Fluid composition and evolution in coesite-bearing rocks (Dora-Maira massif,Western Alps): implications for element recycling during subduction

Fluid inclusions and F, Cl concentration of hydrous minerals were analysed in the coesite-pyrope quartzite, the interlayered jadeite quartzite and their country-rock gneiss from the Dora-Maira massif using a combination of microthermometry, Raman spectrometry, synchrotron X-ray microfiuorescence and electron microprobe analysis. Three populations of fluid inclusions were recognized texturally and can be related to distinct metamorphic stages. A low-salinity aqueous fluid occurs in the retrogressed country gneiss and as late secondary inclusions in jadeite quartzite and chloritized pyrope. An earlier secondary population is found in matrix quartz of the jadeite- and pyro-pe-quartzites. This population can be related to the early decompression and so to incipient breakdown of garnet into phlogopite-bearing assemblages. The inclusion fluid is highly saline (up to 84 wt% equivalent NaCl) and contains Na, Ca, Fe, Cu and Zn as major cations. In pyrope quartzite, additional K was found in these brines, which locally coexist with CO₂-rich inclusions. The oldest fluid inclusions are preserved in kyanite grains included in fresh pyrope and in pyrope itself. In pyrope, all inclusions have decrepitated and contain magnesite, an Mg-phosphate, sheet-silicate(s), a chloride and an opaque phase, with no fluid preser ved. In contrast, the kyanite inclusions in pyrope preserve primary H₂O-CO₂ low-salinity fluid inclusions, probably owing to the low compressibility of the kyanite inclusions and host garnet. In spite of in-situ re-equilibration, these inclusions can be interpreted as relics of the dehydration fluid that attended pyrope growth. These correlations between textural and chemical fluid inclusion data and metamorphic stages are consistent with the fluid composition calculated from the halogen content of different generations of phlogopite and biotite. The preservation of different fluid compositions, both in time and space, is evidence for local control and possibly origin of the fluids, in agreement with isotopic data. These results, in particular the absence of CO₂ in the jadeite quartzite, are best interpreted in terms of a fluid-melt system evolution. With increasing metamorphism, partitioning of H₂O, Na, Ca, Fe and heavy metals into melt (jadeite quartzite) and Mg, Na/K, F, CO₂ and P(?) into a residual aqueous fluid can account for depletion in Na, Ca and Fe of the pyrope quartzite. During the retrograde path, a _{H 2 O} rose as melt crystallized, generating the two populations of hypersaline and water-rich fluids that were highly reactive to pyrope. The process of fluid-melt interaction envisioned here coupled with models of melt extraction in subduction zones provides an attractive opportunity for the instantaneous ( < 1 Ma) and selective transport of elements between a downgoing slab and the overlying mantle wedge.     

The December 4, 1983 to February 18, 1984 eruption of Piton de la Fournaise (La Reunion, Indian Ocean): Description and interpretation

On December 4, 1983 an eruption started at vents located 1.5 km southwest of the summit of Piton de la Fournaise at the base of the central cone. After 31 months of quiescence this was one of the longest repose period in the last fifty years. The eruption had two phases: December 4 to January 18 and January 18 to February 18. Phase 1 produced about 8 × 10⁶ m³ of lava and Phase II about 9 × 10⁶ m³. The erupted lava is an aphyric basalt whose mineralogical and geochemical composition is close to that of other lavas emitted since 1977.The precursors of the December 4 outbreak were limited to two-week shallow (1.5–3 km) seismic crisis of fewer than 50 events. No long-term increase was noted in the local seismicity which is very quiet during repose periods and no long-term ground inflation preceded the eruption. Outbreaks of Phases I and II were preceded by short (2.5 hours and 1.5 hours) seismic swarms corresponding to the rise of magma toward the surface from a shallow reservoir. Large ground deformation explained by the emplacement of the shallow intrusions, was recorded during the seismic swarms. A summit inflation was observed in early January, before the phase II outbreak, while the phase I eruption was still continuing.Piton de la Fournaise volcanological observatory was installed in 1980. Seismic and ground deformation data now available for a period of 4 years including the 1981 and the 1983–1984 eruptions, allow us to describe the physical behavior of the volcano during this period. These observations lead us to propose that the magma transfer from deep levels to the shallow magma reservoir is not a continuous process but a periodic one and that the shallow magma reservoir was not resupplied before the 1981 and 1983–1984 eruptions. Considerations on the eruptive history and the composition of recent lavas indicate that the reservoir was refilled in 1977.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.     

Geological overview and cratering model for the Haughton impact structure,Devon Island,Canadian High Arctic

Abstract— The Haughton impact structure has been the focus of systematic, multi‐disciplinary field and laboratory research activities over the past several years. Regional geological mapping has refined the sedimentary target stratigraphy and constrained the thickness of the sedimentary sequence at the time of impact to ?1880 m. New ⁴⁰Ar–³⁹Ar dates place the impact event at ?39 Ma, in the late Eocene. Haughton has an apparent crater diameter of ?23 km, with an estimated rim (final crater) diameter of ?16 km. The structure lacks a central topographic peak or peak ring, which is unusual for craters of this size. Geological mapping and sampling reveals that a series of different impactites are present at Haughton. The volumetrically dominant crater‐fill impact melt breccias contain a calcite‐anhydrite‐silicate glass groundmass, all of which have been shown to represent impact‐generated melt phases. These impactites are, therefore, stratigraphically and genetically equivalent to coherent impact melt rocks present in craters developed in crystalline targets. The crater‐fill impactites provided a heat source that drove a post‐impact hydrothermal system. During this time, Haughton would have represented a transient, warm, wet microbial oasis. A subsequent episode of erosion, during which time substantial amounts of impactites were removed, was followed by the deposition of intra‐crater lacustrine sediments of the Haughton Formation during the Miocene. Present‐day intra‐crater lakes and ponds preserve a detailed paleoenvironmental record dating back to the last glaciation in the High Arctic. Modern modification of the landscape is dominated by seasonal regional glacial and niveal melting, and local periglacial processes. The impact processing of target materials improved the opportunities for colonization and has provided several present‐day habitats suitable for microbial life that otherwise do not exist in the surrounding terrain.     

