Benthic mucilaginous aggregates in the Mediterranean Sea: Origin, chemical composition and polysaccharide characterization

Benthic mucilaginous aggregates are frequently formed in various parts of the Mediterranean basin, as in the Tyrrhenian and Adriatic Seas. Notwithstanding their wide spatial distribution, the role played by these aggregates in the biogeochemical cycling of organic matter is still largely unknown.The characteristics of the benthic aggregates examined in the present study showed that they are different from other mucilaginous aggregates, such as the “pelagic” ones that can form in the same areas in the water column and subsequently sediment to the seafloor. The aggregates are usually formed of structures of the filamentous macroalgae Acinetospora crinita, Chrysonephos lewisii and Nematochrysopsis marina. The elemental composition of the aggregates showed a marine macrophyte origin on the basis of the bulk organic matter content of the aggregates. Carbohydrates and proteins account for 26.6 to 55.9% of the organic carbon in the mucilage, respectively. Monosaccharide composition of exopolysaccharides in the mucilage aggregates revealed a characteristic pattern, with galactose, xylose or mannose and fucose as the major components. The relatively high content of deoxysugars is another distinctive feature. The abundant sulphate and uronic groups present in the polysaccharides in addition to their macromolecular dimensions and elongation contribute to inter-chain aggregation. Electron microscopic observations suggest that the polysaccharide fraction is the main macromolecular component in the formation of the persistent gel network in the aggregates.     

Phyllosilicate minerals in the hydrothermal mafic–ultramafic-hosted massive-sulfide deposit of Ivanovka (southern Urals): comparison with modern ocean seafloor analogues

We have studied textural relationships and compositions of phyllosilicate minerals in the mafic–ultramafic-hosted massive-sulfide deposit of Ivanovka (Main Uralian Fault Zone, southern Urals). The main hydrothermal phyllosilicate minerals are Mg-rich chlorite, variably ferroan talc, (Mg, Si)-rich and (Ca, Na, K)-poor saponite (stevensite), and serpentine. These minerals occur both as alteration products after mafic volcanics and ultramafic protoliths and, except serpentine, as hydrothermal vein and seafloor mound-like precipitates associated with variable amounts of (Ca, Mg, Fe)-carbonates, quartz and Fe and Cu (Co, Ni) sulfides. Brecciated mafic lithologies underwent pervasive chloritization, while interlayered gabbro sills underwent partial alteration to chlorite + illite ± actinolite ± saponite ± talc-bearing assemblages and later localized deeper alteration to chlorite ± saponite. Ultramafic and mixed ultramafic–mafic breccias were altered to talc-rich rocks with variable amounts of chlorite, carbonate and quartz. Chloritization, locally accompanied by formation of disseminated sulfides, required a high contribution of Mg-rich seawater to the hydrothermal fluid, which could be achieved in a highly permeable, breccia-dominated seafloor. More evolved hydrothermal fluids produced addition of silica, carbonates and further sulfides, and led to local development of saponite after chlorite and widespread replacement of serpentine by talc. The Ivanovka deposit shows many similarities with active and fossil hydrothermal sites on some modern oceanic spreading centers characterized by highly permeable upflow zones. However, given the arc signature of the ore host rocks, the most probable setting for the observed alteration–mineralization patterns is in an early-arc or forearc seafloor–subseafloor environment, characterized by the presence of abundant mafic–ultramafic breccias of tectonic and/or sedimentary origin.Editorial responsibility: J. Hoefs     

Predicting new snow density in the Italian Alps: A variability analysis based on 10 years of measurements

Despite its strong impact on the time evolution of the snowpack, current estimation of new snow density (ρ_hn) is usually accomplished either by using local empirical techniques or by assuming a constant snow density. Faced with the lack of an estimation model of ρ_hn valid for a wide spatial scale and supported by a suitable number of observations, this study aims to develop simple monthly linear regression models at scale of the entire Italian Alpine chain based on 12,112 snowfall observations at 122 stations, using only air temperature as predictor. Moreover, the remaining variance is investigated in both time and space, also considering some qualitative features of the snowfall events. The daily ρ_hn measurements present a mean value of 115 kg m^?3 (105 and 159 kg m^?3 for dry and wet conditions, respectively). The mean air temperature of the 24 hr preceding the snowfall event has been found to be the best predictor of the ρ_hn, within 31% of uncertainty. The analysis of associated residues allows supporting the idea that the adoption of a more local approach than the one analysed here is not able to substantially increase the predictive capabilities of the model. In fact, the main factor explaining the remaining variance over the air temperature is the wind, but in a complex orography, as mountain regions are, supplying realistic local wind fields is particularly challenging. Therefore, we conclude that using only the daily mean temperature as predictor is a good choice for estimating daily new snow density at scale of Italian Alpine chain, as well as at more regional scale.     

Large-Eddy Simulation of Atmospheric Boundary-Layer Flow Over Fluvial-Like Landscapes Using a Dynamic Roughness Model

A recently developed dynamic surface roughness model (Anderson and Meneveau, J Fluid Mech 679:288–314, 2011) for large-eddy simulation (LES) of atmospheric boundary-layer flow over multi-scale topographies is applied to boundary-layer flow over several types of fluvial-like landscapes. The landscapes are generated numerically with simulation of a modified Kardar–Parisi–Zhang equation (Passalacqua et al., Water Resour Res 42:WOD611, 2006). These surfaces possess the fractal-like channel network and anisotropic features often found in real terrains. The dynamic model is shown to lead to accurate flow predictions when the surface-height distributions exhibit power-law scaling (scale invariance) in the prevalent mean flow direction. In those cases, the LES provide accurate predictions (invariant to resolution) of mean velocity profiles. Conversely, some resolution dependence is found for applications in which the landscape’s streamwise spectra do not exhibit pure power-law scaling near wavenumbers corresponding to the LES grid resolution.     

