Adsorption of dissolved organic matter on clay minerals as assessed by infra-red, CPMAS C NMR spectroscopy and low field T1 NMR relaxometry

Dissolved organic matter (DOM) is a very important environmental constituent due to its role in controlling factors for soil formation, mineral weathering and pollutant transport in the environment. Prediction of DOM physical-chemical properties is achieved by studying its chemical structure and spatial conformation. In the present study, dissolved organic matter extracted from compost obtained from the organic fraction of urban wastes (DOM-P) has been analysed by FT-IR, CPMAS ¹³C NMR spectroscopy and ¹H T₁ NMR relaxometry with fast field cycling (FFC) setup. While the first two spectroscopic techniques revealed the chemical changes of dissolved organic matter after adsorption either on kaolinite (DOM-K) or montmorillonite (DOM-S), the latter permitted the evaluation of the conformational variations as assessed by longitudinal relaxation time (T₁) distribution at the fixed magnetic field of 500 mT. Alterations of T₁ distributions from DOM-P to DOM-K and DOM-S were attributed to a decreasing molecular complexity following DOM-P adsorption on the clay minerals. This study applied for the first time solid state ¹H T₁ NMR relaxometry to dissolved organic matter from compost obtained from the organic fraction of urban wastes and revealed that this technique is very promising for studying environmentally relevant natural organic systems.     

Autochthonous and allochthonous plant contributions to coastal benthic detritus deposits: a dual-stable isotope study in a volcanic lake

The high numbers of primary producers represent multiple sources of organic matter accumulating onto lake bottoms. The difficulty of distinguishing the relative contribution to the mixture presents considerable challenges to the analysis of these organic deposits. In this study, dual-stable isotope analysis and IsoSource model were used to identify allochthonous and autochthonous components of detritus deposits (Particulate Organic Matter: POM) at two different bottom slope sites of a volcanic lake (lake Bracciano). Experiments were carried out to calibrate IsoSource on constructed plant mixtures and assess changes in isotope ratios during plant decomposition. IsoSource satisfactorily discriminated the constructed mixture sources with a few exceptions. Changes in isotopic enrichment during decomposition were low, and thus did not represent a confounding variable in the isotopic analysis. By contrast, chemical and geological differences of the study sites were associated with differences in plant δ¹³C and δ¹⁵N values (more than 2‰ within single plant species). At both sites, the isotopic signals of POM fell between polygons delineated by source end members with an evident shift of δ¹³C toward allochthonous sources. POM amount and diversity were greater at the flatter bottom site, where allochthonous contributions were larger than at the other site. In particular, IsoSource ranked species contributions as follows: A. glutinosa > P. australis > A. donax > S. alba > P. nigra > the benthic macroalga Chara sp. at the first site, and A. glutinosa > P. nigra > the aquatic macrophyte C. demersum at the latter. The composition of littoral POM was determined by allochthonous sources in proportion to their relative abundances (as percent land cover) with differences between sites due to bottom slope.     

Groundwater flow analysis using different geothermal constraints: The case study of Acqui Terme area,northwestern Italy

We review some analytical techniques that use underground thermal data as tracers of groundwater flow. These techniques allow the evaluation of the Darcy velocity in shallow aquifers of mid-low permeability and the evaluation of heat gain/loss by conduction in deeper aquifers. Examples of application are then given for the Acqui Terme hydrothermal system, located in the Tertiary Piedmont Basin (northwestern Italy). The analysis of borehole temperatures allowed the inference of the hydraulic features of the sedimentary cover of the hydrothermal system. The results show the presence of a relatively weak flow, with upward and horizontal components, only in conglomerates occurring at the base of the marly impermeable cover. The analysis of the heat transported in the deep parts of the hydrothermal system was approached by splitting the water path into different sections, each with given shape, slope and hydraulic properties. The recharge area is situated in the upland, south of the discharge area. Meteoric water initially descends and then flows horizontally within the fractured metamorphic basement of the basin, heating by conduction. Finally, from a reservoir positioned at intermediate depths, hot water reaches rapidly the surface through a sub-vertical fault. This scheme of deep water flow is constrained by the regional surface heat flow and the local geothermal gradient, and it is consistent with data of rock–water equilibrium temperature.     

