Tectonic significance of different block-in-matrix structures in exhumed convergent plate margins: examples from oceanic and continental HP rocks in Inner Western Alps (northwest Italy)

In the Inner Western Alps, three different types of block-in-matrix structures (BIMs) formed sequentially through time at a convergent plate margin. These show the superposition of progressive deformation from (i) subduction to eclogite-facies depths, (ii) collision, accretion, and exhumation of oceanic crust, represented by the Monviso Meta-ophiolite Complex, to (iii) collision, accretion, and exhumation of the continental Dora Maira units. The Type 1 occurs in the metasedimentary cover of the Dora Maira Unit and consists of a map-scale broken formation with boudinaged ‘native’ blocks of marble (Early Jurassic) in a calcschist matrix. It results from the tectonic overprinting of exhumation-related folding (D2-stage) on an earlier subduction-related dismembered succession (D1-stage). Type 1 also includes ‘non-mappable’ BIMs with ‘exotic’ blocks, resulting from the gravitational collapse of the Triassic carbonate platform of European Continental Margin, triggered by the Early Jurassic rifting. In the Monviso Meta-ophiolite Complex, Types 2 and 3 represent tectonically induced broken and dismembered formations, respectively. They differ from each other in the degree of stratal disruption of primary interbedded horizons of mafic metabreccia (Type 3) and mafic metasandstone (Types 2 and 3) sourced by the Late Jurassic–Early Cretaceous denudation of an oceanic core complex. Dismembered interbeds (Type 2) and isolated blocks were mixed together (Type 3) by the overlap of D2 tectonics and late- to post-exhumation extensional shearing (D3-stage). Development of these types of BIMs may be common in many exhumed convergent plate margins, where severe tectonics and metamorphic recrystallization under high-pressure conditions normally prevent the reconstruction of BIMs or mélange-forming processes. Our findings show that documenting the mode and time of the processes forming BIMs is highly relevant in order to reconstruct the oceanic seafloor morphology and composition of associated stratigraphic successions, and their control in the evolution of those convergent plate margins.     

Toothed whales in the northwestern Mediterranean: insight into their feeding ecology using chemical tracers

Risso’s dolphins, pilot whales and sperm whales rarely strand in the northwestern Mediterranean. Thus, their feeding ecology, through the analysis of stomach contents, is poorly known. The aim of this study was to gain further insight into the segregation/superposition of the diet and habitat of Risso’s dolphins, pilot whales and sperm whales using chemical tracers, namely, stable isotopes (δ¹³C, δ¹⁵N) and organochlorines. Significantly different δ¹⁵N values were obtained in Risso’s dolphins (11.7 ± 0.7‰), sperm whales (10.8 ± 0.3‰) and pilot whales (9.8 ± 0.3‰), revealing different trophic levels. These differences are presumably due to various proportions of Histioteuthidae cephalopods in each toothed whale’s diet. Similar δ¹³C contents between species indicated long-term habitat superposition or corroborated important seasonal migrations. Lower congener 180 concentrations (8.20 vs. 21.73 μg.g⁻¹ lw) and higher tDDT/tPCB ratios (0.93 vs. 0.42) were observed in sperm whales compared with Risso’s dolphins and may indicate wider migrations for the former. Therefore, competition between these species seems to depend on different trophic levels and migration patterns.     

Rock fall simulation at Timpanogos Cave National Monument, American Fork Canyon, Utah, USA

Rock fall from limestone cliffs at Timpanogos Cave National Monument in American Fork Canyon east of Provo, Utah, is a common occurrence. The cave is located in limestone cliffs high on the southern side of the canyon. One fatality in 1933 led to the construction of rock fall shelters at the cave entrance and exit in 1976. Numerous rock fall incidents, including a near miss in 2000 in the vicinity of the trail below the cave exit, have led to a decision to extend the shelter at the cave exit to protect visitors from these ongoing rock fall events initiating from cliffs immediately above the cave exit. Three-dimensional rock fall simulations from sources at the top of these cliffs have provided data from which to assess the spatial frequencies and velocities of rock falls from the cliffs and to constrain the design of protective measures to reduce the rock fall hazard. Results from the rock fall simulations are consistent with the spatial patterns of rock fall impacts that have been observed at the cave exit site.     

Flood risk assessment for informal settlements

The urban informal settlements are particularly vulnerable to flooding events, due to both their generally poor quality of construction and high population density. An integrated approach to the analysis of flooding risk of informal settlements should take into account, and propagate, the many sources of uncertainty affecting the problem, ranging from the characterization of rainfall curve and flooding hazard to the characterization of the vulnerability of the portfolio of buildings. This paper proposes a probabilistic and modular approach for calculating the flooding risk in terms of the mean annual frequency of exceeding a specific limit state for each building within the informal settlement and the expected number of people affected (if the area is not evacuated). The flooding risk in this approach is calculated by the convolution of flooding hazard and flooding fragility for a specified limit state for each structure within the portfolio of buildings. This is achieved by employing the flooding height as an intermediate variable bridging over the fragility and hazard calculations. The focus of this paper is on an ultimate limit state where the life of slum dwellers is endangered by flooding. The fragility is calculated by using a logic tree procedure where several possible combinations of building features/construction details, and their eventual outcome in terms of the necessity to perform structural analysis or the application of nominal threshold flood heights, are taken into account. The logic tree branch probabilities are characterized based on both the orthophoto recognition and the sample in situ building survey. The application of the methodology is presented for Suna, a sub-ward of Dar es Salaam City (Tanzania) in the Msimbazi River basin having a high concentration of informal settlements.     

