Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone

Boreholes drilled through contaminated zones in fractured rock create the potential for vertical movement of contaminated ground water between fractures. The usual assumption is that purging eliminates cross contamination; however, the results of a field study conducted in a trichloroethylene (TCE) plume in fractured sandstone with a mean matrix porosity of 13% demonstrates that matrix-diffusion effects can be strong and persistent. A deep borehole was drilled to 110 m below ground surface (mbgs) near a shallow bedrock well containing high TCE concentrations. The borehole was cored continuously to collect closely spaced samples of rock for analysis of TCE concentrations. Geophysical logging and flowmetering were conducted in the open borehole, and a removable multilevel monitoring system was installed to provide hydraulic-head and ground water samples from discrete fracture zones. The borehole was later reamed to complete a well screened from 89 to 100 mbgs; persistent TCE concentrations at this depth ranged from 2100 to 33,000 microg/L. Rock-core analyses, combined with the other types of borehole information, show that nearly all of this deep contamination was due to the lingering effects of the downward flow of dissolved TCE from shallower depths during the few days of open-hole conditions that existed prior to installation of the multilevel system. This study demonstrates that transfer of contaminant mass to the matrix by diffusion can cause severe cross contamination effects in sedimentary rocks, but these effects generally are not identified from information normally obtained in fractured-rock investigations, resulting in potential misinterpretation of site conditions.     

Assessing the suitability of OSPAR EcoQOs for eutrophication vs ICES criteria for England and Wales

This paper provides a preliminary evaluation of the suitability of OSPAR Ecological Quality objectives for eutrophication for coastal and offshore waters of England and Wales on the basis of ICES criteria. In principle, EcoQOs are easy to understand, but responses to nutrient enrichment are complex. Few studies provide unequivocal evidence of links between inputs and response. Monitoring is generally feasible and in place, but needs to be improved. The best EcoQO is winter nutrient concentrations. Chlorophyll concentrations are a good indicator in environments susceptible to nutrient enrichment. The EcoQO for zoobenthos/fish kills potentially meets all criteria for a good indicator; EcoQOs for phytoplankton indicator species, oxygen concentrations and zoobenthos changes do not. Greater emphasis needs to be placed on seasonal effects of nutrient inputs and phytoplankton response, natural susceptibility of different water bodies, differences between coastal and offshore environments, and developing longer time series of data.     

Spectral evolution of the peculiar Ic Supernova 1998bw

Supernova 1998bw holds the record for the most energetic Type Ic explosion, one of the brightest radio supernovae and probably the first supernova associated with a γ -ray burst. In this paper we present spectral observations of SN 1998bw observed in a cooperative monitoring campaign using the Anglo-Australian Telescope, the UK Schmidt Telescope and the Siding Springs Observatories 2.3-m telescope. We investigate the evolution of the spectrum between 7 and 94 d after V -band maximum in comparison with well-studied examples of Type Ic SNe in order to quantify the unusual properties of this supernova event. Though the early spectra differ greatly from observations of classical Ic supernovae (SNe), we find that the evolution from the photospheric to nebular phases is slow but otherwise typical. The spectra differ predominantly in the extensive line blending and blanketing which has been attributed to the high velocity of the ejecta. We find that by day 19, the absorption line minima blueshifts are 10–50 per cent higher than other SNe and on day 94 emission lines are 45 per cent broader, as expected if the progenitor had a massive envelope. However, it is difficult to explain the extent of line blanketing entirely by line broadening, and we argue that an additional contribution from other species is present, indicating unusual relative abundances or physical conditions in the envelope.     

