lower Fe concentrations than do dissimilatory Fe reducing bacteria. The research reported here compared the effects of the P. mendocina on dissolution of well and poorly ordered Clay Minerals Society Source Clay kaolinites KGa-1b and KGa-2, respectively, under Fe-limited conditions. KGa-1b and KGa-2 contain 0.04 and 0.94 bulk wt.% Fe, respectively, and their surface Fe/Si atomic RATIOS=0.008 and 0.012. Following strong cleaning of the kaolinites in 5.8 M HCl at 85 °C, the surface Fe/Si atomic ratios decreased to 0.004 and 0.008, respectively. Both kaolinites also developed a Si-enriched surface precipitate upon strong cleaning.

Because the P. mendocina take up Fe, we could not measure Fe release from the kaolinite directly, but rather had to monitor it indirectly by comparing microbial populations sizes under Fe-limited growth conditions. We found that microbial growth on uncleaned, weakly cleaned, and strongly cleaned kaolinites increased with the amount of Fe readily available to organic ligands as estimated by dissolution in 0.001 M oxalate (pH 3). This suggests that it is the amount of readily accessible Fe that controls Fe acquisition and hence microbial growth. The trend is based on only a relatively small range of kaolinite Fe contents, and the research thus needs to be expanded to include kaolinites with a broader range of bulk and surface Fe concentrations.

Significant enhancement of Al release was observed in the presence of the bacteria, along with generally some enhancement of Si release. This enhancement of kaolinite dissolution could be related to an observed pH increase from 7–8 to 9 in the presence of the bacteria and/or to production of Al chelating agents. The P. mendocina produce a variety of organic exudates, including siderophores [Chem. Geol. 132 (1996) 25; Geomicrobiology (2001b)], and further studies into the effects of the siderophores on Al complexation and on kaolinite dissolution are ongoing.     

Late Quaternary Vegetation and Climate of the Wind River Range, Wyoming

Sediments from Rapid Lake document glacial and vegetation history in the Temple Lake valley of the Wind River Range, Wyoming over the past 11,000 to 12,000 yr. Radiocarbon age determinations on basal detrital organic matter from Rapid Lake (11,770 ± 710 yr B.P.) and Temple Lake (11,400 ± 630 yr B.P.) bracket the age of the Temple Lake moraine, suggesting that the moraine formed in the late Pleistocene. This terminal Pleistocene readvance may be represented at lower elevations by the expansion of forest into intermontane basins 12,000 to 10,000 yr B.P. Vegetation in the Wind River Range responded to changing environmental conditions at the end of the Pleistocene. Following deglaciation, alpine tundra in the Temple Lake valley was replaced by a Pinus albicaulis parkland by about 11,300 ¹⁴C yr B.P. Picea and Abies, established by 10,600 14C yr B.P., grew with Pinus albicaulis in a mixed conifer forest at and up to 100 m above Rapid Lake for most of the Holocene. Middle Holocene summer temperatures were about 1.5°C warmer than today. By about 5400 ¹⁴C yr B.P. Pinus albicaulis and Abies became less prominent at upper treeline because of decreased winter snowpack and higher maximum summer temperatures. The position of the modern treeline was established by 3000 ¹⁴ C yr B.P. when Picea retreated downslope in response to Neoglacial cooling.     

Lateral heterogeneities in the upper and mid-mantle conductivity in Argentina

Regional studies of Sq variations measured at five permanent observatories in Argentina were performed to estimate the distribution of the electrical conductivity of the upper and mid-mantle, reaching a depth of approximately 800 km. After separating the total field into its parts of external and internal origin, the in duced field was modeled, applying two-dimensional techniques. Additionally, induction arrows and an equivalent apparent resistivity curve were calculated A north-south heterogeneity was detected, showing an increase of the conductivity of the shallower layers north of the profile, which may be related to the presence of high volcanic activity in the area.Also at CONICET (Consejo Nacional de Investigaciones Científicas y Técnicas).     

