Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

基于循环孔洞扩张模型的X型圆管节点超低周疲劳寿命预测

海洋工程钢结构在服役过程中,受风、浪、流或地震等极端循环载荷的影响,易发生超低周疲劳断裂破坏,造成人员伤亡及财产损失,因此超低周疲劳断裂分析及寿命预测对于海工结构安全性评估至关重要。然而,现阶段基于累积损伤理论提出的多种超低周疲劳寿命预测模型无法对多尺度节点实现统一预测,造成了实际工程应用的不便。因此文中基于循环孔洞扩张模型开展X型圆管节点超低周疲劳寿命预测。首先,开发了基于循环孔洞扩张模型的VUSDFLD程序,实现ABAQUS与FORTRAN子程序联合应用,利用有限元分析验证循环孔洞扩张模型在X型圆管节点超低周疲劳断裂分析中的有效性;其次,根据多组X型圆管节点超低周疲劳断裂有限元分析结果,在宏观层面提出了一种基于Manson-Coffin公式的超低周疲劳寿命预测公式;最后,依据Miner理论,将适用于等幅加载的超低周疲劳寿命公式扩展至变幅加载情况,验证了多种节点尺寸下超低周疲劳公式的适用性,为工程应用提供了理论依据。     

Principal Components Analysis of Rainfall and Associated Synoptic Models of the Southwest Monsoon over India

Summary  The summer monsoon circulation shows various spatial and temporal oscillations and often a combination of systems produces an integrated effect. In this study phases of the southwest (SW) monsoon have been identified in an objective manner with the help of T-mode principal component analysis (PCA) of weekly rainfall anomalies. Mean composite charts have been prepared utilising all available upper air data (1977–1986) for each category of the SW monsoon epochs identified by the PCA. These sets of charts have been constructed for both the strong and weak phases associated with the first four significant principal components (PCs). A well defined east-west oriented trough system, extending from about 28° N Latitude/65° E Longitude to 20° N Latitude/90° E Longitude, in the lower levels, has been the main feature associated with the strong phase of the monsoon corresponding to PC I. The trough in the lower levels is more marked in the eastern half compared to the western half in both the sets of charts associated with strong phases of the monsoon related to the PC II and PC III. With PC II, the position of the troughs in the lower levels is further north of its location in PC III. The east-west trough system associated with the strong phase of PC IV has a large southward tilt with height. The charts corresponding to the weak phases of these PCs have synoptic features, such as the position of the trough close to the foothills of the Himalayas, and the shifting of middle and upper tropospheric anticyclones to the south. The study suggests an objective method of interpretation of principal components by utilising synoptic data. In addition, synoptic models and data sets corresponding to different phases of the monsoon can also be prepared in an objective manner by such PCA. Received July 18, 1997 Revised April 30, 1999     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

In situ Raman observation of the crystallization in NaNO3–Na2SO4–H2O solution droplets

Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO₃–Na₂SO₄ system including the formation of the double salt darapskite, Na₃NO₃SO₄·H₂O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na₂SO₄(III), Na₂SO₄(V) and darapskite. The experimental observations are discussed on the basis of the NaNO₃–Na₂SO₄–H₂O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures.     

Integration of reflection seismic and sediment grain-size data from Lake Khubsugul (Northern Mongolia): a reply to Prokopenko and Kendall

Prokopenko and Kendall (J Paleolimnol doi:, 2008) criticise the work presented in Fedotov et al. (J Paleolimnol 39:335–348, 2008), and instead propose an alternative interpretation for the grain-size evolution recorded in the KDP-01 core, retrieved from the central part of Lake Khubsugul. Their interpretation is based (i) on a seismic-stratigraphic re-interpretation of sparker seismic profile khub012 (which they copied from Fedotov et al. (EOS Trans 87:246–250, 2006)), (ii) on the presupposition that changes in lake level are the dominant control on facies distribution in Lake Khubsugul, and (iii) on the invalidation of our age-depth model. In this reply to their comment, we demonstrate that they interpreted seismic artefacts and geometries caused by changes in profile orientation as true stratigraphic features and that the lake-level reconstruction they derive from this interpretation is therefore incorrect. We also demonstrate that their grain-size predictions, which they consider to be predominantly driven by changes in lake level, are inconsistent with the measured sulphate concentration, which is a demonstrated proxy of lake level in Lake Khubsugul, and with the measured grain-size record. Finally, we point out that even if there would be a problem with the age-depth model, this problem would not affect the part of the sedimentary sequence discussed in Fedotov et al. (J Paleolimnol 39:335–348, 2008).     

The hard solar X-ray burst of 18 September 1963

A hard solar X-ray burst was observed by J-P. Legrand on 18 September 1963, 13:56 UT, at balloon altitude. It lasted a few minutes; a steep increase was followed by an exponential decay. During its declining phase a weak radio burst was observed on 3 and 10 cm, not on longer wavelengths.Maximum radio intensity occurred two minutes after that of the X-ray burst. The X-ray and radio bursts ended almost simultaneously. Optically a small shortlived (some minutes) flare point occurred simultaneously with the X-ray burst in a magnetically interesting part of the active region of September 1963. The X-burst photons seem to have had an energy of about 0.5 MeV. The burst was therefore of a fairly rare type, since very few other bursts with similar photon energies have been detected up to now.It is suggested that a mass of gas, magnetically confined to a volume of about 5·10²⁵ cm³ in the low corona, containing about 3·10³⁵ electrons was accelerated to energies of about 0.5 MeV. The gas gradually expanded, partly also to higher levels. The gyro-synchrotron radiation, emitted by the plasma became observable after about two minutes. At the lower radio frequencies the radiation was absorbed by overlying undisturbed coronal matter. Quantitative computations justify this model. A detailed summary of the events, and some numerical data are given in the concluding Section 8 and in Table V.     

Detecting patterns of climate change in long-term forecasts of marine environmental parameters

ABSTRACT

Forecasting environmental parameters in the distant future requires complex modelling and large computational resources. Due to the sensitivity and complexity of forecast models, long-term parameter forecasts (e.g. up to 2100) are uncommon and only produced by a few organisations, in heterogeneous formats and based on different assumptions of greenhouse gases emissions. However, data mining techniques can be used to coerce the data to a uniform time and spatial representation, which facilitates their use in many applications. In this paper, streams of big data coming from AquaMaps and NASA collections of 126 long-term forecasts of nine types of environmental parameters are processed through a cloud computing platform in order to (i) standardise and harmonise the data representations, (ii) produce intermediate scenarios and new informative parameters, and (iii) align all sets on a common time and spatial resolution. Time series cross-correlation applied to these aligned datasets reveals patterns of climate change and similarities between parameter trends in 10 marine areas. Our results highlight that (i) the Mediterranean Sea may have a standalone ‘response’ to climate change with respect to other areas, (ii) the Poles are most representative of global forecasted change, and (iii) the trends are generally alarming for most oceans.     

Minimal Detectable Biases of Cross-Correlated GPS Observations

In this article, analytic expressions are given for the minimal detectable biases (MDBs) of dual-frequency cross-correlated global positioning system (GPS) single difference code and carrier observations. They are given for three different short baseline models. (Short here implies that orbital and atmospheric uncertainties are assumed absent.) A comparison is made with the expressions for the MDBs of non-cross-correlating receivers. Finally, in order to get a better understanding of them, MDBs are visualized as a function of the parameters on which they depend, such as the number ob tracked satellites and the number of observation epochs. ? 2000 John Wiley & Sons, Inc.