Measurement of soluble reactive phosphorus concentration profiles and fluxes in river-bed sediments using DET gel probes

DET (diffusive equilibrium in thin films) gel probes were used for sampling river-bed sediment porewaters, to characterise in situ soluble reactive phosphorus (SRP) concentration profiles and fluxes. DET probes were deployed in three contrasting rural streams: (1) a headwater ‘pristine’ stream, with minimal P inputs from low intensity grassland and no point sources, (2) an intensively cultivated arable catchment, and (3) a stream subject to high P loadings from sewage effluent and intensive arable farming. The DET results showed highly enriched porewater SRP concentrations of between ca. 400 and 5000 μg-P l⁻¹ in the sewage-impacted stream. In contrast, the arable and pristine streams had porewater SRP concentrations <70 μg-P l⁻¹ and <20 μg-P l⁻¹, respectively. Porewater SRP concentration profiles in both the sewage-impacted and arable-impacted streams showed well-defined vertical structure, indicating internal sources and sinks of SRP within the sediment. However, there was little variability in porewater SRP concentrations in the pristine stream. The DET porewater profiles indicated net diffusion of SRP (a) from the overlying river water into the surface sediment and (b) from subsurface sediment upwards towards the sediment–water interface. A mass balance for the sewage-impacted site showed that the influx of SRP into the surface sediments from the overlying river water was small (ca. 1% of the daily river SRP load). The DET results indicated that, in the arable and sewage-impacted streams, the surface ‘cap’ of fine sediment may play an important role in inhibiting upward movement of SRP from subsurface porewaters into the overlying river water, under steady-state, low-flow conditions.     

The Landscape of Diversity in U.S. Higher Education Geography

Palynological analyses were completed for the A and B horizons of a forested Mollic Hapludalf to determine type, amount, and distribution of pollen and spores within the soil solum. Hypotheses regarding the origin of pollen and the mechanisms of its movement within soil bodies are also advanced. Pollen downwash within the mineral soil seems to be very slow and confined to the uppermost porous and most homogenized part of the solum. The predominance of non-arboreal pollen at depth was believed to be a result of deposition with the loess parent material. High arboreal pollen frequencies in the upper horizons coupled with increases in non-arboreal types at depth indicate gradual ongoing mixing from the present vegetation into the soil.     

The formation and survival of discs in a ΛCDM universe

We study the formation of galaxies in a Λ cold dark matter (ΛCDM) universe using high-resolution hydrodynamical simulations with a multiphase treatment of gas, cooling and feedback, focusing on the formation of discs. Our simulations follow eight isolated haloes similar in mass to the Milky Way and extracted from a large cosmological simulation without restriction on spin parameter or merger history. This allows us to investigate how the final properties of the simulated galaxies correlate with the formation histories of their haloes. We find that, at   z = 0  , none of our galaxies contains a disc with more than 20 per cent of its total stellar mass. Four of the eight galaxies nevertheless have well-formed disc components, three have dominant spheroids and very small discs, and one is a spheroidal galaxy with no disc at all. The   z = 0  spheroids are made of old stars, while discs are younger and formed from the inside-out. Neither the existence of a disc at   z = 0  nor the final disc-to-total mass ratio seems to depend on the spin parameter of the halo. Discs are formed in haloes with spin parameters as low as 0.01 and as high as 0.05; galaxies with little or no disc component span the same range in spin parameter. Except for one of the simulated galaxies, all have significant discs at   z ≳ 2  , regardless of their   z = 0  morphologies. Major mergers and instabilities which arise when accreting cold gas is misaligned with the stellar disc trigger a transfer of mass from the discs to the spheroids. In some cases, discs are destroyed, while in others, they survive or reform. This suggests that the survival probability of discs depends on the particular formation history of each galaxy. A realistic ΛCDM model will clearly require weaker star formation at high redshift and later disc assembly than occurs in our models.     