Observations of the Ca <Emphasis Type="SmallCaps">ii</Emphasis> IR Triplet in High Luminosity Quasars: Exploring the Sample

We present a new spectroscopic sample of 11 quasars at intermediate redshift observed with the Infrared Spectrometer and Array Camera (ISAAC) on the ESO Very Large Telescope (VLT), covering O i λ8446 and the Ca ii triplet 8498, 8542, 8662. The new observations – that supplement the sample presented by Martínez-Aldama et al. (2015) – allow us to confirm the constraints on physical conditions and location of the region emitting the low ionization lines, as well as the relation between Ca ii and Fe ii.     

Toothed whales in the northwestern Mediterranean: insight into their feeding ecology using chemical tracers

Risso’s dolphins, pilot whales and sperm whales rarely strand in the northwestern Mediterranean. Thus, their feeding ecology, through the analysis of stomach contents, is poorly known. The aim of this study was to gain further insight into the segregation/superposition of the diet and habitat of Risso’s dolphins, pilot whales and sperm whales using chemical tracers, namely, stable isotopes (δ¹³C, δ¹⁵N) and organochlorines. Significantly different δ¹⁵N values were obtained in Risso’s dolphins (11.7 ± 0.7‰), sperm whales (10.8 ± 0.3‰) and pilot whales (9.8 ± 0.3‰), revealing different trophic levels. These differences are presumably due to various proportions of Histioteuthidae cephalopods in each toothed whale’s diet. Similar δ¹³C contents between species indicated long-term habitat superposition or corroborated important seasonal migrations. Lower congener 180 concentrations (8.20 vs. 21.73 μg.g⁻¹ lw) and higher tDDT/tPCB ratios (0.93 vs. 0.42) were observed in sperm whales compared with Risso’s dolphins and may indicate wider migrations for the former. Therefore, competition between these species seems to depend on different trophic levels and migration patterns.     

Rock fall simulation at Timpanogos Cave National Monument, American Fork Canyon, Utah, USA

Rock fall from limestone cliffs at Timpanogos Cave National Monument in American Fork Canyon east of Provo, Utah, is a common occurrence. The cave is located in limestone cliffs high on the southern side of the canyon. One fatality in 1933 led to the construction of rock fall shelters at the cave entrance and exit in 1976. Numerous rock fall incidents, including a near miss in 2000 in the vicinity of the trail below the cave exit, have led to a decision to extend the shelter at the cave exit to protect visitors from these ongoing rock fall events initiating from cliffs immediately above the cave exit. Three-dimensional rock fall simulations from sources at the top of these cliffs have provided data from which to assess the spatial frequencies and velocities of rock falls from the cliffs and to constrain the design of protective measures to reduce the rock fall hazard. Results from the rock fall simulations are consistent with the spatial patterns of rock fall impacts that have been observed at the cave exit site.     

High-pressure structural study of muscovite

The compressibility and structural variations of two 2M₁ muscovites having compositions (Na_0.07K_0.90 Ba_0.01□_0.02)(Al_1.84Ti_0.04Fe_0.07Mg_0.04)(Si_3.02Al_0.98) O₁₀ (OH)₂ (7 mole % paragonite) and (Na_0.37K_0.60□_0.03)(Al_1.84Ti_0.02 Fe_0.10Mg_0.06)(Si_3.03Al_0.97) O₁₀(OH)₂ (37 mole % paragonite) were determined at pressures between 1 bar and 35 kbar, by single-crystal X-ray diffraction using a Merrill-Bassett diamond anvil cell. Isothermal bulk moduli, setting K′ = 4, were 490 and 540 (± 30) kbar for the Na-poor and Na-rich samples respectively. Both samples show highly anisotropic compressibility patterns, with β _a ∶β _b ∶β _c = 1∶1.15∶3.95 for the Na-poor sample and β _a ∶β _b ∶β _c = 1∶1.19∶3.46 for the Na-rich one. HP structural refinements showed that the different compressibility was largely due to the partial substitution of Na for K in the interlayer region. Moreover, the different compressibility of the tetrahedral and octahedral layers, observed in both micas, increased the a rotation of the tetrahedral layer by about 2° in 28 kbar, as also indicated by the evolution of interlayer cation bond lengths. This increases the repulsion of oxygens of the basal layers and between the high-charged cations of the tetrahedral layer. As a consequence, phengitic substitution, reducing α rotation, would increase the baric stability of mica. Comparison between the HP structures of muscovite and phlogopite indicated the lower compressibility of the latter, mainly due to the greater compressibility of the dioctahedral layer with respect to that of the trioctahedral layer. The HT and HP behaviour of di- and trioctahedral micas showed an anisotropy in the compressional pattern which was markedly greater than that observed in the dilatation pattern. This unexpected result was explained by the different evolution with P and T of alkaliO bond lengths. By combining HP and HT data, a tentative equation of state of muscovite is proposed.