Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.     

Biomineralization of Uranium: A Simulated Experiment and Its Significance

A simulated experimental reduction of U^v1 and the synthesis of uraninite by a sulfate-reducing bacteria,Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were:35℃, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week‘s incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments,might have participated in the biomineralization of this uranium deposit. There is an important difference in the orderdisorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.     

Characteristics of Late Permian Deep-Water Sedimentary Environments： A Case Study of Shaiwa Section, Ziyun County, Guizhou Province, Southwestern China

INTRODUCTIONThe Shaiwa Section is located in the town ofSidazhai, Ziyun County, Guizhou Province, south western China ( Fig. 1 ). This area belongs to theNanpanjiang basin of the Yangtze platform. A greatdeal of work purely on the subdivision of the stratahas been carried out in this region (Guizhou Bureauof Geology and Mineral Resources, 1987). However,studies on recoveries of the paleoenvironments of thisarea are rarely reported. Due to rifting and su…     

三江并流世界自然遗产地旅游地质景观成景地质作用初步分析

三江并流世界自然遗产地丰富独特的旅游地质景观是多种地质作用与不同成景岩组交互叠加作用的结果。其发育的地层基础主要为碳酸盐成景岩组、变质岩成景岩组、碎屑岩成景岩组以及岩浆岩成景岩组等,典型内力成景地质作用为板块缝合作用、断裂成景作用、变质成景作用,外力作用则主要有河流、冰川、丹霞、地热、喀斯特作用等。     

Spatial and temporal variations of albedo on nine glaciers in western China from 2000 to 2011

This research demonstrates the spatiotemporal variations of albedo on nine glaciers in western China during 2000–2011, by the albedo derived from two types of datasets: Landsat TM/ETM + images and MOD10A1 product. Then, the influence factors of glacier albedo and its relationship with glacier mass balance are also analyzed by the correlation approach, which is frequently used in geostatistics. The paper finds that there are different spatiotemporal variations over the glaciers in western China: (1) For a single glacier, the albedo varies gently with altitude on its tongue and increases fast in the middle part, while in the accumulation zones, the albedo value appears in the form of fluctuation. This could provide a quantitative method to retrieve the snowline by determining the threshold albedo value of snowpack and bare ice. (2) For the glaciers in western China, the albedo decreases with distance to the center of Tibetan Plateau (TP). This may relate to the elevation of glacier, for the speed of glacier retreat highly depends on air temperature. (3) In the summer period, albedo on most glaciers declines over the last 12 years, and it decreases much faster in southeastern TP than other regions, for which air temperature overwhelms the black carbon concentration. In addition, the trend of glacier albedo in summer is greatly correlated with that of measured glacier mass balance, which implies that the long‐term albedo datasets by remote sensing technology could be used to monitor and predict the change of glacier mass balance in the future. Copyright © 2013 John Wiley & Sons, Ltd.     

湘西合仁坪金矿床硫、铅同位素地球化学

湘西柳林汊一带广泛分布钠长石_石英脉型金矿,合仁坪金矿床是其典型代表。文章对合仁坪金矿床的硫、铅同位素进行了研究,并与区域石英脉型金矿床进行对比,探讨了该矿的成矿物质来源,并初步确定了其矿床成因。研究表明,合仁坪金矿床硫化物的δ34S值范围较窄(-4.8‰~4.4‰),平均为-0.6‰,该矿床的硫为深源硫,由深部变质流体带入;铅的同位素组成较均一,并表现出明显的造山带铅的特点。结合区域成矿作用,进一步研究揭示,合仁坪金矿床为一典型的造山型金矿,其成矿可能与湘西雪峰山地区加里东期的造山作用有关。     

