Biosorption characteristics of heavy metals (Ni2+, Zn2+, Cd2+, Pb2+) from aqueous solution by Hizikia fusiformis

Heavy metal ions (Pb²⁺, Cd²⁺, Ni²⁺, and Zn²⁺) were biosorbed by brown seaweed (Hizikia fusiformis), which was collected from Jeju Island of South Korea. The metal adsorption capacity of H. fusiformis improved significantly by washing with water or by base or acid treatments. The maximum sorption by NaOH-pretreated biomass was observed near a slightly acidic pH (pH 4?6) for Pb²⁺, Cd²⁺, Ni²⁺, and Zn²⁺. This result suggests that the treatment of H. fusiformis biomass with NaOH helped increase the functional forms of carboxylate ester units. Kinetic data showed that the biosorption occurred rapidly during the first 60 min, and most of the heavy metals were bound to the seaweed within 180 min. The maximum metal adsorption capacities assumed by a Langmuir model were on the order of Pb²⁺ > Cd²⁺ > Ni²⁺ > Zn²⁺. Equilibrium adsorption data for the heavy metal ions could fit well in the Langmuir model with regression coefficients R ² > 0.97.     

Effect of rainfall characteristics on removal efficiency evaluation in vegetative filter strips

The efficiency of a facility to remove non-point source pollution is likely to fluctuate according to conditions such as facility type and rainfall events; therefore, it is required to use a proper method to estimate removal efficiency. This study was conducted to estimate the efficiency of a facility with vegetative filter strips to remove pollutants by using methods previously used for the estimation of removal efficiency and compensate for weaknesses of the known methods. Other ways were presented to estimate an efficiency by which rainfall events were classified according to meteorological condition and amount of rainfall. Rainfall of frequency and summation of load as rainfall of frequency, where the frequencies per rainfall class were considered in efficiency ratio and summation of loads, respectively, seemed to have higher removal efficiencies than those estimated with the previous methods. Although it rained at the basin site, often in small quantity (below 10 mm), the rainfall events of below 10 mm were less frequent, during the monitored rainfall events, which accordingly resulted in low removal efficiencies. However, if the frequencies per rainfall class were considered, overall removal efficiencies of VFS might be increased because the removal efficiencies of the rainfall class under 10?mm was higher than other rainfall classes. Therefore, it is desirable to take into account such factors as effects of rainfall when it comes to measuring the removal efficiency of a non-point source pollutant of a factor, because those facilities are likely to be influenced by meteorological conditions including rainfall characteristics.     

Paleoenvironmental analysis of the Mawaki archaeological site,central Japan,in relation to the stratigraphic position of dolphin bones

In order to elucidate the paleoenvironment associated with the early Holocene Mawaki archaeological site on the Noto Peninsula of central Japan, a high‐resolution stratigraphic study was conducted of 17 boreholes drilled at the archaeological site. We selected three boreholes for which lithological and/or chronological data are reported. Initial magnetic susceptibility was utilized for correlation of clastic core samples with the assistance of 26 radiocarbon dates. Four lithological units (A, B, C, and D in ascending order) were identified and interpreted as a sequence in a cycle of marine transgression and regression. Dated coastal horizons were chosen to indicate former sea levels. A Holocene relative sea level curve was generated on the basis of the geological data, and a rapid rise from 8000cal. yr B.P. to 7000cal. yr B.P. and a succeeding minor sea level fall represent the basic eustatic trend around the Sea of Japan because hydroisostatic and tectonic effects are moderate in the study area. Abundant dolphin bones lay just above the top of the marine sequence (boundary between Units C and D), located in the seashore environment. Cultural artifacts are found in a subaerial deposit (Unit D) near the dolphin bone level that is assigned to a period of high, stable sea level after the post‐glacial eustatic highstand. Dolphin bones are associated with stone artifacts (arrowheads, knives, and scrapers) and ritual wood columns, indicating the presence of a longstanding fishery during the early Holocene on the Sea of Japan coast. © 2011 Wiley Periodicals, Inc.     

