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81.
Darren?G.?ChertkoffEmail author James?E.?Gardner 《Contributions to Mineralogy and Petrology》2004,146(6):715-735
Volcán Ceboruco, Mexico, erupted ~1,000 years ago, producing the Jala pumice and forming a ~4-km-wide caldera. During that eruption, 2.8 to 3.5 km3 of rhyodacite (~70 wt% SiO2) magma and 0.2 to 0.5 km3 of mixed dacite (~67 wt% SiO2) magma were tapped and deposited as the Jala pumice. Subsequently, the caldera was partially filled by extrusion of the Dos Equis dome, a low-silica (~64 wt% SiO2) dacite dome with a volume of ~1.3 km3. Petrographic evidence indicates that the Jala dacite and Dos Equis dacite originated largely through the mixing of three end-member magmas: (1) rhyodacite magma, (2) dacite magma, and (3) mafic magma. Linear least-squares modeling and detailed modal analysis indicate that the Jala dacite is predominantly a bimodal mixture of rhyodacite and dacite with a small additional mafic component, whereas the Dos Equis dacite is composed of mostly dacite mixed with subordinate amounts of rhyodacite and mafic magma. According to Fe–Ti oxide geothermometry, before the caldera-forming eruption the rhyodacite last equilibrated at ~865 °C, whereas the dacite was originally at ~890 °C but was heated to ~960 °C by intrusion of mafic magma as hot as ~1,030 °C. Zoning profiles in plagioclase and/or magnetite phenocrysts indicate that mixing between mafic and dacite magma occurred ~34–47 days prior to eruption, whereas subsequent mixing between rhyodacite and dacite magmas occurred only 1–4 days prior to eruption. Following the caldera-forming eruption, continued inputs of mafic magma led to effusion of the Dos Equis dome dacite. In this case, timing between mixing and eruption is estimated at ~93–185 days based on the thickness of plagioclase overgrowth rims.Editorial responsibility: T.L. Grove 相似文献
82.
The decline of the British shipping industry has had a significant impact on those sectors of the UK economy which have traditionally relied on ex-seafarers as a source of skilled labour. An in-depth study of the impacts of this problem was undertaken in 2003 to consider the implications of developments which have taken place in the industry since 1996. The UK economy's requirement for people with seafaring experience to fill land-based jobs was assessed, together with the implications of any shortfall. This paper considers the demand aspects of changes which have occurred since 1996. 相似文献
83.
People with seafaring experience and skills are employed in the maritime sector of the UK economy in land-based jobs as well as in seagoing ones. This paper examines the balance of supply and demand in the land-based jobs market. It then considers the likely effects of a shortfall in the supply of British ships’ officers to fill net vacancies in jobs ashore, including the policy implications of this and the consequences for the economy's maritime skills base if the Government fails to act decisively now to correct market failure. 相似文献
84.
The use of small volumes of sample and reagents permits the adaption of a copper-coated cadmium column to the manual analysis of nitrate in seawater. The apparatus used for this modification is described. 相似文献
85.
The glutathione S-transferases (GST) are a major group of conjugative enzymes involved in the detoxification of electrophilic compounds and products of oxidative stress. We have previously described the kinetics of hepatic GST conjugation in largemouth bass using a variety of synthetic GST reference substrates. In the present study, we investigated the ability of largemouth bass hepatic GSTs to conjugate 4-hydroxynon-2-enal (4HNE), a mutagenic and cytotoxic alpha-beta-unsaturated aldehyde produced during oxidative injury. Hepatic cytosolic fractions from largemouth bass rapidly catalyzed GSH-dependent 4HNE conjugation, with the rate of GST-4HNE conjugation in bass liver exceeding those of several other mammalian and aquatic species. No apparent sex-related differences in GST-4HNE activity were observed among adult bass. SDS-PAGE and Western blotting analysis of GSH affinity-purified bass liver cytosolic GST revealed the presence of two major GST subunits of approximately 30 and 27 KDa that exhibited slight cross-reactivity when probed with a rat alpha class GST antibody, but not to rat mu, pi or theta class GST. The rapid conjugation of 4HNE by hepatic GST suggests an important role for GSTs in protecting against peroxidation of polyunsaturated fatty acids in bass liver. 相似文献
86.