Computer simulation of the structure and stability of forsterite surfaces

The aim of this paper is to demonstrate that atomistic simulations can be used to evaluate the structure of mineral surfaces and to provide reliable data for forsterite surfaces up to a plane index of 2 using the code METADISE. The methods used to calculate the surface structure and energy which have more commonly been used to study ceramics are briefly explained as is a comparison with experimental data, most notable the crystal morphology. The predicted morphologies show that all the methods (Donnay-Harker, Attachment energies and equilibrium) show most of the surfaces that are expressed in observed crystals. The equilibrium morphology calculated from the relaxed surface energies is the only method which expresses the {201} surfaces and the {101} surfaces, which appear only upon relaxation. The more stable surfaces are shown to be those which have the highest surface density and more closely resemble close packed structures with highly coordinated surface ions and silicon as far from the surface as possible. The most stable surfaces the {100} which has alternating layers of MgO and SiO₂ terminating with an MgO layer. The structure is similar to the MgO {100} surfaces and has a similar energy (1.28?Jm^?2 compared to 1.20). The second most stable are the {201} which have a stepped surface topology, but is also compact with a relaxed surface energy of 1.56?Jm^?2. The results indicate that atomistic simulation is well suited to the prediction of surface structure and morphology although care must be taken in choosing potentials which model the structure and elastic properties accurately.     

Spectral properties of hydromagnetic fluctuations near 4 and 5 a.u.

Power spectra of vector components of interplanetary magnetic field fluctuations near 4–5 a.u. during quiet intervals show a frequency dependence very close to f^s over the frequency range 4 × 10^?5 to 9 × 10^?3 Hz (corresponding to periods of 7 h-2 min). While the spectra are generally very close to power law in frequency, variations in slope among the spectra exceed those expected from random errors and may represent true temporal variations. Mean slopes corrected for systematic error are s = ? 1.50±0.02 (Pioneer 10, mean heliocentric distance 5.3 a.u.) and s = ? 1.52±0.02 (Pioneer 11, mean heliocentric distance 3.9 a.u.) and are consistent with several determinations of spectral slope for magnetic fluctuations near 1 a.u. Radial evolution of the perturbations is investigated by choosing data samples in which Pioneer 10 and 11 and the sun are nearly colinear. The dependence on heliocentric distance of σ_c², the composite vector variance, and of σ_c/B_mag, where B_mag is the mean magnitude of the magnetic field, show that the radial variation of fluctuation amplitude is highly variable in time with a dependence on heliocentric distance typically in the range R^?1 to R^?1.5. These observations are compared with theoretical models of outward propagating Alfven waves of solar origin and of MHD turbulence. The mean slopes agree well with that expected for turbulence. The significant variability observed in spectral slopes and in the radial dependence of fluctuation amplitude in data selected specifically for conditions of relative magnetic quiet is noteworthy and urges caution in modeling heliospheric magnetic microstructure in studies of galactic cosmic ray modulation.     

THE USE OF FOREST STRUCTURE AND FUNCTION FOR INTERPRETING VEGETATION-ENVIRONMENT RELATIONSHIPS

Species structural and functional characteristics are used in concert with forest composition to examine links between the physical environment and vegetation along an elevational transect of thirty forest stands in Yosemite National Park, California. The structural/functional approach promotes communication by allowing direct analysis and presentation of ecologically significant information. Patterns of leaf persistence, shade tolerance/twig thickness, and windthrow susceptibility are related to changes along the altitudinal gradient as an illustration of the interpretive capabilities of the technique.     

Thermal processing and crystallization of amorphous Mg‐Ca silicates

The structural evolution of sol–gel‐produced amorphous Mg_(x)Ca_(1–x)SiO₃ silicates is investigated. Mid‐IR Fourier transform infrared spectroscopy and synchrotron X‐ray diffraction are used to confirm the amorphous nature of the as‐prepared silicates, while subsequent in situ synchrotron X‐ray powder diffraction measurements are used to study the evolution of crystalline mineral phases as a function of annealing temperature. Multiple silicate phases, including diopside, enstatite, forsterite, and SiO₂, are identified, while Rietveld (i.e., structure) refinement of the diffraction data is used to quantify phase change relationships. Investigated as possible analogs for the refractory dust grain materials likely to have been present in the early solar nebula, the likely relevance of these investigations to the observed silicate compositions of chondritic meteorites and cometary bodies and the processing of their precursor materials is discussed.