Trends in total ozone and the effect of the equatorial zonal wind QBO

Trends in total column ozone have been analyzed in terms of the equatorial zonal wind. We used zonal monthly mean total ozone from Total Ozone Mapping Spectrometer (TOMS) and monthly mean zonal wind in the equatorial stratosphere at 30 hPa to define the phases of the quasi-biennial oscillation (QBO). Total column ozone trends have been assessed during the period 1979–2004, for both Hemispheres, and for each month, under three conditions considering, all the ozone dataset, ozone values during easterly phase and ozone values during westerly phase of the QBO. When the whole dataset is considered, negative trends are observed. From low to midlatitudes a zonal pattern is noticed with increasing negative values toward higher latitudes. When the data is filtered according to the QBO phase, statistically significant positive trends appear in the westerly case during January to May at low latitudes .The trend pattern in the case of the easterly phase presents more negative values.     

Ocean-bottom seismometer observations of seismic activity at Loihi Seamount,Hawaii

This study reports the result of deep ocean-bottom seismometer recording of an undersea volcanic event in progress. An array of five three-component, isolated sensor ocean-bottom seismometers (ISOBS) was deployed for 28 days on the summit and flanks of Loihi Seamount, Hawaii, to monitor seismicity. The deployment was prompted by reports from the Hawaiian Volcano Observatory (HVO) of a swarm of small-magnitude events located beneath the active submarine volcano in late September, 1986. Monitoring of this earthquake swarm by the University of Hawaii commenced 1 October 1986. Although seismicity tapered off rapidly after 11 October, more than 200 events were located. Systematic changes in spatial clustering during the initial swarm activity suggest changing patterns of stress within this crustal volume, possibly due to induced stress resulting from magma movement in the underlying crust or deep portions of the edifice.Most of the very shallow (< 10 km) events were located beneath the summit and southwest flank of the elongate edifice. No shallow tremor was observed despite a search through the data, although such tremor may have ceased prior to deployment of the ocean-bottom seismometers (OBS). Constraints on the association between seismicity and observed topographic and tectonic elements of Loihi are also of primary importance. Many of the earthquakes located near the steep flanks generated rock falls that were recorded on the OBSs. This is consistent with the results of dredge and bottom photography data indicating that the flanks are covered with fragments of shattered lava pillows and flows. Dike intrusion and mass wasting are major influences on the morphology of Loihi. Intact flows have been observed near the deep portion of the south rift zone; however, few events were located in that region during this swarm.     

The impact of pro‐glacial lakes on downstream sediment delivery in Norway

Glacier recessions caused by climate change may uncover pro‐glacial lakes that form important sedimentation basins regulating the downstream sediment delivery. The impact of modern pro‐glacial lakes on fluvial sediment transport from three different Norwegian glaciers: Nigardsbreen, Engabreen and Tunsbergdalsbreen, and their long‐term development has been studied. All of these lakes developed in modern times in overdeepened bedrock basins. The recession of Nigardsbreen uncovered a 1.8 km long and on average 15 m deep pro‐glacial lake basin during 1937 to 1968. Since then the glacier front has been situated entirely on land, and the sediment input and output of the lake has been measured. The suspended sediment transport into and out of the lake averaged 11 730 t yr^?1 and 2340 t yr^?1 respectively. Thus, 20% remained in suspension at the outlet. The measured mean annual bedload supplied to the lake was 11 800 t yr^?1, giving a total transport of 23 530 t yr^?1 which corresponds to a specific sediment yield of 561 t km^?2 yr^?1. A 1.9 km long and up to 90 m deep pro‐glacial lake basin downstream from Engabreen glacier was uncovered during 1890 to 1944. The average suspended sediment load delivered from the glacier during the years 1970–1981 amounted to 12 375 t yr^?1and the transport out of the lake was 2021 t yr^?1, giving an average of 16% remaining in suspension. The mean annual bedload was 8000 t yr^?1, thus the total transport was 20 375 t yr^?1, giving a specific sediment yield of 566 t km^?2 yr^?1. For Tunsbergdalsbreen glacier, measurements in the early 1970s indicated that the suspended sediment transport was on average 44 000 t yr^?1. From 1987 to 1993 the recession of the glacier uncovered a small pro‐glacial lake, 0.3 km long and around 9 m deep. Downstream from this, the suspended sediment load measured in 2009 was 28 000 t yr^?1, indicating that as much as 64% remained in suspension. Flow velocity, grain size of sediment, and morphology of the lake are important factors controlling the sedimentation rate in the pro‐glacial lakes. A survey of the sub‐glacial morphology of Tunsbergdalsbreen revealed that there are several overdeepened basins beneath the glacier. The largest is 4 km long and 100 m deep. When the glacier melts back they will become lakes and act as sedimentation basins. Despite an expected increase in sediment yield from the glacier, little sediment will pass these lakes and downstream sediment delivery will be reduced markedly. Beneath Nigardsbreen there was only a small depression that may form a lake and the sediment delivery will not be significantly affected. © 2014 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Quilotoa volcano — Ecuador: An overview of young dacitic volcanism in a lake-filled caldera

