Combined effects of pumped-storage operation and climate change on thermal structure and water quality

Climatic Change - The assessment of ecological impacts of pumped-storage (PS) hydropower plants on the two connected water bodies is usually based on present climatic conditions. However,...     

Surface-water quality for the Salí River watershed in NW Argentina

Spatial and temporal variations of Na, Mg, Si, K, Ca, SO₄^2-, Cl^-, HCO₃^-, Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ce, Cd, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Ge, Gd, Hf, Hg, Ho, I, La, Li, Mn, Mo, Nb, Nd, Ni, P, Pb, Pr, Rb, Sb, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, U, V, W, Y, Yb, Zn, and Zr were monitored through 37 sampling stations to determine the main aspects influencing the surface-water quality in the Salí River watershed (Tucumán Province, NW Argentina). The influence of the regional geological setting on water chemistry allows to distinguish three sub-basins. The interaction with sedimentary rocks was found to be dominant in the northern and central-eastern sub-basin as well as in the southern sub-basin, whereas the metamorphic-granitic basement of the Pampean Ranges was noted in the central sub-basin. In addition, anthropogenic activities affect the spatial variation of K, P, Mn, Rb, and Pb as well as dissolved oxygen concentrations and Eh. Temporal water-quality variation is related to the spatial distribution of precipitation and to the seasonal character of the main local industries (sugar cane, alcohol, citrus), increasing P and K concentrations and decreasing dissolved oxygen concentration and Eh in winter. Cl^-, Na, SO₄^2-, Al, As, B, Fe, Mn, Se and U concentrations exceed the regulated drinking-water thresholds at several sampling stations.     

About the Efficiency of Numerical 1-D and 2-D Modelling of Site Effects in Basin Structures

—In the present study we compare results obtained from experimental estimates of local site amplification effects with those from numerical modelling using four different techniques. We benefit from an extremely precise knowledge of the near-surface structure and experimental estimates of the local amplification factors which are determined from seismic weak-motion data recorded by a dense array across a sedimentary basin at a European test-site in Northern Greece. The possibilities and limitations of the different modelling techniques (a 1-D technique, and three 2-D techniques) to model the effects of local amplification effects are tested. Amplifications calculated by the numerical techniques are only qualitatively compared with observed data from experimental studies in the time domain and directly in the frequency domain.¶As a result we conclude that, in the case of a complex subsurface geometry, 1-D modelling underestimates the amplification patterns in terms of absolute amplification level, and cannot correctly account for resonant frequencies, at least for modes higher than the fundamental mode. If a more realistic incident wave field than just a plane wave is taken into account, 2-D modelling reveals the fundamental frequency and shows adequate amplifications not only at the fundamental frequency but also at higher frequencies. The general trend of the amplifications at the lowest frequencies is well determined by the 2-D numerical modelling, and can therefore supply information for seismic risk analysis.     

Numerical modeling for analyzing thermal surface anomalies induced by underground coal fires

Coal seams burning underneath the surface are recognized all over the world and have drawn increasing public attention in the past years. Frequently, such fires are analyzed by detecting anomalies like increased exhaust gas concentrations and soil temperatures at the surface. A proper analysis presumes the understanding of involved processes, which determine the spatial distribution and dynamic behavior of the anomalies.In this paper, we explain the relevance of mechanical and energy transport processes with respect to the occurrence of temperature anomalies at the surface. Two approaches are presented, aiming to obtain insight into the underground coal fire situation: In-situ temperature mapping and numerical simulation. In 2000 to 2005, annual temperature mapping in the Wuda (Inner Mongolia, PR China) coal fire area showed that most thermal anomalies on the surface are closely related to fractures, where hot exhaust gases from the coal fire are released. Those fractures develop due to rock mechanical failure after volume reduction in the seams. The measured signals at the surface are therefore strongly affected by mechanical processes.More insight into causes and effects of involved energy transport processes is obtained by numerical simulation of the dynamic behavior of coal fires. Simulations show the inter-relation between release and transport of thermal energy in and around underground coal fires. Our simulation results show a time delay between the coal fire propagation and the observed appearance of the surface temperature signal. Additionally, the overall energy flux away from the burning coal seam into the surrounding bedrock is about 30-times higher than the flux through the surface. This is of particular importance for an estimation of the energy released based on surface temperature measurements. Finally, the simulation results also prove that a fire propagation rate estimated from the interpretation of surface anomalies can differ from the actual rate in the seam.     

Organic pollutants associated with macromolecular soil organic matter: Mode of binding

A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.     

A “tsunami” in the protoplanetary disk of SV Cep

The results of ~15 years of photometric observations of the UX Ori star SV Cep in the near-infrared (JHKL) are presented. They demonstrate the presence of a cyclic component with a period of ~7 years in the variations of the IR fluxes. This is clearly seen in all four IR bands, but is absent in the optical. The variation amplitude is highest in the K band: ΔK ≈ 0.68 ^m . The shape of the variations differs slightly in the transition from J to L. However, it is reproduced with good accuracy during two cycles, suggesting a periodic process is observed. If the periodic perturbations in the circumstellar disk of SV Cep are due to a companion’s orbitalmotion, the orbital semi-major axis should be ~5AU, foramass of SVCep of 2.6M _⊙. The absence of a seven-year period in the optical light curve of SV Cep means that the observed period cannot be due to variations in the circumstellar extinction. The IR brightness variations could be due to the companion’s motion along an eccentric orbit, resulting in a periodic modulation of the rate of accretion onto the star.     

Observational Tracking of the 2D Structure of Coronal Mass Ejections Between the Sun and 1 AU

The Solar TErrestrial RElations Observatory (STEREO) provides high cadence and high resolution images of the structure and morphology of coronal mass ejections (CMEs) in the inner heliosphere. CME directions and propagation speeds have often been estimated through the use of time-elongation maps obtained from the STEREO Heliospheric Imager (HI) data. Many of these CMEs have been identified by citizen scientists working within the SolarStormWatch project ( www.solarstormwatch.com ) as they work towards providing robust real-time identification of Earth-directed CMEs. The wide field of view of HI allows scientists to directly observe the two-dimensional (2D) structures, while the relative simplicity of time-elongation analysis means that it can be easily applied to many such events, thereby enabling a much deeper understanding of how CMEs evolve between the Sun and the Earth. For events with certain orientations, both the rear and front edges of the CME can be monitored at varying heliocentric distances (R) between the Sun and 1?AU. Here we take four example events with measurable position angle widths and identified by the citizen scientists. These events were chosen for the clarity of their structure within the HI cameras and their long track lengths in the time-elongation maps. We show a linear dependency with R for the growth of the radial width (W) and the 2D aspect ratio (??) of these CMEs, which are measured out to ???0.7?AU. We estimated the radial width from a linear best fit for the average of the four CMEs. We obtained the relationships W=0.14R+0.04 for the width and ??=2.5R+0.86 for the aspect ratio (W and R in units of?AU).