Development of a hydrodynamic model of the Bay of Biscay. Validation of hydrology

The hydrology of the Bay of Biscay was investigated using the regional ocean model MARS3D (Model for Application at Regional Scale). The simulated hydrology is compared to a set of various data encompassing monthly climatology, remote sensing SST, CTD casts, and coastal salinity measurements. Special focus was put on the validation over the continental shelf. This paper reports that despite some misfits, the climatological hydrology and its seasonal variability are correctly simulated. Various statistics computed over the period from 1999–2004 highlight different aspects of the hydrology. The biases and root mean square errors (RMSE) remain very weak at all depths when comparing salinity (<0.1 and <0.6 psu respectively). The predicted temperature shows a global overestimation of temperature (bias of around 0.8 °C) and the maximum errors are located near the thermocline (rmse of 1 °C at 20–40 m). The model is shown to properly reproduce the annual dynamics of sea surface temperature, as well as the dynamics of large river plumes observed by high frequency time series from coastal salinity gauges. The misfits highlighted by these various comparisons between model and observations are attributed to heat fluxes and mixing parameterisation.     

A Comprehensive Framework for Intrinsic OpenStreetMap Quality Analysis

OpenStreetMap (OSM) is one of the most popular examples of a Volunteered Geographic Information (VGI) project. In the past years it has become a serious alternative source for geodata. Since the quality of OSM data can vary strongly, different aspects have been investigated in several scientific studies. In most cases the data is compared with commercial or administrative datasets which, however, are not always accessible due to the lack of availability, contradictory licensing restrictions or high procurement costs. In this investigation a framework containing more than 25 methods and indicators is presented, allowing OSM quality assessments based solely on the data's history. Without the usage of a reference data set, approximate statements on OSM data quality are possible. For this purpose existing methods are taken up, developed further, and integrated into an extensible open source framework. This enables arbitrarily repeatable intrinsic OSM quality analyses for any part of the world.     

Impact‐induced microbial endolithic habitats

Abstract— Asteroid and comet impacts on Earth are commonly viewed as agents of ecosystem destruction, be it on local or global scales. However, for some microbial communities, impacts may represent an opportunity for habitat formation as some substrates are rendered more suitable for colonization when processed by impacts. We describe how heavily shocked gneissic crystalline basement rocks exposed at the Haughton impact structure, Devon Island, Nunavut, Arctic Canada, are hosts to endolithic photosynthetic microorganisms in significantly greater abundance than lesser‐shocked or unshocked gneisses. Two factors contribute to this enhancement: (a) increased porosity due to impact fracturing and differential mineral vaporization, and (b) increased translucence due to the selective vaporization of opaque mineral phases. Using biological ultraviolet radiation dosimetry, and by measuring the concentrations of photoprotective compounds, we demonstrate that a covering of 0.8 mm of shocked gneiss can provide substantial protection from ultraviolet radiation, reducing the inactivation of Bacillus subtilis spores by 2 orders of magnitude. The colonisation of the shocked habitat represents a potential mechanism for pioneer microorganisms to invade an impact structure in the earliest stages of post‐impact primary succession. The communities are analogous to the endolithic communities associated with sedimentary rocks in Antarctica, but because they occur in shocked crystalline rocks, they illustrate a mechanism for the creation of microbial habitats on planetary surfaces that do not have exposed sedimentary units. This might have been the case on early Earth. The data have implications for the microhabitats in which biological signatures might be sought on Mars.     

Impact of intra-daily SST variability on ENSO characteristics in a coupled model

This paper explores the impact of intra-daily Sea Surface Temperature (SST) variability on the tropical large-scale climate variability and differentiates it from the response of the system to the forcing of the solar diurnal cycle. Our methodology is based on a set of numerical experiments based on a fully global coupled ocean–atmosphere general circulation in which we alter (1) the frequency at which the atmosphere sees the SST variations and (2) the amplitude of the SST diurnal cycle. Our results highlight the complexity of the scale interactions existing between the intra-daily and inter-annual variability of the tropical climate system. Neglecting the SST intra-daily variability results, in our CGCM, to a systematic decrease of 15% of El Ni?o—Southern Oscillation (ENSO) amplitude. Furthermore, ENSO frequency and skewness are also significantly modified and are in better agreement with observations when SST intra-daily variability is directly taken into account in the coupling interface of our CGCM. These significant modifications of the SST interannual variability are not associated with any remarkable changes in the mean state or the seasonal variability. They can therefore not be explained by a rectification of the mean state as usually advocated in recent studies focusing on the diurnal cycle and its impact. Furthermore, we demonstrate that SST high frequency coupling is systematically associated with a strengthening of the air-sea feedbacks involved in ENSO physics: SST/sea level pressure (or Bjerknes) feedback, zonal wind/heat content (or Wyrtki) feedback, but also negative surface heat flux feedbacks. In our model, nearly all these results (excepted for SST skewness) are independent of the amplitude of the SST diurnal cycle suggesting that the systematic deterioration of the air-sea coupling by a daily exchange of SST information is cascading toward the major mode of tropical variability, i.e. ENSO.