Marine carbonate systems in the Sarmatian (Middle Miocene) of the Central Paratethys: the Zsámbék Basin of Hungary

The study of eight stratigraphic sections at the margin of the semi-enclosed Zsámbék Basin (Hungary) allows the sedimentary anatomy of oolitic–bioclastic systems in the Sarmatian of the Central Paratethys to be reconstructed. The mollusc, foraminiferal and ostracod associations indicate that the carbonate systems are Latest Badenian to Late Sarmatian in age. The Lower–Upper Sarmatian deposits are organized in superimposed subaqueous dunes prograding towards the basin on a low-angle ramp. During the Late Sarmatian, the ramp underwent subaerial erosion linked to a moderate relative fall in sea-level. Lagoonal deposits were later formed and microbial–nubeculariid–bryozoan–serpulid buildups were emplaced. The 'abnormal' marine conditions of the Sarmatian, conducive to the development of a poorly diversified flora and fauna and dominant non-skeletal grains, are linked to fluctuating salinities, mesotrophic to eutrophic conditions and perhaps high alkalinity.     

CONDITIONAL SAMPLING AND SCALE ANALYSIS OF THE MARINE ATMOSPHERIC MIXED LAYER -- SOFIA EXPERIMENT

During the SOFIA experiment, performed in the Azores region in June1992, airborne missions were conducted in the atmospheric boundary layerwith two aircraft instrumented for turbulence measurements. We show howthe conditional sampling technique, applied to the velocity, temperatureand moisture fluctuations, is able to describe the various parcels whichconstitute the turbulent field. Each parcel, so identified, is characterized byits fractional area and by its contribution to the transfers of sensible heat andlatent heat. On the other hand, a scale analysis is conducted by filteringthe turbulent signals in five non-overlapping frequency bands, definedaccording to the characteristic turbulent scales. The contribution of eachband to the turbulent energy and to the transfers is thus presented. Theimportance of the lowest frequencies, which are generally removed fromthe signals by high-pass filtering before computing turbulent fluxes, isshown. In the final section, the conditional sampling technique is applied tothe signals filtered in the various bands. Despite a slight deformation of theeddies due to the filtering technique, the contribution of each parcel can beestimated at the various scales analysed.     

LIDAR DETERMINATION OF THE ENTRAINMENT ZONE THICKNESS AT THE TOP OF THE UNSTABLE MARINE ATMOSPHERIC BOUNDARY LAYER

The thickness of the entrainment zone at the top of the marine atmosphericboundary layer (MABL) has been documented by an airborne lidar on twoconsecutive days during a cold-air outbreak episode over the Mediterranean.In addition to the lidar observations, in situ turbulent flux measurementsat three levels in the MABL were made by a second aircraft. The flights' tracksare broken down in segments 25–30 km long and the data are filtered for theparametrization of turbulent entrainment in the MABL at scales smaller thana few kilometres. The structural parameters of the entrainment zone aredetermined by lidar from the distributions of the instantaneous MABL topheight. The average values Ph0 and Ph2 of the cumulativeprobability distributions are used to define the bottom and top heights of the entrainment zone h0 and h2, respectively. The parameters h0 andh2 are calculated by reference to a linear vertical buoyancy flux profilein the framework of a first-order jump model. The model is constrained by bothlidar and in situ data to determine Ph0 and Ph2 and so h0and h2. In unstable conditions theaverage fraction Ph0 is estimated to be 6.0 ± 1%. It is shown to beslightly sensitive to the presence of cloud at small cloud fractions.The mean value of the ratio of the inversion level buoyancy flux to the surfacebuoyancy flux ARv is found to range from 0.15 to 0.30 depending on the shearin the MABL. The average value is 0.22 ± 0.05. Our resultsare in good agreement with previous analysis at comparable spatial scales.In purely convective conditions, the value of ARv given by theparametrizations fitted to our results is about 0.10–0.12, a value smallerthan the commonly accepted value of 0.2. When compared to previousparametrization results, our proportionality constant for the mechanicalproduction of turbulent kinetic energy is also found to be scaled down, ingood agreement with large-eddy simulation results. It is suggestedthat mesoscale organized motions in the MABL is the source of thisdifference.     