SHRINKING HOUSEHOLD SIZE AND ITS EFFECT ON URBAN POPULATION DENSITY PATTERNS: A CASE STUDY OF PHOENIX,ARIZONA

Increased divorce, declining fertility and mortality, and changing lifestyles have resulted in a consistent decline in average household size in U.S. urban areas. The purpose of this paper is to show that decreases in household size between 1970 and 1975 were spatially variable in metropolitan Phoenix and that this affected the overall pattern of residential density. This is demonstrated by a series of maps depicting average household size in 1970, changes therein between 1970 and 1975, and the relationships between changes in population, numbers of dwelling units, and household size in the study area.     

System identification of a concrete arch dam and calibration of its finite element model

A magnitude 4.3 earthquake occurred near Pacoima Dam on 13 January 2001. An accelerometer array that had been upgraded after the Northridge earthquake recorded the motion with 17 channels on the dam and the dam–foundation interface. Using this data, properties of the first two modes are found from a system identification study. Modal properties are also determined from a forced vibration experiment performed in 2002 and indicate a significantly stiffer system than is estimated from the 2001 earthquake records. The 2001 earthquake, although small, must have induced temporary nonlinearity. This has implications for structural health monitoring. The source of the nonlinear behaviour is believed to be loss of stiffness in the foundation rock. A finite element model of Pacoima Dam is constructed and calibrated to match modal properties determined from the system identification study. A dynamic simulation of the 2001 earthquake response produces computed motions that agree fairly well with the recorded ones. Copyright © 2006 John Wiley & Sons, Ltd.     

Coupled thermal, hydraulic and geochemical evolution of pyritic tailings in unsaturated column experiments

The evolution of pore-water and the composition of solid phases in the vadose zone of pyritic tailings was studied by means of unsaturated column experiments. Several columns of water-saturated mine tailings were dried during 125 days under controlled laboratory conditions. The columns were dismantled at four successive drying stages and the evolution of pore-water, mineralogy, water content and temperature was characterized.Sulfide and aluminosilicate minerals present in the waste dissolved, releasing sulfate and other solutes (mainly Fe, Zn, Cu, Al, Mg and Ca) to the pore-water. Evaporation caused a crust of efflorescent, water-soluble sulfates to develop over the complete top surface of the columns and into the pores of the underlying waste material. This crust, which has also been identified in the field, changed the hydraulic properties of the tailings and produced a decrease in the evaporation rate of the columns. Moreover, these water-soluble precipitates (mainly rozenite, szomolnokite, halotrichite, hexahydrite, mirabilite and gypsum) acted as temporary sinks for Cd, Pb, Co and Ni, which could be released to the surface run-off or the groundwaters during rainfall events under field conditions.Pore-water evolution was determined not only by geochemical processes (dissolution of sulfides and aluminosilicates, precipitation of secondary phases) but also by thermal and hydraulic processes. Progressive dilution was observed in the lower part of the columns. Dilution was caused by the thermally driven vapor flux from the top of the column to its colder bottom and subsequent condensation therein. This process, which may also occur in tailings under sub-arid climate, played a key role on the evolution of pore-water with increasing drying.     

Crustal attenuation in the Southern Andean retroarc (38°–39°30′ S) determined from tectonic and gravimetric studies: The Lonco-Luán asthenospheric anomaly

