Elemental (C,N, H and P) and stable isotope (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) signatures in sediments from Zeekoevlei,South Africa: a record of human intervention in the lake

We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ¹³C_organic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ¹⁵N_organic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ¹⁵N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l⁻¹) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.     

Analysis of frequency shifting in seismic signals using Gabor-Wigner transform

A hybrid time-frequency method known as Gabor-Wigner transform(GWT) is introduced in this paper for examining the time-frequency patterns of earthquake damaged buildings. GWT is developed by combining the Gabor transform(GT) and Wigner-Ville distribution(WVD). GT and WVD have been used separately on synthetic and recorded earthquake data to identify frequency shifting due to earthquake damages, but GT is prone to windowing effect and WVD involves ambiguity function. Hence to obtain better clarity and to remove the cross terms(frequency interference), GT and WVD are judiciously combined and the resultant GWT used to identify frequency shifting. Synthetic seismic response of an instrumented building and real-time earthquake data recorded on the building were investigated using GWT. It is found that GWT offers good accuracy for even slow variations in frequency, good time-frequency resolution, and localized response. Presented results confirm the efficacy of GWT when compared with GT and WVD used separately. Simulation results were quantified by the Renyi entropy measures and GWT shown to be an adequate technique in identifying localized response for structural damage detection.     

Geospatial and geostatistical approach for groundwater potential zone delineation

Over the past few decades, groundwater has become an essential commodity owing to increased demand as a result of growing population, industrialization, urbanization and so on. The water supply situation is expected to become more severe in the future because of continued unsustainable water use and projected change in hydrometeorological parameters due to climate change. This study is based on the integrated approach of remote sensing, geographical information system and multicriteria decision‐making techniques to determine the most important contributing factors that affect the groundwater resources and to delineate the groundwater potential zones. Ten thematic layers, namely, geomorphology, geology, soil, topographic elevation (digital elevation model), land use/land cover, drainage density, lineament density, proximity of surface water bodies, surface temperature and post‐monsoon groundwater depth, were considered for the present study. These thematic layers were selected for groundwater prospecting based on the literature; discussion with the experts of the Central Ground Water Board, Government of India; field observations; geophysical investigation; and multivariate techniques. The thematic layers and their features were assigned suitable weights on Saaty's scale according to their relative significance for groundwater occurrence. The assigned weights of the layers and their features were normalized by using the analytic hierarchy process and eigenvector method. Finally, the selected thematic maps were integrated using a weighted linear combination method to create the final groundwater potential zone map. The final output map shows different zones of groundwater potential, namely, very good (16%), good (35%), moderate (28%) low (17%) and very low (2.1%). The groundwater potential zone map was finally validated using the discharge and groundwater depth data from 28 and 98 pumping wells, respectively, which showed good correlation. Copyright © 2014 John Wiley & Sons, Ltd.     

Optimal design of rain gauge network in the Middle Yarra River catchment,Australia

Rainfall data are a fundamental input for effective planning, designing and operating of water resources projects. A well‐designed rain gauge network is capable of providing accurate estimates of necessary areal average and/or point rainfall estimates at any desired ungauged location in a catchment. Increasing network density with additional rain gauge stations has been the main underlying criterion in the past to reduce error and uncertainty in rainfall estimates. However, installing and operation of additional stations in a network involves large cost and manpower. Hence, the objective of this study is to design an optimal rain gauge network in the Middle Yarra River catchment in Victoria, Australia. The optimal positioning of additional stations as well as optimally relocating of existing redundant stations using the kriging‐based geostatistical approach was undertaken in this study. Reduction of kriging error was considered as an indicator for optimal spatial positioning of the stations. Daily rainfall records of 1997 (an El Niño year) and 2010 (a La Niña year) were used for the analysis. Ordinary kriging was applied for rainfall data interpolation to estimate the kriging error for the network. The results indicate that significant reduction in the kriging error can be achieved by the optimal spatial positioning of the additional as well as redundant stations. Thus, the obtained optimal rain gauge network is expected to be appropriate for providing high quality rainfall estimates over the catchment. The concept proposed in this study for optimal rain gauge network design through combined use of additional and redundant stations together is equally applicable to any other catchment. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Petrological considerations for the demineralization of Rajmahal coals with <Emphasis Type="Italic">Pseudomonas mendocina</Emphasis> B6-1

The present study entails the results of the petrological coniderations for demineralization of Rajmahal Gondwana coals with Psudomonas mendocina B6-1. Inertinite group macerals are the dominant constituents of these coals, followed by vitrinite group, while liptinite occurs in low concentration. The amount of Mineral matter is moderately high. The concentration of major, minor and trace elements is high when compared with Clarke values. After the treatment of these coals with Pseudomonas mendocina strain B6-1, a significant reduction in the elemental content of oxygen, hydrogen and sulphur was observed. A gradual reduction of pyrite phase due to bioleaching was identified and its signatures were reflected in the XRD spectra and FTIR absorption bands. Over 5 % reduction in the ash content and decrease of major, minor and trace element to variable degrees were also noticed. Fe, As, and Ca positively correlate with the ash removal percentage indicating that the samples with high concentration of these elements were prone to demineralization with Pseudomonas mendocina strain B6-1 whereas Ni, Zn, Cr and Cu, negatively correlate with the ash removal percentage and shows that their enrichment impeded the process of demineralization. With increasing concentration of vitrinite the removal of major/minor/trace elements also increased which is attributed to the possible association of these elements with the mineral matter occurring as superficial mounting and superficial blanketing over the vitrinite macerals. This could facilitate the bacterial access to the elements to act upon and remove it to the variable extent. Some minerals occur intergrown with inertinites causing restricted bacterial action owing to the nonexposure of the mineral particles and less surface area available to the bacteria for bioleaching. Sulfur removal strongly relates with increase in inertinite content and decrease in liptinite content. This appears that sulfur associated with liptinites have shown difficult removal condition. The maximum removal of the trace elements like Cd, Cu, Co, Zn and Pb was observed from the ‘banded dull coal’ samples of the Rajmahal basin while maximum removal of major/minor elements like Fe, Ca and Mg was noticed from the ‘banded bright coal’ samples. However, maximum removal of Mn and As was also observed in the samples of ‘banded coal’.     

Magnetic and radiometric signatures over a Proterozoic massive sulfide setting of northern fringe of Dalma Volcanics,eastern India: An implication to metallogeny

Magnetic and radiometric surveys were carried out over a felsic dominated rifted margin of Proterozoic volcanic terrain of a mobile belt in the eastern India. The studies were made in blocks I and II of 0.65 sq km and 0.70 sq km respectively over a previously identified conductor in the northern fringe of Dalma Volcanics (DVs). In general, both the blocks show high magnetic signature associated with sulfide mineralisation. The interpretation of magnetic data suggests that nature of the causative source is mainly horizontal cylinder in both the blocks. The depth to the top of the causative source is about 25 m in both the blocks and extends upto 60 m in block I and 40m in block II. Gamma count rate exhibits about a factor of two to three enhancements above the field background for both the blocks. The obtained iso-rad maps are similar to uranium and copper belt in the Singhbhum shear zone south of the study area. The anomalous radiometric signature of the residual soil/rock of the area indicates towards hydrothermal alteration. The detailed magnetic surveys and preliminary iso-rads results seems quite encouraging and may be attributed to VMS setting in the area and potential sulfide mineralisation with uranium mineral association in the DVs province.