Origin of polyhalite deposits in the Zechstein (Upper Permian) Zdrada platform (northern Poland)

Polyhalite deposits in the Zechstein (Upper Permian) of northern Poland occur in the Lower Werra Anhydrite. In the Zdrada Sulphate Platform, the polyhalite appears to be a very early replacement of anhydrite. The replacement was caused by the halite-precipitating brines which contained potassium and magnesium ions. The formation of polyhalite was preceded by the syndepositional anhydritization of the original gypsum deposit which has often preserved its primary textures. This anhydritization on the platform and its slopes was a reaction of the precipitated gypsum in a hydrologically open evaporite basin, with brines of salt basins adjacent to the sulphate platform. These brines, when nearly saturated with respect to halite, and potassium and magnesium rich, reacted with anhydrite to precipitate polyhalite along the slopes of the Zdrada Platform. The oxygen and sulphur isotopic compositions of sulphate evaporites indicate that marine solutions were the only source of sulphate ions supplied to the Zechstein basin, and that anhydrite was transformed to polyhalite by reaction with marine brines more concentrated than those that precipitated precursor calcium sulphate minerals.     

Rheological Transitions During Partial Melting and Crystallization with Application to Felsic Magma Segregation and Transfer

We consider the rheological behaviour of felsic magma in thezone of partial melting and during subsequent crystallization.We also introduce and combine concepts (mushy zone, percolationtheory, granular flow, shear localization) derived from thenon-geological literature and apply them to field observationson migmatites and granites. Segregation and transportation offelsic magmas is commonly observed in association with non-coaxialdeformation, suggesting that gravity forces have limited influenceduring magma segregation. Solid to liquid and liquid to solidtransitions are shown to be rheologically different, which infirmsthe concept of a unique rheological critical melt percentagefor both transitions. Four stages are examined, which dependon the melt fraction present. (1) A minimum of 8% melt by volume must first be produced toovercome the liquid percolation threshold (LPT) above whichmelt pockets can connect, thus allowing local magma displacement.Transport of the liquid phase is amplified by deformation towarddilatant sinks and is restricted to a very local scale. Thiscorresponds to partially molten domains illustrated by incipientmigmatites. (2) When more melt (20–25%) is present, a melt escapethreshold (MET) allows segregation and transport of the meltand part of the residual solid phase, over large distances.This corresponds to segregation and transfer of magma towardsthe upper crust. (3) Segregation of magma also occurs during granite emplacementand crystallization. In a flowing magma containing few particles(20%), particles rotate independently within the flow, defininga fabric. As soon as sufficient crystals are formed, they interactto construct a rigid skeleton. Such a random loose packed frameworkinvolves 55% solids and corresponds to the rigid percolationthreshold (RPT). Above the RPT, clusters of particles can sustainstress, and the liquid fraction can still flow. The only remainingpossibilities for rearranging particles are local shear zones,often within the intrusion rim, which, as a consequence, developsdilatancy. This stage of segregation during crystallizationis totally different from that of magma segregation during incipientmelting. (4) Finally, the system becomes totally locked when random closepacking is reached, at 72–75% solidification; this isthe particle locking threshold (PLT). The introduction of four thresholds must be viewed in the contextof a two-fold division of the cycle that generates igneous rocks,first involving a transition from solid to liquid (i.e. partialmelting) and then a transition from liquid to solid (i.e. crystallization).Neither transition is simply the reverse of the other. In thecase of melting, pockets of melt have to be connected to afforda path to escaping magma. This is a bond-percolation, in thesense of physical percoloation theory. In the case of crystallization,randomly distributed solid particles mechanically interact,and contacts between them can propagate forces. Building a crystalframework is a site-percolation, for which the threshold ishigher than that of bond-percolation. For each transition twothresholds are applicable. The present approach, which basicallydiffers from that based on a unique critical melt fraction,expands and clarifies the idea of a first and a second percolationthreshold. One threshold in each transition (LPT and RPT, respectively)corresponds to a percolation threshold in the sense of physicalpercolation theory. Its value is independent of external forces,but relies on the type and abundance of minerals forming thematrix within which melt connectivity is developing. The exactvalue of the second threshold (MET or PLT) will vary accordingto external forces, such as deformation and the particle shape. KEY WORDS: migmatites; partial melting; granites; magma segregation; magma solidification ^*Corresponding author. Telephone: 33 03 83 44 19 00. Fax: 33 03 83 44 00 29. e-mail: jlv{at}cregu.cnrs-nancy.fr     

Freshwater organisms that build stromatolites: a synopsis of biocrystallization by prokaryotic and eukaryotic algae