Effects of organochlorine compounds on cytochrome P450 aromatase activity in an immortal sea turtle cell line

Many classes of environmental contaminants affect the reproductive function of animals through interactions with the endocrine system. The primary components affected by endocrine active compounds (EACs) are the steroid receptors and the enzymes responsible for steroidogenesis. This study sought to develop an in vitro model for assessing EAC effects in sea turtles by examining their ability to alter cytochrome P450 aromatase (CYP19) activity. Aromatase is the enzyme responsible for the conversion of testosterone to estradiol. This enzyme is critical in the sexual differentiation of reptiles which demonstrate temperature-dependent sex determination. An immortal testis cell line GST-TS from a green sea turtle was grown in culture at 30 degrees C in RPMI 1640 media. The cells were exposed to three known aromatase inducers; dexamethasone (Dex), 8Br-cyclic AMP, or human chronic gonadotropin (HCG) and one aromatase inhibitor 4-androstenol-dione (4-OHA). In addition, the GST-TS cells were exposed to 0.1-30 microM atrazine and 3-100 microM 4,4'-DDE. The inducing compounds that have been shown to increase aromatase activity in other systems failed to induce aromatase activity in the GST-TS cells, yet exposure to the inhibiting compound, 4-OHA, did result in a significant reduction. Atrazine (0.1, 1.0 and 10 microM) significantly induced aromatase activity following a 24 h exposure, and 4,4'-DDE inhibited the activity but only at cytotoxic concentrations (100 microM). Based on these results, this in vitro model can be useful in examining the endocrine effects of EACs in sea turtles.     

Foraminifera as indicators of marine pollutant contamination on the inner continental shelf of southern Brazil

Analyses of living foraminiferal and environmental parameters near an outfall at Mar Grosso Beach (Laguna, SC, Brazil) demonstrate its usefulness as indicators of domestic sewage pollution. The low species diversity may be due to sand accumulation in the central part. Higher diversity was noted closer to the mouth of Laguna estuarine system where reduced salinity and higher temperatures indicate freshwater influence, suggesting a relationship between increased diversity and greater availability of terrestrial food. On the basis of foraminiferal diversity and average coliform count the higher values are closer to the mouth of the estuarine system and under the influence of the outfall. Due to the effect of local hydrodynamics, the particulate organic waste derived from the outfall does not settle down locally, and thus, do not accumulate nearby. Our hypothesis is that the fine material derived from the outfall is accumulating on the southwestern and northwestern parts of the beach.     

Runoff from soils under different management and simulated rainfall regimes in southern Brazil

Abstract

Surface runoff and drainage were evaluated for southern Brazilian soils subjected to different rainfall intensities and management practices. Soils received up to four applications of simulated rainfall in sequences with one application per day. Seven lysimeters, each of 1 m³ volume, were used to measure drainage volume, with measurement of initial and final water content, times at which surface runoff and lysimeter drainage began, and the volume rates of flow. At the end of the second test, soils were subjected to two levels of disturbance (denoted by low and high soil movement) by opening furrows. These cultivation treatments altered the times at which lysimeter surface runoff and drainage were initiated, the rates of surface runoff, the final infiltration and internal drainage, and the components of the water balance throughout the series of trials. Mean times at which surface runoff was initiated in lysimeters subjected to greater soil disturbance were longer than those with little soil disturbance. Final infiltration rates were greater in lysimeters with little soil disturbance. It was also found that lysimeter surface runoff generation was influenced by the state of development of maize grown in the lysimeter.

Editor D. Koutsoyiannis; Associate editor G. Mahé     

Heterogeneous distributions of CO2 may be more important for dissolution and karstification in coastal eogenetic limestone than mixing dissolution