Earthquake focal mechanisms and stress inversion in the Irpinia Region (southern Italy)

The goal of this study was to estimate the stress field acting in the Irpinia Region, an area of southern Italy that has been struck in the past by destructive earthquakes and that is now characterized by low to moderate seismicity. The dataset are records of 2,352 aftershocks following the last strong event: the 23 November 1980 earthquake (M 6.9). The earthquakes were recorded at seven seismic stations, on average, and have been located using a three-dimensional (3D) P-wave velocity model and a probabilistic, non-linear, global search technique. The use of a 3D velocity model yielded a more stable estimation of take-off angles, a crucial parameter for focal mechanism computation. The earthquake focal mechanisms were computed from the P-wave first-motion polarity data using the FPFIT algorithm. Fault plane solutions show mostly normal component faulting (pure normal fault and normal fault with a strike-slip component). Only some fault plane solutions show strike-slip and reverse faulting. The stress field is estimated using the method proposed by Michael (J Geophys Res 92:357–368, 1987a) by inverting selected focal mechanisms, and the results show that the Irpinia Region is subjected to a NE–SW extension with horizontal σ ₃ (plunge 0°, trend 230°) and subvertical σ ₁ (plunge 80°, trend 320°), in agreement with the results derived from other stress indicators.     

Effects of Surface Geology on Seismic Ground Motion Deduced from Ambient-Noise Measurements in the Town of Avellino, Irpinia Region (Italy)

The effects of surface geology on ground motion provide an important tool in seismic hazard studies. It is well known that the presence of soft sediments can cause amplification of the ground motion at the surface, particularly when there is a sharp impedance contrast at shallow depth. The town of Avellino is located in an area characterised by high seismicity in Italy, about 30?km from the epicentre of the 23 November 1980, Irpinia earthquake (M?=?6.9). No earthquake recordings are available in the area. The local geology is characterised by strong heterogeneity, with impedance contrasts at depth. We present the results from seismic noise measurements carried out in the urban area of Avellino to evaluate the effects of local geology on the seismic ground motion. We computed the horizontal-to-vertical (H/V) noise spectral ratios at 16 selected sites in this urban area for which drilling data are available within the first 40?m of depth. A Rayleigh wave inversion technique using the peak frequencies of the noise H/V spectral ratios is then presented for estimating Vs models, assuming that the thicknesses of the shallow soil layers are known. The results show a good correspondence between experimental and theoretical peak frequencies, which are interpreted in terms of sediment resonance. For one site, which is characterised by a broad peak in the horizontal-to-vertical spectral-ratio curve, simple one-dimensional modelling is not representative of the resonance effects. Consistent variations in peak amplitudes are seen among the sites. A site classification based on shear-wave velocity characteristics, in terms of Vs30, cannot explain these data. The differences observed are better correlated to the impedance contrast between the sediments and basement. A more detailed investigation of the physical parameters of the subsoil structure, together with earthquake data, are desirable for future research, to confirm these data in terms of site response.     

High-order polynomial continuation method for trajectory design in non-Keplerian environments

Celestial Mechanics and Dynamical Astronomy - We are dealing with the averaged model used to study the secular effects in the motion of a body of the negligible mass in the context of a spatial...     

Dissociation Constants of Protonated Oxidized Glutathione in Seawater Media at Different Salinities

Oxidized glutathione (GSSG), which has four carboxylic and two amino groups, interacts with metal ions and may affect the bioavailability and geochemistry of metals in natural waters. In the present paper, six stepwise protonation constants K^\textH_i K^{\text{H}}_{i} for GSSG were measured as a function of salinity, S = 5–35‰ at t = 25°C (and in NaCl/MgCl₂ mixtures at different ionic strengths), in order to provide thermodynamic data for their acid base properties, which are useful for studying the interaction with metals in these media. The protonation enthalpies (ΔH _i /kJ mol⁻¹) were also determined at t = 25°C. The results were interpreted using the SIT model and Pitzer equations. The seawater model with the interaction parameters accounts for the differences between the values in NaCl and seawater. The results suggest that it is important to consider all of the ionic interactions in natural waters in examining the proton dissociation of GSSG.