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71.
72.
Studies of Mesozoic granites associated with rare earth element (REE)‐rich weathered crust deposits in southernmost Jiangxi Province indicate that they have high‐K to shoshonite compositions and belong to ilmenite‐series I‐type granites. Of the studied rocks at 59–292 ppm of bulk REE content, the highest are seen in the biotite granites of Dingnan (358, 429 ppm) and mafic biotite granite of the Wuliting Granite (344 ppm) near the Dajishan tungsten mine, both areas where weathered‐crust REE deposits occur. REE‐bearing accessory minerals in these granites are mainly zircon, apatite and allanite, and REE‐fluorocarbonates are common. REE enrichment occurs in the rims of apatite crystals, and in fluorocarbonates that occur along grain boundaries of and cracks in major silicate minerals, and in fluorocarbonates that replaced altered biotite. It is therefore thought that a major part of the REE content of these granites was concentrated during deuteric activity, rather than during magmatic crystallization. The crack‐filling REE‐fluorocarbonates could subsequently have been easily leached out and deposited in weathered crust developed during a long period of exposure. 相似文献
73.
An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H2S/HS–/SO
inf4
sup2–
. The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H2S+HH–=Au(HS)
2
–
+1/2H2 (K14); PtS+HS–+H+=Pt (HS)
2
0
(K15); PdS+HS–+H+=Pd (HS)
2
0
(K16); PtS2+H2=Pt (HS)
2
0
(K21).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H2 gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H2 at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits. 相似文献
74.
浙闽山区茶叶生产基地评价的探讨 总被引:6,自引:0,他引:6
茶叶基地的评价包括对基地的自然和经济条件的评估,应用系统分析方法,将自然和经济条件进行定量的综合评估,用综合评价值区分基地间的差异,最后定性与定量相结合,提出茶叶生产基地的合理布局. 相似文献
75.
We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California. 相似文献
76.
镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口,也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同:蛇绿岩以产出铬铁矿床为特征,阿拉斯加型岩体主要赋含铂族元素(PGE)矿床,大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关,但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程,而极少关注流体作用。近年来,实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用,同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为,刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素,已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题,总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录,提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用,强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。 相似文献
77.
火山渣丘,是火山区内的一种特殊的地质现象,以前地其成因国内外尚无详细探讨和描述,有的学者曾经统称为副火山。笔者通过实地调查,对这一结论提出新的见解,认为火山渣丘的形成是一复杂的地质现象,其成因具有多元性。这对探讨火山喷发规律,对火山地质地貌的准确描述与具有积极作用。 相似文献
78.
含煤层地质环境下地震波场的数值模拟 总被引:3,自引:2,他引:1
本文对含低速煤层地质环境下弹性波场多波多分量地震资料进行了二维数值模拟研究,对人工边界反射进行了有效处理,频散效应得到了有效的压制,对几种不同激发与观测排列方式下的弹性波资料进行了模型计算与分析。 相似文献
79.
80.
Monochromatic photographs of the Orion Nebula taken through narrow bandpass interference filters (Δλ=10 Å) centred on Hα, Hβ and [NII] lines are presented. Ratio contours of Hα/[NII] and Hα/Hβ are derived. They enable a detailed study of the point-to-point variation in ionization structure and temperature throughout the nebula. Dust located within the ionized gas is studied from the Hα/Hβ ratio which varies from point to point over the nebula. Its strongest concentration, apart in the obvious ‘dark bay’, occurs in a shell surrounding the exciting stars, with about 2′ of diameter. Close to Θ1 Ori the Hα/Hβ ratio, corrected for interstellar reddening, is about 3.0 in good agreement with the predicted value (Brocklehurst, 1971). To account for these measures, the following arguments are proposed:
- Dust grains are completely or partially destroyed in region close to the exciting stars.
- Radiation pressure and stellar wind push the remaining dust up to some equilibrium distance outwards. The consequence of this action is obviously the formation of a ‘dust mantle’ which is seen as a ring in projection.