Quilotoa volcano, an example of young dacitic volcanism in a lake-filled caldera, is found at the southwest end of the Ecuador's volcanic front. It has had a long series of powerful plinian eruptions of moderate to large size (VEI = 4–6), at repetitive intervals of roughly 10–15 thousand years. At least eight eruptive cycles (labeled Q-I to Q-VIII with increasing age) over the past 200 ka are recognized, often beginning with a phreatomagmatic onset and followed by a pumice-rich lapilli fall, and then a sequence of pumice, crystal, and lithic-rich deposits belonging to surges and ash flows. These unwelded pyroclastic flows left veneers on hillsides as well as very thick accumulations in the surrounding valleys, the farthest ash flow having traveled about 17 km down the Toachi valley. The bulk volumes of the youngest flow deposits are on the order of 5 km³, but that of Q-I's 800 yr BP ash-fall unit is about 18 km³. In the last two eruption cycles water has had a more important role.     

Effects of increased inundation and wrack deposition on a high salt marsh plant community

Salt marshes respond to both slowly increasing tidal inundation with sea level rise and abrupt disturbances, such as storm-induced wrack deposition. The effects of inundation pattern and wrack deposition have been studied independently but not in combination. We manipulated inundation of tidal creek water and wrack presence individually and in combination, in two neighboring communities within a Virginia high salt marsh during 1994 and 1995. The effects of these manipulations were assessed by measurements of aboveground plant biomass. Altered inundation by itself produced little response in the various categories of plant biomass measured. Wrack deposition affected all species (i.e., Juncus roemerianus, Spartina patens, and Distichlis spicata) showing a significant reduction in aboveground biomass, as expected. Recovery after wrack deposition was dependent on the species. S. patens and D. spicata recovered from wrack deposition within one growing season, while J. roemerianus did not. Because the effects of wrack deposition greatly exceeded those of experimentally increased inundation, the possible interactions between the two were masked. Increased inundation may have inhibited the colonization of bare areas by some species after the removal of wrack from an area, although statistical significance at α=0.01 was not reached. Our results confirm that wrack deposition can cause the redistribution of species within the high marsh community. Altered inundation may have a greater effect on the re-establishment of the plant community after wrack deposition than it does without wrack deposition.     

Vegetation changes and sequential flowering after rain in the southern Atacama Desert

We describe the changes in plant cover, species richness, and flowering after rainfall over an entire growing season (September 1989–January 1990) in a southern Atacama Desert site in Chile. One month after the rain, vegetation was dominated by annuals and geophytes which dried out after 19 weeks. Among all species, including shrubs, we found differences of 4–10 weeks in the length and peak of the flowering period. The flowering sequence of the species belonging to the families Brassicaceae, Liliaceae, Onagraceae, and Asteraceae matched closely the sequences described for temperate plant communities, suggesting that this phenological character is phylogenetically determined.     

