Geochemical evolution of groundwater in hard-rock aquifers of South India using statistical and modelling techniques

ABSTRACT

Multivariate statistical analysis and inverse geochemical modelling techniques were employed to deduce the mechanism of groundwater evolution in the hard-rock terrain of Telangana, South India. Q-mode hierarchical cluster analysis (HCA) and principal component analysis (PCA) were used to extract the hydrogeochemical characteristics and classify the groundwater samples into three principal groups. Use of thermodynamic stability diagrams and inverse geochemical modelling in PHREEQC identified the chemical reactions controlling hydrogeochemistry of each of the groups obtained from statistical analysis. The model output showed that a few phases are governing the water chemistry in this area and the geochemical reactions responsible for evolution of groundwater chemistry along the flow path are (i) dissolution of evaporite minerals (dolomite, halite); (ii) dissolution of primary silicate minerals (albite, anorthite, K-feldspar, biotite); (iii) precipitation of secondary silicate minerals (kaolinite, quartz, gibbsite, Ca-montmorillonite) along with anhydrite and calcite; and (iv) reverse ion exchange processes.     

Experimental and Numerical Flow Simulation over Weirs

Water Resources - This paper reports a series of experimental studies done to simulate the flow behavior over crump and ogee type of weirs. The transition of subcritical to supercritical flow, as...     

Impact of different sea surface roughness on surface gravity waves using a coupled atmosphere–wave model: a case of Hurricane Isaac (2012)

Ocean Dynamics - The complicated pattern of the chaotic ocean surface depends strongly on the interaction between wind and waves. An accurate representation of momentum and energy exchange at...     

Detrital and authigenic(?) baddeleyite (ZrO2) in ferromanganese nodules of Central Indian Ocean Basin

Occurrence of baddeleyite (ZrO2) which is a rare mineral has been recorded in ferromanganese nodules of Central Indian Ocean Basin (CIOB). The mineral occurs either as independent isolated sub-rounded to elliptical grains or in clusters forming fine subhedral crystals (<3 mm) within ferromanganese concretionary growth bands. The mode of occurrence, textural features and chemistry of the mineral suggest detrital and possibly an authigenic origin for baddeleyite. For authigenic origin it is proposed that zirconium might have got released either from the terrigenous sediments or the altered seafloor rocks forming halogen complexes and subsequently it has re-precipitated in the form of baddeleyite within manganese nodules under oxic to sub-oxic conditions.     

Calibration and validation of a general infiltration model

A general infiltration model proposed by Singh and Yu (1990) was calibrated and validated using a split sampling approach for 191 sets of infiltration data observed in the states of Minnesota and Georgia in the USA. Of the five model parameters, f_c (the final infiltration rate), S_o (the available storage space) and exponent ‘n’ were found to be more predictable than the other two parameters: m (exponent) and a (proportionality factor). A critical examination of the general model revealed that it is related to the Soil Conservation Service (1956) curve number (SCS‐CN) method and its parameter S_o is equivalent to the potential maximum retention of the SCS‐CN method and is, in turn, found to be a function of soil sorptivity and hydraulic conductivity. The general model was found to describe infiltration rate with time varying curve number. Copyright © 1999 John Wiley & Sons, Ltd.     

Spatial characteristics of landslides triggered by the 2015 M<Subscript>w</Subscript> 7.8 (Gorkha) and M<Subscript>w</Subscript> 7.3 (Dolakha) earthquakes in Nepal

High magnitude earthquakes trigger numerous landslides and their occurrences are mainly controlled by terrain parameters. We created an inventory of 15,551 landslides with a total area of 90.2 km² triggered by the 2015 M_w 7.8 (Gorkha) and M_w 7.3 (Dolakha) earthquakes in Nepal, through interpretation of very high resolution satellite images (e.g. WorldView, Pleiades, Cartosat-1 and 2, Resourcesat-2). Our spatial analysis of landslide occurrences with ground acceleration, slope, lithology and surface defomation indicated ubiquitous control of steep slope on landslides with ground acceleration as the trigger. Spatial distribution of landslides shows increasing frequency away from the Gorkha earthquake epicentre up to 130 km towards east, dropping sharply thereafter, which is an abnormal phenomenon of coseismic landslides. Landslides are laterally concentrated in three zones which matches well with the seismic rupture evolution of Gorkha earthquake, as reported through teleseismic measurements.     

