Geochemistry and stable isotope investigation of acid mine drainage associated with abandoned coal mines in central Montana,USA

The Great Falls-Lewistown Coal Field (GFLCF) in central Montana contains over 400 abandoned underground coal mines, many of which are discharging acidic water with serious environmental consequences. Areas of the mines that are completely submerged by groundwater have circum-neutral pH and relatively low concentrations of metals, whereas areas that are only partially flooded or freely draining have acidic pH (< 3) and high concentrations of metals. The pH of the mine drains either decreases or increases after discharging to the surface, depending on the initial ratio of acidity (mainly Al and Fe²⁺) to alkalinity (mainly HCO₃^?). In acidic, Fe-rich waters, oxidation of Fe²⁺ after exposure to air is microbially catalyzed and follows zero-order kinetics, with computed rate constants falling in the range of 0.97 to 1.25 mmol L^? 1 h^? 1. In contrast, Fe²⁺ oxidation in near-neutral pH waters appears to be first-order with respect to Fe²⁺ concentration, although insufficient data were collected to constrain the rate law expression. Rates of Fe²⁺ oxidation in the field are dependent on temperature such that lower Fe²⁺ concentrations were measured in down-gradient waters during the day, and higher concentrations at night. Diel cycles in dissolved concentrations of Zn and other trace metals (Mn, Ni) were also noted for down-gradient waters that were net alkaline, but not in the acidic drains.The coal seams of the GFLCF and overlying Cretaceous sandstones form a perched aquifer that lies ~ 50 m above the regional water table situated in the underlying Madison Limestone. The δD and δ¹⁸O values of flooded mine waters suggest local derivation from meteoric water that has been partially evaporated in agricultural soils overlying the coal mines. The S and O isotopic composition of dissolved sulfate in the low pH mine drains is consistent with oxidation of biogenic pyrite in coal under aerated conditions. A clear distinction exists between the isotopic composition of sulfate in the acid mine waters and sulfate in the adjacent sedimentary aquifers, making it theoretically possible to determine if acid drainage from the coal mines has leaked into the underlying Madison aquifer.     

New dates and palaeoenvironmental evidence for the Middle to Upper Palaeolithic occupation of Higueral de Valleja Cave,southern Spain

A research programme has been set up at Higueral de Valleja Cave in southern Spain to investigate the late survival and eventual extinction of the southern Iberian Neanderthals and the arrival of modern humans. Of key interest in the first phase of research was to understand the depositional environment in the entrance chamber of the cave and to establish whether palaeoenvironmental and dating samples could be retrieved from the Middle and Upper Palaeolithic sequences. The outcome is a series of OSL, TL and radiocarbon dates showing that the cave was occupied by Neanderthal populations in Marine Isotope Stage (MIS) 3, if not earlier, and by modern human Solutrean populations during the last glacial maximum. Cave sediments provisionally indicate that the lower Middle Palaeolithic sequence (X–VIII) formed in warm and humid environments and the upper sequence (VIII–V) formed when the climate was cooler and drier. The presence of long grass phytoliths and of the small mammals Microtus duodecimcostatus, Microtus brecciensis and Apodemus sylvaticus in the upper sequence indicates that a range of habitat types persisted near the cave including grassland, scrubby vegetation, patchy tree cover and ponds. This raises the possibility that environmental factors were key factors in the late survival of Neanderthal populations at the cave.     

Staying cool in a changing climate: Reaching vulnerable populations during heat events