The western retroarc of the Southern Andes between 38° and 40° S is formed by a NNW-elongated ridge not associated with stacked thrust sheets. On the contrary, during the last 4–3 Ma this ridge was affected by extensional deformation, regional uplift and related folding on a very broad scale. Receiver function analysis shows that the drainage divide area and adjacent retroarc lie over an attenuated crust. Expected crustal thickness at these latitudes is around 38 km, whereas in this part of the retroarc the thickness is less than 32 km. The causes for such attenuation have been linked to a moderate steepening of the subducted Nazca plate beneath the South American plate, which is suggested by a westward shift and narrowing of the magmatic arc during the last 4 to 5 Ma. Gravimetric studies show that the upper plate did not react homogeneously to slab steepening, but ancient sutures and lithospheric discontinuities deeply buried under Mesozoic to Cenozoic sequences in the retroarc were locally reactivated. These processes resulted in an asthenospheric anomaly that correlates at the surface with the area of Pliocene to Quaternary doming, widespread extension and three radial troughs. Two of the troughs have accommodated substantial amounts of extension, but the third was probably aborted at an early stage. Moreover, the presence of an anomalous concentration of calderas and large volcanic centers over the proposed asthenospheric anomaly, and their age distribution, may indicate minor migration of the asthenospheric anomaly between 4 and 2 Ma through the western South American plate.     

Separation of local and regional information in distorted GDS response functions by hypothetical event analysis

Electromagnetic investigations are usually intended to examine regional structures where induction takes place at a given period range. However, the regional information is often distorted by galvanic effects at local conductivity boundaries. Bahr (1985) and Groom & Bailey (1989) developed a physical distortion model for decomposing the MT impedance tensor, based upon local galvanic distortion of a regional 2-D electromagnetic field. We have extended their method to predict the magnetic variation fields created at an array of sites. The magnetic response functions at periods around 1000 s may be distorted by large-scale inhomogeneities in the upper or middle crust. In this period range, the data measured by a magnetometer array contain common information that can be extracted if the data set is treated as a unit, for example by using hypothetical event analysis. With this technique it is always possible to recover the regional strike direction from distorted data, even if a strong, spatially varying regional vertical field component is present in the data set. The determination of the regional impedance phases, on the other hand, is far more sensitive to deviations from the physical distortion model.
The approach has been used to investigate the Iapetus data set. For the array, which covers an area of 200  km × 300  km in northern England/southern Scotland, the technique revealed a common regional strike azimuth of ca . N125° E in the period range 500–2000  s. This direction differs from the strike indicated by the induction arrows, which seem influenced mainly by local current concentrations along the east–west-striking Northumberland Trough and a NE–SW-striking mid-crustal conductor. Both impedance phases are positive and differ by ca . 10°, which supports the assumptions of distortion fields in the data set and that the regional structure is 2-D.     

Petrological And Geochemical Characteristics Of The Granulitic Terrain Of Brejses, Bahia, Brazil

New petrological and geochemical characteristics of the Brejtes region, situated in the south of Bahia, Brazil are discussed. The region forms a part of the most important and extensive granulite facies terrain in Brazil of Archean/Paleoproterozoic age. Five groups of rock types all equilibrated in the granulite facies are identified in this region. They are: i) supracrustal and related rocks, ii) undifferentiated granulites, iii) hornblende bearing enderbite-charnockites, iv) hornblende free enderbite-charnockites, v) charnockites. The first group appears to be the oldest in the region as they form enclaves in the 2.9 Ga old undifferentiated granulites. The third and fourth group are enderbite-charnockites, whose protoliths constitute two series of calc-alkaline rocks, one titanium poor (hornblende free) and another titanium rich (hornblende bearing). U/Pb zircon SHRIMP dates indicate ages of formation at 2.81 Ga (hornblende free) and 2.69 Ga (hornblende bearing) for the two groups. The fifth group of rocks have charnockitic affinity and are present in the center of the Brejtes Dome. These rocks are also have calc-alkaline affinity, but show petrographic and geochemical characteristics distinct from those of other groups. Preliminary geochronological investigations by zircon Pb-Pb evaporation method yielded 2.6 Ga and 2.0 Ga for the charnockites from the inner core of the Brejtes Dome. These age data suggest that the circular structure was formed by the re-fusion of the 2.6 Ga old deep crustal material generating younger charnockites at 2.0 Ga.