Mixing dissolution, a process whereby mixtures of two waters with different chemical compositions drive undersaturation with respect to carbonate minerals, is commonly considered to form cavernous macroporosity (e.g. flank margin caves and banana holes) in eogenetic karst aquifers. On small islands, macroporosity commonly originates when focused dissolution forms globular chambers lacking entrances to the surface, suggesting that dissolution processes are decoupled from surface hydrology. Mixing dissolution has been thought to be the primary dissolution process because meteoric water would equilibrate rapidly with calcium carbonate as it infiltrates through matrix porosity and because pCO₂ was assumed to be homogeneously distributed within the phreatic zone. Here, we report data from two abandoned well fields in an eogenetic karst aquifer on San Salvador Island, Bahamas, that demonstrate pCO₂ in the phreatic zone is distributed heterogeneously. The pCO₂ varied from less than log ?2.0 to more than log ?1.0 atm over distances of less than 30 m, generating dissolution in the subsurface where water flows from regions of low to high pCO₂ and cementation where water flows from regions of high to low pCO_2. Using simple geochemical models, we show dissolution caused by heterogeneously distributed pCO₂ can dissolve 2.5 to 10 times more calcite than the maximum amount possible by mixing of freshwater and seawater. Dissolution resulting from spatial variability in pCO₂ forms isolated, globular chambers lacking initial entrances to the surface, a morphology that is characteristic of flank margin caves and banana holes, both of which have entrances that form by erosion or collapse after cave formation. Our results indicate that heterogeneous pCO₂, rather than mixing dissolution, may be the dominant mechanism for observed spatial distribution of dissolution, cementation and macroporosity generation in eogenetic karst aquifers and for landscape development in these settings. Copyright © 2015 John Wiley & Sons, Ltd.     

Henry Darcy in his own words

A recently published English translation of the Les Fontaines publiques de la ville de Dijon 1 provides access to Henry Darcy's own words on the importance of water for public sanitation and on questions engineers face in building water supply systems. Written near the end of Darcy's life, the book is a compendium of the water knowledge he had gained over decades and his opinions on these topics reveal his personality. In the 1840s, Darcy built a water supply system to provide water to 120 street fountains for domestic purposes, street washing and firefighting. Surrounded by poverty, Darcy insisted on free water for the poor and on sharing the spring water with towns located along the aqueduct that brought it to Dijon. In the preface to the book, Darcy introduces his experiment on water flow through sand with the modest words “to my knowledge, no one has experimentally demonstrated the laws of water flow through sand.” This article provides a sampling of the book's insights into the personality of this remarkable man.

Relative influence of vegetation on urban energy budgets and surface temperatures

Two deterministic models were combined: one for canopy leaf energy budgets and one for street canyon energy budgets. The effects of street parks and roof gardens in contrast to non-vegetated city blocks were examined by the use of four typical urban morphologies, which were exposed latitudinally to summer and winter simulations. A variety of increases and decreases in shortwave radiation, net radiation, sensible heat flux, and system reradiation resulted. These changes appear to represent the generalized limits of the possible responses to the addition of vegetation to non-vegetated city blocks.     

Assessing the simulation and prediction of rainfall associated with the MJO in the POAMA seasonal forecast system

We assess the ability of the Predictive Ocean Atmosphere Model for Australia (POAMA) to simulate and predict weekly rainfall associated with the MJO using a 27-year hindcast dataset. After an initial 2-week atmospheric adjustment, the POAMA model is shown to simulate well, both in pattern and in intensity, the weekly-mean rainfall variation associated with the evolution of the MJO over the tropical Indo-Pacific. The simulation is most realistic in December?CFebruary (austral summer) and least realistic in March?CMay (austral autumn). Regionally, the most problematic area is the Maritime Continent, which is a common problem area in other models. Coupled with our previous demonstration of the ability of POAMA to predict the evolution of the large-scale structure of the MJO for up to about 3?weeks, this ability to simulate the regional rainfall evolution associated with the MJO translates to enhanced predictability of rainfall regionally throughout much of the tropical Indo-Pacific when the MJO is present in the initial conditions during October?CMarch. We also demonstrate enhanced prediction skill of rainfall at up to 3?weeks lead time over the north-east Pacific and north Atlantic, which are areas of pronounced teleconnections excited by the MJO-modulation of tropical Indo-Pacific rainfall. Failure to simulate and predict the modulation of rainfall in such places as the Maritime Continent and tropical Australia by the MJO indicates, however, there is still much room for improvement of the prediction of the MJO and its teleconnections.