应用激光拉曼光谱研究锆石LA-ICP-MSU-Pb定年中的α通量基体效应

α通量基体效应是由标准锆石与样品锆石之间的晶体损伤(以α通量表示)不同引起的激光剥蚀速率和坑下分馏行为的差异,已被证实是导致锆石LA-ICP-MS U-Pb定年结果存在系统偏倚的重要原因。α通量越高,剥蚀速率越快,坑下分馏越明显,然而α通量基体效应的校正尚未引起足够的重视。本文采用激光拉曼光谱和LA-ICP-MS对八达岭花岗杂岩样品进行研究,结果表明:实际α通量(D_α~P)≤0.75×1018g-1的锆石样品,蜕晶化程度较弱,其定年结果存在的α通量基体效应可以忽略;D_α~P0.75×1018g~(-1)的锆石样品,蜕晶化程度较高,其定年结果受α通量基体效应的影响明显,依据年龄差-D_α~P经验方程如y=347.8×exp(0.260×10~(-15)x)进行校正可获得准确的年龄结果。本研究认为:采用激光拉曼光谱和半高宽(FWHM)-D_α~P校准曲线获得目标锆石D_α~P,利用年龄差-D_α~P经验方程估计LA-ICP-MS系统偏倚,是校正α通量基体效应的可行途径。     

无锡梅雨期湿沉降综合分析

利用2008—2014年梅雨期间酸雨观测资料及2014年6月16—27日降水个例加密采样资料,结合大气污染物资料分析了近7 a无锡梅雨期酸雨特征,研究降水过程中空气污染物、p H值、电导率的变化及降水对污染物的清除作用。结果表明:无锡市梅雨期酸雨年平均p H值呈现逐年递增趋势。降水过程中,颗粒物质量浓度显著降低;气体浓度变化受其自身日变化及排放源影响大于雨水的清除作用;样品的p H值、K值每个过程变化并不一致,K值变化与颗粒物质量浓度变化大致保持一致。降水、风对颗粒物质量浓度影响大于对气体浓度的影响。长时间连续降水时,降水对颗粒污染物的清除存在极限。小时雨量在0~0.5 mm时,降水对颗粒物浓度做负清除,其值反而略有增加;小时雨量在0.6~5.0 mm时,降水对颗粒物质量浓度做正清除;小时雨量达到5.1 mm及以上时,对PM_(2.5)和PM_(2.5-10)做正清除,对PM_(10)做负清除。降水对SO_2有稀释清除作用;对NO_2的稀释作用取决于其开始浓度值;对CO、O_3的清除作用不显著。     

7月不同形态南亚高压与北半球大气环流的关系

利用NCEP/NCAR月平均高度场和风场再分析资料,分析了1948—2013年7月南亚高压多中心特征及其与北半球大气环流的关系。结果表明:1)南亚高压存在1至5个中心不等,其中以双中心类和三中心类为主,占总样本数的82%,其次是单中心类,占总样本数的14%,四中心类和五中心类仅占总样本数的3%。2)根据高压中心个数、经向位置和环流特征,将不同类高压分成了不同型,其中单中心类分为Ⅰ1型和Ⅰ2型,分别占该类的44%和56%,双中心类分为Ⅱ1型、Ⅱ2型和Ⅱ3型,分别占该类的66.7%、18.5%和14.8%,三中心类仅考虑了Ⅲ1型,占该类的67%。3)Ⅰ1型高压中心在伊朗高原上空,Ⅰ2型高压中心在青藏高原上空,Ⅱ1型两高压中心分别在伊朗高原和青藏高原上空,Ⅱ2型两高压中心分别在伊朗高原和我国东部西太平洋上空,Ⅱ3型两高压中心分别在青藏高原和我国东部西太平洋上空,Ⅲ1型三个高压中心分别在伊朗高原、青藏高原和我国东部西太平洋上空。4)不同类型的高压中心所在地区高层位势高度场和对流层中上层温度场都表现为显著正异常,且不同区域温度场异常的维持机制不相同。     

M-Quadtree索引:一种基于改进四叉树编码方法的云存储环境下空间索引方法

为了解决基于"键-值"模型的云存储环境仅支持简单的关键字查询,不支持多维空间查询的问题,提出了一种新的分布式空间索引方法——M-Quadtree索引。在索引构建过程中,设计了一种基于改进四叉树的空间数据划分方法,该方法规定了叶节点区域的最小数据量,通过四叉树叶节点的再合并,解决了划分后各子区域间存储量不平衡的问题,并且满足了MapReduce并行化要求。给出了MapReduce框架下M-Quadtree索引的快速构建、查询与更新算法,并在搭建的Hadoop平台进行了关键参数对索引效率的影响以及不同规模数据下索引的创建、查询和更新试验。与现有分布式空间索引的对比试验及分析结果表明,M-Quadtree索引在数据存储量负载均衡、算法并行化和空间查询效率等方面表现得更好。