Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Investigation of submicron volcanic aerosol-particles by photoelectron emission

Volcanic aerosol emissions have been studied for the first time by in situ photoelectric charging. Explorative studies on Mt Etna reveal large concentrations of particles below 1000 nm with the spectrum peaking in the size range of 100–1000 nm diameter. Although a large fraction of the particles is already charged upon emission, the net electrical charge carried by the aerosol turned out to be close to zero.Particles with high photoelectric yield vary greatly in their relative abundance and seem to occur mainly at active points of the volcano.     

Authigenic iron and titanium oxides in triassic red beds: (St. Bees Sandstone), Cumbria,Northern England

Authigenic iron and titanium oxides occur in three main textural varieties in the St. Bees Sandstone, a Triassic red bed succession in Cumbria. These are: (a) overgrowths of haematite, titaniferous haematite, anatase, and rutile which generally occur on detrital host grains of similar compositions. The overgrowths may occur as syntaxial rim cements or rhombohedral and prismatic projections and are always in optical continuity, (b) discrete crystals of anatase (including octahedrite) and haematite 10-40 μm in size occur in pore spaces, and (c) fine grained ( < 1 μm) pigmentary haematite occurs as grain coatings around detrital grains and in the interstitial matrix. The euhedral nature and pore-filling habit clearly indicate the authigenic origin of these iron- and titanium oxides. All three textural varieties are believed to have been precipitated from ground waters containing dissolved ferrous and titanium ions. These ions were derived from the intrastratal solution of detrital iron and titanium bearing grains including ferromagnesian silicates and iron-titanium oxides. The precipitation of iron oxides from migrating ground waters in the manner described here goes some way to explaining how thick, uniformly red successions can be formed.     

Revised identifications in the 5C2 survey

In the present paper revised distances of optical objects from radio sources of the 5C2 survey are given. A statistical investigation of the data is given for blue objects and galaxies by the statistical method of the “first neighbour”. The identification rate on blue plates for both the blue objects and galaxies amounts to about 40% out of the total number of 26 identifications. For every blue object and galaxy which are proposed as an identification the statistical reliability is given.     

Photometrische Kalibrierung von Schmidtspiegelaufnahmen durch ein bildteilendes Hilfsprisma

Plates of the Tautenburg Schmidt can be calibrated with the aid of a beam-splitting prisma only if Schraffierkassette plates are used. The effects of image structure, scintillation and intermittence on in-focus images are different for the main component and the prismatic companion. Therefore, such plates cannot be used to set up a photometric scale.     

Possible Interpretations of B2 and 5C Quasar Candidate Counts and the “Cut off” in Quasar Density

Optical quasar candidate counts in the far reaching radio surveys B₂ and 5C are consistent either with a luminosity function containing a high percentage of low luminosity objects and a cut off in quasar density or, more probably, with a normal number of quasars at high redshifts and a less steep luminosity function. The absence of high redshifted objects in currently available samples is to be expected of q₀ ≈︂ o and if some of the few quasars observed at z>2.2 are exceptionally bright intrinsically and not typical for the bulk.     

Discrepancy of masses in double galaxies

The estimations of integral masses of double galaxies are obtained taking as a basis recent observational data on 150 pairs of galaxies with measured radial velocities for both components. It is shown that the mean orbital mass-to-luminosity ratio essentially depends on a morphological type of double galaxies and on a kind of interaction between pair components. Minimal values of mass-to-luminosity ratio take place for double galaxies having linear features of interaction, namely: bridges, tails; as well for pairs with compact and Markarian components, too. The empirical relation between mass-to-luminosity ratio and linear separation of pair components do not indicate on an existence of a hidden stellar coronae around double galaxies.     

Directional dependence of P- and S-wave propagation and polarization in foliated rocks from the Kola superdeep well: Evidence from laboratory measurements and calculations based on TOF neutron diffraction

We have measured P- and S-wave velocities on two amphibolite and two gneiss samples from the Kola superdeep borehole as a function of pressure (up to 600 MPa) and temperature (up to 600 °C). The velocity measurements include compressional (Vp) and shear wave velocities (Vs1, Vs2) propagating in three orthogonal directions which were in general not parallel to inherent rock symmetry axes or planes. The measurements are accompanied by 3D-velocities calculations based on lattice preferred orientation (LPO) obtained by TOF (Time Of Flight) neutron diffraction analysis which allows the investigation of bulk volumes up to several cubic centimetres due to the high penetration depth of neutrons. The LPO-based numerical velocity calculations give important information on the different contribution of the various rock-forming minerals to bulk elastic anisotropy and on the relations of seismic anisotropy, shear wave splitting, and shear wave polarization to the structural reference frame (foliation and lineation). Comparison with measured velocities obtained for the three propagation directions that were not in accordance with the structural frame of the rocks (foliation and lineation) demonstrate that for shear waves propagating through anisotropic rocks the vibration directions are as important as the propagation directions. The study demonstrates that proper measurement of shear wave splitting by means of two orthogonal polarized sending and receiving shear wave transducers is only possible when their propagation and polarization directions are parallel and normal to foliation and lineation, respectively.     

Numerical Modeling of the Observed Wiechert Seismograph Magnification

—The paper presents results of experiments designed to measure the actual dynamic magnification of the Wiechert 1000 kg horizontal seismometer when excited by seismic waves. This is accomplished by comparing 51 digital records of seismic events recorded by the Wiechert and a well calibrated reference seismometer. The results obtained indicate that the magnification of the Wiechert seismometer is influenced by the interaction of its mass and frame, especially for high frequencies. This interaction has been modeled by considering a system of two coupled pendulums, yielding a theoretical dynamic magnification curve which exhibits main features of the observed magnification. The dis crepancy between the nominal and the actual response of the Wiechert seismograph may lead to errors in studies involving spectral analyses of recorded seismograms, and to overestimation of local earth quake magnitudes.