The frequency and intensity of hot weather events are expected to increase globally, threatening human health, especially among the elderly, poor, and chronically ill. Current literature indicates that emergency preparedness plans, heat health warning systems, and related interventions may not be reaching or supporting behavior change among those most vulnerable in heat events. Using a qualitative multiple case study design, we comprehensively examined practices of these populations to stay cool during hot weather (“cooling behaviors”) in four U.S. cities with documented racial/ethnic and socio-economic disparities and diverse heat preparedness strategies: Phoenix, Arizona; Detroit, Michigan; New York City, New York; and Philadelphia, Pennsylvania. Based on semi-structured in-depth interviews we conducted with 173 community members and organizational leaders during 2009–2010, we assessed why vulnerable populations do or do not participate in health-promoting behaviors at home or in their community during heat events, inquiring about perceptions of heat-related threats and vulnerability and the role of social support. While vulnerable populations often recognize heat's potential health threats, many overlook or disassociate from risk factors or rely on experiences living in or visiting warmer climates as a protective factor. Many adopt basic cooling behaviors, but unknowingly harmful behaviors such as improper use of fans and heating and cooling systems are also adopted. Decision-making related to commonly promoted behaviors such as air conditioner use and cooling center attendance is complex, and these resources are often inaccessible financially, physically, or culturally. Interviewees expressed how interpersonal, intergenerational relationships are generally but not always protective, where peer relationships are a valuable mechanism for facilitating cooling behaviors among the elderly during heat events. To prevent disparities in heat morbidity and mortality in an increasingly changing climate, we note the implications of local context, and we broadly inform heat preparedness plans, interventions, and messages by sharing the perspectives and words of community members representing vulnerable populations and leaders who work most closely with them.     

Re-thinking colonialism to prepare for the impacts of rapid environmental change

This essay demonstrates how key concepts from ecology can be applied within historical analyses in order to gain insights regarding contemporary environmental change. We employ a coupled human and natural systems conceptual framework in a nascent historical analysis of rapid societal and environmental change in colonial New England, where European colonization led to stark and rapid transformations. Introduced diseases reduced indigenous communities to a fraction of their pre-contact levels. European agriculture and associated pest species, deforestation and overharvest of ecologically influential species were among key aspects of the rapid changes in colonial New England. Cross-continental biotic introductions initiated reinforcing feedback loops that accelerated the transition of human and natural systems into novel states. Integrating colonial history and ecology can help identify important interactions between human and natural systems useful for contemporary societies adjusting to environmental change.     

Ultraviolet spectroscopy of Comet 9P/Tempel 1 with Alice/Rosetta during the Deep Impact encounter

We report on spectroscopic observations of periodic Comet 9P/Tempel 1 by the Alice ultraviolet spectrograph on the Rosetta spacecraft in conjunction with NASA's Deep Impact mission. Our objectives were to measure an increase in atomic and molecular emissions produced by the excavation of volatile sub-surface material. We unambiguously detected atomic oxygen emission from the quiescent coma but no enhancement at the 10% (1-σ) level following the impact. We derive a quiescent H₂O production rate of 9×¹⁰²⁷ molecules s⁻¹ with an estimated uncertainty of ∼30%. Our upper limits to the volatiles produced by the impact are consistent with other estimates.     

The dipole anisotropy of the 2 Micron All-Sky Redshift Survey

We estimate the acceleration on the Local Group (LG) from the 2 Micron All-Sky Redshift Survey (2MRS). The sample used includes about 23 200 galaxies with extinction-corrected magnitudes brighter than   K _s= 11.25  and it allows us to calculate the flux-weighted dipole. The near-infrared flux-weighted dipoles are very robust because they closely approximate a mass-weighted dipole, bypassing the effects of redshift distortions and require no preferred reference frame. This is combined with the redshift information to determine the change in dipole with distance. The misalignment angle between the LG and the cosmic microwave background (CMB) dipole drops to  12°± 7°  at around  50  h ⁻¹ Mpc  , but then increases at larger distances, reaching  21°± 8°  at around  130  h ⁻¹ Mpc  . Exclusion of the galaxies Maffei 1, Maffei 2, Dwingeloo 1, IC342 and M87 brings the resultant flux dipole to  14°± 7°  away from the CMB velocity dipole. In both cases, the dipole seemingly converges by  60  h ⁻¹ Mpc  . Assuming convergence, the comparison of the 2MRS flux dipole and the CMB dipole provides a value for the combination of the mass density and luminosity bias parameters  Ω^0.6_m/ b _L= 0.40 ± 0.09  .