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311.
Benjamin G. Petri Radek Fučík Tissa H. Illangasekare Kathleen M. Smits John A. Christ Toshihiro Sakaki Carolyn C. Sauck 《Ground water》2015,53(5):685-698
The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed. 相似文献
312.
Patricia M. Clayton Ching‐Yi Tsai Jeffrey W. Berman Laura N. Lowes 《地震工程与结构动力学》2015,44(12):2093-2110
Previous research has shown that self‐centering steel plate shear walls (SC‐SPSWs) are capable of achieving enhanced seismic performance at multiple hazard levels, including recentering following design‐level earthquakes. When modeling SC‐SPSWs numerically, these studies considered an idealized tension‐only steel plate shear wall (SPSW) web plate behavior. Research has shown that web plate behavior is more complex than predicted by the idealized model, and web plates can provide more strength, stiffness, and energy dissipation than predicted by the idealized model. The idealized model of web plate behavior is used widely in SPSW numerical models where the moment‐resisting boundary frame provides supplemental hysteretic damping and stiffness; however, in SC‐SPSWs, where the post‐tensioned boundary frame is designed to remain elastic during an earthquake, accounting for the more complex web plate behavior can have a significant impact on seismic performance estimates from numerical simulation. This paper presents different methods for modeling SC‐SPSWs. Responses from these models are compared with experimental results. A simple modification of the tension‐only model, referred to as the tension‐compression strip model, is shown to provide a reasonable approximation of SC‐SPSW behavior. Results from nonlinear response history analyses of SC‐SPSWs with the tension‐only and tension‐compression web plate models are compared to assess how the approximation of web plate behavior affects SC‐SPSW seismic performance. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
313.
Heterogeneous distributions of CO2 may be more important for dissolution and karstification in coastal eogenetic limestone than mixing dissolution 下载免费PDF全文
Jason D. Gulley Jonathon B. Martin Paul J. Moore Amy Brown Patricia D. Spellman John Ezell 《地球表面变化过程与地形》2015,40(8):1057-1071
Mixing dissolution, a process whereby mixtures of two waters with different chemical compositions drive undersaturation with respect to carbonate minerals, is commonly considered to form cavernous macroporosity (e.g. flank margin caves and banana holes) in eogenetic karst aquifers. On small islands, macroporosity commonly originates when focused dissolution forms globular chambers lacking entrances to the surface, suggesting that dissolution processes are decoupled from surface hydrology. Mixing dissolution has been thought to be the primary dissolution process because meteoric water would equilibrate rapidly with calcium carbonate as it infiltrates through matrix porosity and because pCO2 was assumed to be homogeneously distributed within the phreatic zone. Here, we report data from two abandoned well fields in an eogenetic karst aquifer on San Salvador Island, Bahamas, that demonstrate pCO2 in the phreatic zone is distributed heterogeneously. The pCO2 varied from less than log ?2.0 to more than log ?1.0 atm over distances of less than 30 m, generating dissolution in the subsurface where water flows from regions of low to high pCO2 and cementation where water flows from regions of high to low pCO2. Using simple geochemical models, we show dissolution caused by heterogeneously distributed pCO2 can dissolve 2.5 to 10 times more calcite than the maximum amount possible by mixing of freshwater and seawater. Dissolution resulting from spatial variability in pCO2 forms isolated, globular chambers lacking initial entrances to the surface, a morphology that is characteristic of flank margin caves and banana holes, both of which have entrances that form by erosion or collapse after cave formation. Our results indicate that heterogeneous pCO2, rather than mixing dissolution, may be the dominant mechanism for observed spatial distribution of dissolution, cementation and macroporosity generation in eogenetic karst aquifers and for landscape development in these settings. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
314.
Comparing generalized Pareto models fitted to extreme observations: an application to the largest temperatures in Spain 总被引:1,自引:1,他引:0
Andrés M. Alonso Patricia de Zea Bermudez Manuel G. Scotto 《Stochastic Environmental Research and Risk Assessment (SERRA)》2014,28(5):1221-1233
In this paper, a subsampling-based testing procedure for the comparison of the exceedance distributions of stationary time series is introduced. The proposed testing procedure has a number of advantages including the fact that the assumption of stationary can be relaxed for some specific forms of non-stationary and also that the two time series are not required to be independently-generated. For this purpose, a test based on the Kolmogorov–Smirnov and the L 1-Wasserstein distances between generalized Pareto distributions is introduced and studied in some detail. The performance of the testing procedure is illustrated through a simulation study and with an empirical application to a set of data concerning daily maximum temperature in the 17 autonomous communities of Spain for the period 1990–2004. The autonomous communities were clustered according to the similarities of the fitted generalized Pareto models and then mapped. The cluster analysis reveals a clear distinction between the four northeast communities on the shores of the Bay of Biscay (which are the regions exhibiting milder temperatures) and the remaining regions. A second cluster corresponds to the southern Mediterranean area and the central region which corresponds to the communities with highest temperatures. 相似文献
315.
In the western part of the city of Zagreb, Croatia, hydrogeochemical and isotopic investigations of the Samobor aquifer were
carried out with the aim of determining the differences in hydrogeochemical characteristics at increasing aquifer depths.