Reinforcement and Arching Effect of Geogrid-Reinforced and Pile-Supported Embankment on Marine Soft Ground

The effectiveness of constructing a geogrid-reinforced and pile supported embankment on soft ground to reduce differential settlement has been studied by pilot scale field tests and numerical analysis. Three-by-three pile groups with varying pile spacing were driven into a layer of soft ground, and a layer of geogrid was used as reinforcement over each pile group. Further, a 2-D numerical analysis has been conducted using the computer program FLAC 2D. The mechanisms of load transfer can be considered as a combination of embankment soil arching, geogrid tension, and stress transfer due to the difference in stiffness between pile and soft ground. Based on the pilot scale field tests and results of numerical analysis, we find that the geosynthetic reinforcement slightly interferes with soil arching, and helps reduce differential settlement of the soft ground. Also, the most effective load transfer and vertical stress reduction at the midspan between piles occurs when the pile cap spacing index D/b (D: pile cap spacing, b: diameter of pile) is 3.0.     

Seasonal variations in the low-salinity intermediate water in the region south of sub-polar front of the East Sea (Sea of Japan)

Seasonal variations in the low-salinity intermediate water (ESIW) in the region south of the sub-polar front of the East Sea were investigated by using historical hydrographic data. The salinity of the representative density (sigma-0=27.2) of the ESIW was minimal in summer and maximal in winter in the region south of the sub-polar front. The selected four subregions showed different salinity variations. In the west of Oki Spur and the Yamato Basin, salinity fluctuated similarly, with a minimum during summer. In the Ulleung Basin and northwest of Sado Island, however, variations in salinity showed two minima, one is in winter and the other is in summer. These results imply differences in the flow path of the ESIW into the region south of the sub-polar front over time.     

Projected Heat Wave Characteristics over the Korean Peninsula During the Twenty-First Century

Climate change is expected to increase temperatures globally, and consequently more frequent, longer, and hotter heat waves are likely to occur. Ambiguity in defining heat waves appropriately makes it difficult to compare changes in heat wave events over time. This study provides a quantitative definition of a heat wave and makes probabilistic heat wave projections for the Korean Peninsula under two global warming scenarios. Changes to heat waves under global warming are investigated using the representative concentration pathway 4.5 (RCP4.5) and 8.5 (RCP8.5) experiments from 30 coupled models participating in phase five of the Coupled Model Inter-comparison Project. Probabilistic climate projections from multi-model ensembles have been constructed using both simple and weighted averaging. Results from both methods are similar and show that heat waves will be more intense, frequent, and longer lasting. These trends are more apparent under the RCP8.5 scenario as compared to the RCP4.5 scenario. Under the RCP8.5 scenario, typical heat waves are projected to become stronger than any heat wave experienced in the recent measurement record. Furthermore, under this scenario, it cannot be ruled out that Korea will experience heat wave conditions spanning almost an entire summer before the end of the 21st century.     

Intercomparison of Planetary Boundary-Layer Parametrizations in the WRF Model for a Single Day from CASES-99

This study compares five planetary boundary-layer (PBL) parametrizations in the Weather Research and Forecasting (WRF) numerical model for a single day from the Cooperative Atmosphere-Surface Exchange Study (CASES-99) field program. The five schemes include two first-order closure schemes—the Yonsei University (YSU) PBL and Asymmetric Convective Model version 2 (ACM2), and three turbulent kinetic energy (TKE) closure schemes—the Mellor–Yamada–Janjić (MYJ), quasi-normal scale elimination (QNSE), and Bougeault–Lacarrére (BouLac) PBL. The comparison results reveal that discrepancies among thermodynamic surface variables from different schemes are large at daytime, while the variables converge at nighttime with large deviations from those observed. On the other hand, wind components are more divergent at nighttime with significant biases. Regarding PBL structures, a non-local scheme with the entrainment flux proportional to the surface flux is favourable in unstable conditions. In stable conditions, the local TKE closure schemes show better performance. The sensitivity of simulated variables to surface-layer parametrizations is also investigated to assess relative contributions of the surface-layer parametrizations to typical features of each PBL scheme. In the surface layer, temperature and moisture are more strongly influenced by surface-layer formulations than by PBL mixing algorithms in both convective and stable regimes, while wind speed depends on vertical diffusion formulations in the convective regime. Regarding PBL structures, surface-layer formulations only contribute to near-surface variability and then PBL mean properties, whereas shapes of the profiles are determined by PBL mixing algorithms.     