Land use and the spatial distribution of perfluoroalkyl compounds as measured in the plasma of bottlenose dolphins (Tursiops truncatus)

The distribution of perfluoroalkyl compounds (PFCs) in the environment is well documented with higher concentrations observed in wildlife located in industrial and urban areas. This study examined the distribution of PFCs in relation to land use using blood samples collected from bottlenose dolphins during capture-release health assessment surveys conducted in Charleston, SC. The study area was partitioned into three subareas (ACW, CHS, and SRE) based upon habitat and land use characteristics. The ACW and CHS subareas are characterized by high degrees of industrial and urban land uses, while the SRE subarea is more residential and characterized by a lower degree of developed land use. Long-term monitoring data from photo-identification surveys were used to group bottlenose dolphins based on their proportions of sightings in the different subareas. Dolphins affiliated with both the ACW and CHS subareas were observed to have significantly higher mean plasma concentrations of perfluorooctane sulfonate (PFOS), perfluorodecanoic acid (PFDA) and perfluoroundecanoic acid (PFUnA) than those affiliated with the SRE subarea. Dolphins affiliated with the ACW subarea were found to have a significantly higher mean plasma concentration of PFUnA than those affiliated with the CHS subarea. Further examination of the distribution of the PFCs revealed positive correlations with developed land uses and negative correlations with wetland/marsh land cover. A positive correlation was also observed between PFUnA and agricultural land use. The variability and scale of the observed contaminant burdens have important implications for the conservation and management of living marine resources and illustrates the importance of long-term monitoring of free-ranging wildlife species.     

Primary production and implications for metabolic balance in Hawaiian lee eddies

Recent discrepancies between geochemical and biological approaches for determining whether ocean ecosystems are net heterotrophic or net autotrophic have led to uncertainty in the net metabolic state of open ocean ecosystems. Geochemical approaches indicate that the oceans are net positive autotrophic, but direct observations based on short-term incubation techniques suggest that the ocean is in a state of net heterotrophy. One hypothesis for the apparent discrepancy is that net autotrophic production occurs in aperiodic “bursts,” which are superimposed on a more constant background state of net heterotrophy. Mixing events, which introduce new nutrients to the surface ocean, provide one mechanism for fueling such aperiodic bursts of net production. In conjunction with the Eddy Flux (E-Flux) program in the lee of the Hawaiian Islands during winter 2004–2005, we examined the relationship between photosynthesis and irradiance (P vs. E) in surface waters inside and outside of two cold-core, cyclonic eddies, and conducted five incubation experiments to examine the metabolic response of mixed-layer plankton communities to nutrient-rich deep-sea water additions. Our results showed that in the mixed layer, maximum rates of light-saturated photosynthesis, derived from photosynthesis–irradiance experiments were not significantly different inside vs. outside the eddies (p=0.35 and 0.44 for E-Flux I and E-Flux III, respectively). Addition of nutrients to mixed-layer water showed that (1) gross primary production (GPP) became decoupled from a more constant rate of respiration and (2) net system metabolism shifted from approximate balance, or slight net heterotrophy, to a demonstrably net autotrophic system. From these results, we determined that the threshold GPP for net autotrophic production for the mixed layer of the study region was 1.65 mmol O₂ m⁻³ d⁻¹, which is consistent with previous estimates for the oligotrophic open ocean.     

The effect of cadmium on fulvic acid adsorption to Bacillus subtilis

The effects of Cd on the adsorption of an aquatic fulvic acid (FA) to the surface of Bacillus subtilis were investigated from pH 2.5 to 7.0, at fixed ionic strength (0.1 M NaClO₄) and at ambient temperature (22 °C). Cd (14 mg/l) had no effect on FA adsorption at pH<5 but increased FA adsorption at pH>6. The effects of Cd (0, 14 mg/l) on FA adsorption to B. subtilis were further examined as a function of initial FA concentration (0–45 mg C/l) at pH 6.5. FA adsorption isotherms also were measured at pH 6.5 as a function of dissolved Cd concentration (0–14 mg/l) at three initial FA concentrations (4, 8, 22 mg C/l). At all FA concentrations studied at pH 6.5, FA adsorption increased with increasing initial total Cd concentration.

Under all studied conditions, preferential adsorption of high- to intermediate-molecular-weight FA components to B. subtilis resulted in a fractionation of the FA pool, with lower-molecular-weight components remaining in solution. At pH>6, Cd further enhanced the adsorption of high- to intermediate-molecular-weight FA components but did not significantly enhance the adsorption of lower-molecular-weight components. Hence, the overall process of adsorptive fractionation was not altered significantly by the presence of Cd.

Overall, the results of this study (1) demonstrate that FA adsorption to bacterial surfaces can be altered by the presence of a metal cation, and (2) provide further evidence that microbe–metal–ligand interactions may significantly affect the mobility and fate of natural organic matter in the subsurface.