The aquifer comprises 40-m thick gravelly–sandy deposits, with lenses and interlayers of silt and clay. The analyses have
proven that with increasing aquifer depth, there are decreases in groundwater temperature and the values of electrical conductivity
and increases in the sodium, iron and manganese concentrations. The δ13C distribution shows an evident increase in biogenic carbon concentrations with increasing aquifer depth. The measured specific
14C activities showed that the deeper part of the aquifer is characterized by slow water exchange, while the shallower part
is influenced by current recharge, although the pumping wells located on the well-field downstream penetrate the aquifer fully.
A direct exchange of water from the Sava River and groundwater occurs in the near vicinity of the river. This exchange weakens
further away, while the difference in hydrogeochemical characteristics between the Sava River water and groundwater increases. 相似文献
316.
Laboratory experiments show that dusty bodies in a gaseous environment eject dust particles if they are illuminated. We find that even more intense dust eruptions occur when the light source is turned off. We attribute this to a compression of gas by thermal creep in response to the changing temperature gradients in the top dust layers. The effect is studied at a light flux of 13 kW/m2 and 1 mbar ambient pressure. The effect is applicable to protoplanetary disks and Mars. In the inner part of protoplanetary disks, planetesimals can be eroded especially at the terminator of a rotating body. This leads to the production of dust which can then be transported towards the disk edge or the outer disk regions. The generated dust might constitute a significant fraction of the warm dust observed in extrasolar protoplanetary disks. We estimate erosion rates of about 1 kg s?1 for 100 m parent bodies. The dust might also contribute to subsequent planetary growth in different locations or on existing protoplanets which are large enough not to be susceptible to particle loss by light induced ejection. Due to the ejections, planetesimals and smaller bodies will be accelerated or decelerated and drift outward or inward, respectively. The effect might also explain the entrainment of dust in dust devils on Mars, especially at high altitudes where gas drag alone might not be sufficient. 相似文献
317.
The morphology, swimming behaviour, settlement preferences and behaviour of five species of Demospongiae are described. The sponges, Haliclona sp., Microciona coccinea, Ophlitaspongia seriata, Mycale macilenta, and Halichondria moorei, are all common in the intertidal region in the north of New Zealand. The view is put forward that larval behaviour must be interpreted in terms of the known ecological situation of the adult sponge. 相似文献
318.
Automatic tracing of the foot of the continental slope 总被引:1,自引:0,他引:1
The UNCLOS III (Article 76, Section 4(b)) defines the foot of the continental slope as the point of maximum change in the gradient at its base. It is impossible to locate so defined afoot and thus to trace the foot‐line objectively by eye. In this study we show a method designed automatically to detect and trace the foot‐line of the continental slope from an irregular array of bathymetrical data. Our algorithm first transforms the bathymetric surface to a maximum curvature surface. On this new surface, the foot‐line corresponds to one of the ridges; instead of tracing the foot‐line on the bathymetric surface, we now can trace the ridges on the maximum curvature surface. The tracing of the ridges can be done automatically and objectively and the foot‐line is identified as being one of these ridges. We devote particular attention to the case when the ridge‐line is not defined, i.e., to the case when the point of maximum gradient change becomes a region of maximum gradient change. 相似文献
319.
Damir Vilicic Milivoj Kuzmic Igor Tomažić Zrinka Ljubešić Sunčica Bosak Robert Precali Tamara Djakovac Danijela Marić Jelena Godrijan 《Marine Ecology》2013,34(4):451-466
A 275‐km‐long transversel Northern Adriatic profile from the mouth of the Po River (Italian Adriatic coast) to the Kvarner region (Croatian coastal island area) was investigated in three successive case studies in August 2008, 2009 and 2010. The short Po River pulses in August result in the surface advection of riverine water, nutrients and phytoplankton from the western to the eastern side of the Adriatic. This surface spreading exhibits inter‐annual variability depending on the riverine discharge in the preceding period. The Po River discharge pulse in August 2010 in particular resulted in an extraordinary tongue‐like advection of riverine water, nutrients, and phytoplankton towards the Eastern Adriatic coast. The phenomenon was detected using both satellite imagery and classical oceanographic measurements. In the advective water, toxic dinoflagellates were most abundant in August 2010, when the influence of the Po was greatest. 相似文献
320.
Foraminifera as indicators of marine pollutant contamination on the inner continental shelf of southern Brazil 总被引:1,自引:0,他引:1
Analyses of living foraminiferal and environmental parameters near an outfall at Mar Grosso Beach (Laguna, SC, Brazil) demonstrate its usefulness as indicators of domestic sewage pollution. The low species diversity may be due to sand accumulation in the central part. Higher diversity was noted closer to the mouth of Laguna estuarine system where reduced salinity and higher temperatures indicate freshwater influence, suggesting a relationship between increased diversity and greater availability of terrestrial food. On the basis of foraminiferal diversity and average coliform count the higher values are closer to the mouth of the estuarine system and under the influence of the outfall. Due to the effect of local hydrodynamics, the particulate organic waste derived from the outfall does not settle down locally, and thus, do not accumulate nearby. Our hypothesis is that the fine material derived from the outfall is accumulating on the southwestern and northwestern parts of the beach. 相似文献