Bacterial biosurfactants can be an ecofriendly and advanced technology for remediation of heavy metals and co-contaminated soil

Environmental pollution due to heavy metals has become a significant drawback as a result of their ecotoxicity. Hence, their remediation is of pressing concern. Many technologies are planned for their remediation; however, most of them are highly expensive and result in incomplete removal of contaminants. So, massive attention has paid to the event and application of the latest biologically techniques, that is effective in remedy and cost, not harming the prevailing surroundings. Hence, application of biosurfactant in heavy metal remediation is one among the recent ecofriendly technique. The present review critically highlights bacterial biosurfactants as a best alternative technique for heavy metals remediation. The review also emphasizes that bacterial biosurfactants can open up a new vista in remediation of metal-contaminated soil.     

Exploring the diverse potentials of <Emphasis Type="Italic">Planococcus</Emphasis> sp. TRC1 for the deconstruction of recalcitrant kraft lignin

Kraft lignin (KL) is the chief contaminant which is responsible for dark coloration, toxicity and high chemical oxygen demand (COD) of paper pulp mill effluent. The present study investigated the diverse potentials of Planococcus sp. TRC1 in the biodegradation of KL. Preliminary evaluation indicated that the strain was able to grow on broad spectrum of lignin-derived compounds, decolorize lignin-mimicking dyes and catabolize substrates of ligninolytic enzymes. Response surface methodology (RSM) was executed to perform the optimization of different process parameters. The results displayed that Planococcus sp. TRC1 could completely utilize 100 mg L^?1 of KL and 78% of 200 mg L^?1 of KL as sole source of carbon with concurrent reduction in COD and color. The biokinetic details of KL biodegradation showed that the values of \(\mu^{*}\), µ _max, \(q^{*}\) and q _max were 0.018 h^?1, 0.01 h^?1, 0.023 g g^?1 h^?1 and 0.05 g g^?1 h^?1, respectively. UV–visible spectrophotometry, SEM and FTIR indicated the significant alterations in the surface morphology, functional groups and chromophores during the course of biodegradation. XRD revealed the emergence of peak signifying the formation of low molecular weight intermediates after bacterial treatment. Considering the environmental impact, bacterial-treated KL illustrated less phytotoxicity using Vigna radiata seed bioassay. These results suggested that Planococcus sp. TRC1 could be a promising strain for the degradation of KL in an ecofriendly way.     

Swelling behaviour of expansive soil treated with fly ash–GGBS based binder

In this article, the potential of a binder developed by admixing fly ash and ground granulated blast furnace slag (GGBS) to stabilise expansive soils is evaluated. Laboratory tests included determination of free swell index, swell potential and swelling pressure tests of the soil/binder mixtures at different mixing ratio. The test results showed decrease in the swelling behaviour of the soil with increase in binder content. The percent swell–time relationship was observed to fit the hyperbolic curves enabling us to predict the ultimate percent swell from few initial test results. Addition of 1% of lime to the binder showed further improvement in reducing swelling. A good linear relationship is established between percent oedometer swell and modified free swell index (MFSI) for soil/binder mixtures without lime but the same has not been observed in the presence of lime. The compressibility characteristics of the soil/binder mixtures reduced nominally with increase in binder content but in the presence of lime, the compressibility reduced significantly. Binder used in this study has been found to be effective and economic to stabilise expansive soils with lesser amount of chemical additives such as lime.