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We present observations of the 1300 micron continuum emission and the C18O spectral-line emission from three well-studied giant molecular cloud cores: Orion, W49, and W51. The observations were obtained at the Five College Radio Astronomy Observatory, and they provide a means to examine the consistency of these two methods to trace the column density structure of molecular clouds. We find a good general correlation between the 1300 micron continuum, which traces the column density of dust, and the C18O J = 2 --> 1 line emission, which traces the column density of molecular gas, when the effects of source temperature are taken into consideration. Moreover, nominal values for the gas and dust abundances and the dust properties reproduce the observed continuum-to-line ratios. Thus, no strong C18O abundance gradients within sources has been found, and it appears that either the C18O emission lines or the submillimeter dust emission may be used to derive the mass column density within molecular clouds accurately.  相似文献   
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Thermoplastic resin pellets are melted and formed into an enormous number of inexpensive consumer goods, many of which are discarded after a relatively short period of use, dropped haphazardly onto watersheds and then make their way to the ocean where some get ingested by marine life. In 2003 and 2004 pre-production thermoplastic resin pellets and post-consumer plastic fragments were collected and analyzed for contamination for persistent organic pollutants (POPs). Samples were taken from the North Pacific Gyre, and selected sites in California, Hawaii, and from Guadalupe Island, Mexico. The total concentration of PCBs ranged from 27 to 980 ng/g; DDTs from 22 to 7100 ng/g and PAHs from 39 to 1200 ng/g, and aliphatic hydrocarbons from 1.1 to 8600 microg/g. Analytical methods were developed to extract, concentrate and identify POPs that may have accumulated on plastic fragments and plastic pellets. The results of this study confirm that plastic debris is a trap for POPs.  相似文献   
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The antifouling boosting agent Irgarol 1051 is a strong inhibitor of the photosystem II (PSII) with high efficiency/toxicity towards algae. However, because some phytoplankton species are more sensitive to Irgarol than others, its persistent release into the environment could result in adverse changes in the phytoplankton community structure at heavily impacted sites such as marinas. Continuous monitoring in the Florida Keys showed Irgarol concentrations of up to 635 ngL(-1) in the canal system leading to Key Largo Harbor Marina (KLH) with a sharp decrease in concentration at stations offshore from the mouth of the canal. Preliminary phytoplankton community assessments from surface water samples collected in KLH between February and August 2004 showed changes in several phytoplankton species in concordance with the increase of the herbicide concentrations. Typical responses include an increase in the abundance of eukaryotes and Cryptomonas sp. as Irgarol concentrations increase.  相似文献   
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一般认为,地面气压等于流体静力大气单位面积上的重量。但这只对笛卡尔天体才是正确的。这里,单位面积是指大气柱底部的表面积。对于圆柱形行星或球形行星来说,其表面气压总量是小于单位面积上大气的重量。在曲面上,侧向压力有助于支撑气柱,从而减少了气柱底部的气压。据计算,其表面气压比类似于地球上的静止大气单位面积上的重量小0.25%。  相似文献   
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Antifouling paints on small to medium recreational vessels were first recognized as an important source of pollution in the 1970s. One of the principle biocides in these paints is Cu. Results from a field program in the Gold Coast Broadwater, Queensland, demonstrate a clear correlation between recreational boat numbers at anchorage sites and water column Cu concentrations, for both time-integrated 24 h DGT measurements (n=14, r=0.815, p<0.001) and measurements on composite 0.45 mum-filtered grab samples (n=14, r=0.698, p<0.01) collected every 4 h over 24 h. At boat numbers above 30 the 0.45 microm-filterable Cu concentrations were mostly above the relevant guideline value (1.3 microgl(-1)) but the DGT-reactive Cu concentrations were well below this value at all boat numbers studied. For three-day DGT deployments in Moreton Bay, Queensland, correlations between Cu levels and vessel numbers were not observed, possibly because of uncertain estimates of boat numbers. However, using a multi-factorial ANOVA, DGT-reactive Cu concentrations showed a significant effect for 'sites with vessels vs. sites without vessels' (alpha=0.10, p=0.077) and for 'sampling period' (non-holiday weekdays, weekends, holiday weekdays, holiday weekends) at alpha=0.10, p=0.02. Cu levels in sediments at the same sites were strongly influenced by fraction of clay (<63 microm) material but also by whether the samples were collected at an anchorage or control site. Results from this study further support the view that Cu emissions from antifouling paints may become an important source in waters with high boat numbers and should be taken into account when designing management instruments for coastal waterways.  相似文献   
19.
Aquifer vulnerability to pesticide migration through till aquitards   总被引:1,自引:0,他引:1  
This study investigates the influence of key factors-mainly recharge rate and degradation half-life--on downward migration of the widely used pesticide mecoprop (MCPP) through a typical clayey till aquitard. The study uses the numerical model FRAC3Dvs, which is a three-dimensional discrete fracture/matrix diffusion (DFMD) numerical transport model. The model was calibrated with laboratory and field data from a site near Havdrup, Denmark, but the overall findings are expected to be relevant to many other sites in similar settings. Fracture flow and MCPP transport parameters for the model were obtained through calibration using well-characterized laboratory experiments with large (0.5 m diameter by 0.5 m high) undisturbed columns of the fractured till and a field experiment. A second level of upscaling and sensitivity analysis was then carried out using data on hydraulic head, fracture spacing, and water budget from the field site. The simulations of downward migration of MCPP show that MCPP concentration and mass flux into the underlying aquifer, and hence the aquifer vulnerability to this pesticide compound, is mainly dependent on the degradation rate of the pesticide, the overall aquitard water budget, and the ground water recharge rate into the aquifer. The influence of flow rate, matrix diffusion, and degradation rate are intertwined. This results in one to four orders of magnitude higher MCPP flux into the aquifer from aquifer recharge rates of 20 and 120 mm/yr, respectively, for no degradation and MCPP half-life of 0.5 yr. From a sensitivity analysis it was found that the range of MCPP flux into the aquifer varied less than one order of magnitude due to (1) changing fracture spacing from 1 to 10 m, or (2) preferential flow along inclined thin sand layers, which represent common conditions for the current and other settings of clayey till in Denmark and other glaciated areas in Europe and North America. The results indicate that for aquifers overlain by fractured clayey tills, the vulnerability to contamination with pesticides (pesticide flux into the aquifer) and other widespread agricultural contaminants is going to vary strongly in the watershed as a function of the distribution of aquitard water budget (flow rate) and aquitard redox environment (controlling contaminant degradation rates), even if the thickness of the till is relatively constant. DFMD modeling of cause-effect relationships within such systems has great potential to support decisions in planning, regulation, and contaminant remediation.  相似文献   
20.
An ELISA for cod vitellogenin (VTG) has been set up using cod lipovitellin for plate coating and standardisation. The assay has been applied to plasma samples collected from male and female cod caught in three distinct areas around the UK, three areas off the Norwegian coast and also to cod reared initially at an aquaculture site and subsequently maintained at a research station. The aim of the study was to determine whether there were any signs of oestrogenic endocrine disruption in a fish species living offshore. VTG induction was found in male cod caught in the North Sea, the Shetland Box area, in Oslofjord and also in cultivated fish. There was a strong relationship between concentrations of VTG and fish size. There was no evidence that the presence of VTG in the plasma of males is a natural part of their life cycle. On the other hand, the size of fish at which these elevated VTG concentrations appear (ca. 5 kg) is about the size that cod change from feeding primarily on benthic invertebrates to mainly other fish, both benthic and pelagic. The possibility is suggested that large cod pick up oestrogenic endocrine disrupters through the food chain.  相似文献   
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