A scattering-based over-land rainfall retrieval algorithm for South Korea using GCOM-W1/AMSR-2 data

Heavy summer rainfall is a primary natural disaster affecting lives and properties in the Korean Peninsula. This study presents a satellite-based rainfall rate retrieval algorithm for the South Korea combining polarization-corrected temperature (PCT) and scattering index (SI) data from the 36.5 and 89.0 GHz channels of the Advanced microwave Scanning Radiometer 2 (AMSR-2) onboard the Global Change Observation Mission (GCOM)-W1 satellite. The coefficients for the algorithm were obtained from spatial and temporal collocation data from the AMSR-2 and groundbased automatic weather station rain gauges from 1 July - 30 August during the years, 2012-2015. There were time delays of about 25 minutes between the AMSR-2 observations and the ground raingauge measurements. A new linearly-combined rainfall retrieval algorithm focused on heavy rain for the PCT and SI was validated using ground-based rainfall observations for the South Korea from 1 July - 30 August, 2016. The validation presented PCT and SI methods showed slightly improved results for rainfall > 5 mm h^-1 compared to the current ASMR-2 level 2 data. The best bias and root mean square error (RMSE) for the PCT method at AMSR-2 36.5 GHz were 2.09 mm h^-1 and 7.29 mm h^-1, respectively, while the current official AMSR-2 rainfall rates show a larger bias and RMSE (4.80 mm h^-1 and 9.35 mm h^-1, respectively). This study provides a scatteringbased over-land rainfall retrieval algorithm for South Korea affected by stationary front rain and typhoons with the advantages of the previous PCT and SI methods to be applied to a variety of spaceborne passive microwave radiometers.     

Critical influence of the pattern of Tropical Ocean warming on remote climate trends

Evidence is presented that the recent trend patterns of surface air temperature and precipitation over the land masses surrounding the North Atlantic Ocean (North America, Greenland, Europe, and North Africa) have been strongly influenced by the warming pattern of the tropical oceans. The current generation of atmosphere–ocean coupled climate models with prescribed radiative forcing changes generally do not capture these regional trend patterns. On the other hand, even uncoupled atmospheric models without the prescribed radiative forcing changes, but with the observed oceanic warming specified only in the tropics, are more successful in this regard. The tropical oceanic warming pattern is poorly represented in the coupled simulations. Our analysis points to model error rather than unpredictable climate noise as a major cause of this discrepancy with respect to the observed trends. This tropical error needs to be reduced to increase confidence in regional climate change projections around the globe, and to formulate better societal responses to projected changes in high-impact phenomena such as droughts and wet spells.     

Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries

Contamination of persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDT and its metabolites (DDTs), HCH (hexachlorocyclohexane) isomers (HCHs), chlordane compounds (CHLs), and HCB (hexachlorobenzene) were examined in mussels collected from coastal waters of Asian countries such as Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, Philippines, Far East Russia, Singapore, and Vietnam in 1994, 1997, 1998, 1999, and 2001 to elucidate the contamination status, distribution and possible pollution sources and to assess the risks on aquatic organisms and human. OCs were detected in all mussels collected from all the sampling sites investigated. Considerable residue levels of p,p(')-DDT and alpha-HCH were found in mussels and the concentrations of DDTs and HCHs found in mussels from Asian developing countries were higher than those in developed nations suggesting present usage of DDTs and HCHs along the coastal waters of Asian developing countries. On the other hand, lower concentrations of PCBs detected in mussels from Asian developing countries than those in developed countries indicate that PCBs contamination in mussels is strongly related to industrial and activities. To our knowledge, this is a first comprehensive report on monitoring OCs pollution in the Asia-Pacific region.