In freshwater environments such as river and stream bottoms, rocks and submerged vegetation are covered with a biological felt (also called a periphyton, microbial mat, biofilm, etc.) that is susceptible to calcification. Compilation of an extensive bibliography and our own observations have allowed the identification of 44 species of Coccogonophyceae, 122 Hormogonophyceae, 2 Chrysophyceae, 35 Chlorophyceae, 3 Xanthophyceae, 2 diatoms, and 3 Rhodophyceae that grow on calcareous tufa and coat vegetation. Diverse genera include species that are also calcified but impossible to determine because they lack reproductive organs. Crystals have been described from 74 species in the literature and we have observed 53 others. They can be classified into 10 groups: (1) platelets on cell walls (Volvocales, analogues of coccolithophorids) (2) crystals in mucilage (Synechococcus, diatoms, Hydrurus) and calcified stalks (Oocardium) (3) sheaths containing crystals in the form of simple or three-branched needles, dendritic crystals, and crystals with box-work fabric (Geitleria, Scytonema) (4) sheaths containing calcite spherulites (5) stalks intersecting a large crystal (Cymbella) (6) micrite tubes (Phormidium, Schizothrix) (7) isolated rhombohedra (Zygnema, Scytonema), rhombohedra in clusters or chains (Nostoc parmelioides) (8) sparite platelets (Vaucheria) or isodiametric crystals (Scytonema, Chaetophora) (9) large crystals crosscut by many parallel filaments (Rivularia, Batrachospermum), and (10) fan-like crystals (Phormidium). These crystals can be arranged in clusters or form regular laminations. They can transform into isodiametric sparite crystals to form fan-like or radial palisadic structures. Knowledge of primary crystals and their diagenetic transformations is necessary to correctly interpret freshwater stromatolites. The latter always result from intense calcification and are a diagenetic transformation of a biological felt made of many prokaryotic and eukaryotic algal species, small invertebrates, and organic and mineral debris.     

An effective scale-dependent dispersivity deduced from a purely convective flow field

Abstract

In the case of straight flow but with hydraulic conductivity varying in a transverse direction, the distribution of hydraulic conductivity has been determined for which the breakthrough curve due to convection only will have the same analytical form as the onedimensional convection/dispersion equation solution at the outlet end of a porous medium. That distribution is found exactly and it is very similar to the lognormal distribution. This result is significant since field evidence indicates that the logarithm of hydraulic conductivity is normally distributed. For the case considered, a simple relation between dispersivity and the coefficient of variation of hydraulic conductivity is found. One can thus determine very simply dispersivity in terms of the parameters of the distribution of hydraulic conductivity. This is particularly useful to estimate dispersivity in various cells of finite difference or finite element models when the distribution of hydraulic conductivity is not stationary, i.e. varies in space.     

3. Hydrometry

Abstract

The derived model achieves the rainfall/discharge conversion by means of two individual equations, namely, a production function and a modulation function.     

Modelling the evolution of vein microstructure with phase-field techniques – a first look

Vein microstructures in the Earth's crust contain a wealth of information on the physical conditions of crystal growth, but correct interpretation requires an improved understanding of the processes involved. In this paper the processes involved in the formation of veins are briefly reviewed, and the possibilities of modelling these processes using the phase-field method are discussed. This technique, which is established in the computational materials science community to investigate crystallization processes, is shown to be a powerful tool to describe processes during vein formation and other geological processes involving crystal growth.     

From non‐tidal shelf to tide‐dominated strait: The Miocene Bonifacio Basin,Southern Corsica

This study documents a change from a non‐tidal to tide‐dominated shelf system that occurred between Corsica and Sardinia (the Bonifacio Basin, Western Mediterranean) during the early to middle Miocene. The non‐tidal deposits formed on a low‐energy siliciclastic shelf surrounded by progradational coralline algal ramps at full highstand. The tidal deposits consist of an up to 200 m thick succession of siliciclastic to coralline‐rich cross‐beds formed by large sub‐tidal dunes. Based on outcrop and sub‐surface data, it is possible to conclude that the tidal currents were amplified as a consequence of the rapid subsidence of the basin centre due to tectonic activity. It is suggested that this tectonic event initiated the strait between Corsica and Sardinia. The strait was deep enough to allow the tidal flux to be significantly increased, generating a localized strong tidal current at the junction between the Western Mediterranean and the East Corsica Basin.