Estimating nitrogen transformation rates in aquatic ecosystems by isotope dilution techniques is simplified by directly measuring nitrogen isotopic ratios for NH4+ in the water using high performance cation exchange liquid chromatography (HPLC). Modifications of HPLC conditions and implementation of a median-area method for retention time determination improved and linearized a previously reported sigmoid relationship between the retention time shift (RTshift) of the NH4+ peak and the ratio of [15NH4+]: [Total NH4+] in seawater fortified with 15NH4+. Increasing the temperature of the HPLC column from 47 to 85 °C increased mobile phase buffer flow rate relative to column back pressure, decreased the retention time for NH4+, and allowed the buffer pH to be optimized relative to the pK of NH4+. The use of median-area rather than maximum-height to define the retention time of NH4+ further improved the linearity (r > 0.995) of the relationship between the ratio [15NH4+]: [Total NH4+] and RTshift over the range of isotope ratios. Reduction of NO3− to NH4+ by adding zinc dust to acidified (pH 2) seawater or lakewater samples, followed by pH neutralization, and subsequent analysis of NH4+ isotope ratios by HPLC, extended application of the method to isotope dilution experiments with NO3−. Advantages of this direct-injection method over mass-measurement approaches traditionally used for isotope dilution experiments include small sample size and minimal sample preparation. 相似文献
87.
Major alterations in the distribution of peripheral blood cells were observed among winter flounder (Pseudopleuronectes americanus) from Martha's Vineyard (MV), East Cape Cod Bay (ECCB), Fox Island (FI) (Narragansett Bay), Central Long Island Sound (CLIS), Gaspee Point (GP) (Narragansett Bay), Black Rock Harbor (BRH) (Bridgeport, CT), New Bedford Harbor (NBH) and Quincy Bay (QB) (Boston Harbor). Collection locations ranged from relatively uncontaminated offshore (MV) and nearshore (ECCB) sites to the more contaminated estuarine (FI, CLIS) and urban embayments (GP, BRH, NBH, QB). Differential diagnosis demonstrated a shift in lymphocyte counts from 28% (MV) to 54% (QB) that increased with the incidence of liver lesions in relation to known and suspected levels of sediment chemical contamination. A significant change in the ratio of circulating immature to mature erythrocytes was observed in flounder collected from Boston Harbor. Immature erythrocytes comprised 18% of the total erythrocyte population of fish from QB in comparison to 6% observed in flounder from ECCB. 相似文献
88.
89.
In the weeks following the 2011 Rena oil spill, a series of surveys was initiated on eight rocky intertidal reefs to describe the distribution of oil and to assess the impacts of oil on ecological communities. Consistent but relatively low cover of oil occurred at two sites (Mt Maunganui and Moturiki). The area covered by oil had decreased by c. 90% after 5 months due to natural weathering processes. There were immediate effects of oil fouling on the mussel Limnoperna pulex and its associated fauna, with reductions in the number of mussels and infaunal taxonomic richness. However, no ecological effects on any of the communities were detectable after 1 month. Overall, the ecological effects of the Rena oil spill on rocky shore intertidal communities were small and not long-lasting, but we stress that this does not consider potential sublethal effects and their consequences on organisms. 相似文献
90.
Daniel D.P. McCarthy Graham S. Whitelaw Scott Anderson Donald Cowan Fred McGarry Anthony Robins Holly L. Gardner Christine D. Barbeau Nadia A. Charania Zachariah General Jeff Liedtke Celine Sutherland Paulo Alencar Leonard J.S. Tsuji 《Geoforum》2012,43(2):305-314
The remote First Nation (FN) communities of the Mushkegowuk Territory on the west coast of James Bay, Ontario, Canada are currently facing increased development pressures and the imposition of a government land use planning process. The land use planning process is mandated in the Far North Act (received Royal Assent on September 23, 2010). There is a need for capacity enhancement for community-based natural resource planning and management in the Territory. A number of frameworks are emerging for addressing change brought on by resource development and building resilience to such change at the community level. Among these include the concept of adaptive capacity. In collaboration with FN community leaders, we explored the use of “collaborative geomatics” tools to foster adaptive capacity. Our action research suggests that collaborative geomatics technologies should enhance the Mushkegowuk First Nations’ adaptive capacity to address environmental and policy change by allowing them to collect and manage data collaboratively (e.g., traditional environmental knowledge, western science) to create opportunities for innovative community development, including natural resource development and management. 相似文献