Role of slumped beds in the genesis and evolution of huge hypogean rooms: an example in the Valle del Nosê (Como,Northern Italy)

Abstract

During a detailed structural analysis of the cave systems of the Valle del Nosê (Como, Northern Italy), a systematic occurrence of thick (metric to decametric) slumped beds in several huge rooms and in other wide underground voids was observed. The systematic control, that these structures exert on the morphologies of the karst systems, suggests that slumped beds might play a major role in the genesis and evolution of large underground voids. In fact, thanks to their very high permeability, these beds seem to be able to act as the preferential way for water flowing in the very first phases of karst development, thus guiding cave development, while their mechanical properties, different from those of unslumped beds, make them prone to break down collapse, thus increasing the possibilities of the formation of huge rooms. On the basis of the observed field data, a genetic and evolutive model is therefore suggested to explain the origin of the largest voids in this area. This model has by now a strictly local effectiveness. © 2000 Éditions scientifiques et médicales Elsevier SAS     

Mineralogical and chemical evolution of ochreous precipitates from the Libiola Fe–Cu-sulfide mine (Eastern Liguria,Italy)

The mineralogical and chemical evolution of ochreous precipitates forming from acid mine drainage (AMD) from the abandoned Libiola Fe–Cu-sulfide mine (Eastern Liguria, Italy) was followed through a multianalytical approach (XRD, TEM, XRF, ICP) applied to surface precipitates and associated waters collected from several mine adits. The mineralogy of the precipitates changed significantly as a consequence of the variations of the chemical parameters of the circulating solutions (mainly pH, Eh, and sulfate concentrations) which, in turn, were mainly controlled by mixing with unpolluted stream and rill waters of the mining area. A progressive transition from jarosite-, to schwertmannite-, to goethite-, to ferrihydrite-, to amorphous-dominated precipitates was observed, mainly as a consequence of an increase in the pH of the associated solutions. This mineralogical evolution agrees well with the aqueous speciation and Eh–pH stability calculations performed on the waters associated with the different precipitate types. Furthermore, TEM analysis indicated that metastable pristine phases (schwertmannite) tend to transform progressively to well-crystallized more stable species, here represented by goethite. The comparison of the water chemistry and the crystal chemistry of the different precipitates showed a significant decrease in the Zn, Cu, Ni, Co contents in waters where the coexisting precipitates were almost exclusively composed of goethite. The distribution of V, Sr, As concentrations within the different precipitates showed that the most efficient scavenging phase for these elements was jarosite, whereas ferrihydrite efficiently took up Pb ions, and schwermannite acted as a natural sink for Cr.     

Copper Biosorption by Spent Coffee Ground: Equilibrium,Kinetics, and Mechanism

The potential use of spent coffee ground (SCG) for the removal of copper has been investigated as a low‐cost adsorbent for the biosorption of heavy metals. Adsorption batch experiments were conducted to determine isotherms and kinetics. The biosorption equilibrium data were found to fit well the Freundlich model and an experimental maximum biosorption capacity of copper ions 0.214 mmol/g was achieved. The biosorption kinetics of SCG was studied at different adsorbate concentrations (0.1–1.0 mM) and stirring speeds (100–400/min). The results showed an increase in the copper ion uptake with raising the initial metal concentration and the kinetic data followed the pseudo‐second order rate expression. The effect of stirring speed was a significant factor for the external mass transfer resistance at 100/min and coefficients were estimated by the Mathews and Weber model. Biosorption of copper ions onto SCG was observed to be related mainly with the release of calcium and hydrogen ions suggesting that biosorption performance by SCG can be attributed to ion‐exchange mechanism with calcium and hydrogen ions neutralizing the carboxyl and hydroxyl groups of the biomass.     

Representing the visibility structure of a polyhedral terrain through a horizon map

Abstract

We present a model for describing the visibility of a polyhedral terrain from a fixed viewpoint, based on a collection of nested horizons. We briefly introduce the concepts of mathematical and digital terrain models, and some background notions for visibility problems on terrains. Then, we define horizons on a polyhedral terrain, and introduce a visibility model, that we call the horizon map. We present a construction algorithm and a data structure for encoding the horizon map, and show how it can be used for solving point visibility queries with respect to a fixed viewpoint.     

The age of the Paludi Formation: a major constraint to the beginning of the Apulia-verging orogenic transport in the northern sector of the Calabria–Peloritani Arc

A stratigraphic revision of the Paludi Formation, cropping out in Northern Calabria on the north-eastern side of Sila Massif, has confirmed that it has been deposited between two main tectonic phases. Actually the formation is involved only by top to the north-east thrusts, different from those separating the crystalline and ophiolitic nappes of Northern Calabria, and rests unconformably on the Sila Unit, the uppermost nappe of the tectonic stack. In the frame of the interpretation of Northern Calabria as a fragment of the Alps, the Paludi Formation play the role of a deposit post-dating the eo-alpine tectonic phases and pre-dating the Apenninic orogenic transport. Therefore the Aquitanian age of the formation, obtained by nannofloras analyses, can be considered the minimum age to the Apulia-verging orogenic transport, witnessed by top to north-east thrusts. It fairly corresponds to the age referred to the Lucanian ocean closure.