Gold partitioning in melt-vapor-brine systems

We used laser-ablation inductively coupled plasma mass spectrometry to measure the solubility of gold in synthetic sulfur-free vapor and brine fluid inclusions in a vapor + brine + haplogranite + magnetite + gold metal assemblage. Experiments were conducted at 800°C, oxygen fugacity buffered at Ni-NiO (NNO), and pressures ranging from 110 to 145 MPa. The wt% NaCl eq. of vapor increases from 2.3 to 19 and that of brine decreases from 57 to 35 with increasing pressure. The composition of the vapors and brines are dominated by NaCl + KCl + FeCl₂ + H₂O. Gold concentrations in vapor and brine decrease from 36 to 5 and 50 to 28 μg/g, respectively, and the calculated vapor:brine partition coefficients for gold decrease from 0.72 to 0.17 as pressure decreases from 145 to 110 MPa. These data are consistent with the thermodynamic boundary condition that the concentration of gold in the vapor and brine must approach a common value as the critical pressure is approached along the 800°C isotherm in the NaCl-KCl-FeCl₂-HCl-H₂O system.We use the equilibrium constant for gold dissolution as AuOH⁰, extrapolated from lower temperature and overlapping pressure range, to calculate expected concentrations of AuOH⁰ in our experimental vapors. These calculations suggest that a significant quantity of gold in our experimental vapors is present as a non-hydroxide species. Possible chloridogold(I) species are hypothesized based on the positively correlated gold and chloride concentrations in our experimental vapors. The absolute concentration of gold in our synthetic vapor, brine, and melt and calculated mass partition coefficients for gold between these physicochemically distinct magmatic phases suggests that gold solubility in aqueous fluids is a function of aqueous phase salinity, specifically total chloride concentration, at magmatic conditions. However, though we highlight here the effect of salinity, the combination of our data with data sets from lower temperatures evinces a significant decrease in gold solubility as temperature drops from 800°C to 600°C. This decrease in solubility has implications for gold deposition from ascending magmatic fluids.     

Predicting New Hampshire indoor radon concentrations from geologic information and other covariates

 Generalized geologic province information and data on house construction were used to predict indoor radon concentrations in New Hampshire (NH). A mixed-effects regression model was used to predict the geometric mean (GM) short-term radon concentrations in 259 NH towns. Bayesian methods were used to avoid over-fitting and to minimize the effects of small sample variation within towns. Data from a random survey of short-term radon measurements, individual residence building characteristics, along with geologic unit information, and average surface radium concentration by town, were variables used in the model. Predicted town GM short-term indoor radon concentrations for detached houses with usable basements range from 34 Bq/m³ (1 pCi/l) to 558 Bq/m³ (15 pCi/l), with uncertainties of about 30%. A geologic province consisting of glacial deposits and marine sediments was associated with significantly elevated radon levels, after adjustment for radium concentration and building type. Validation and interpretation of results are discussed. Received: 20 October 1997 · Accepted: 18 May 1998     

Biocalcification in the Eastern Oyster (<Emphasis Type="Italic">Crassostrea virginica)</Emphasis> in Relation to Long-term Trends in Chesapeake Bay pH

Anthropogenic carbon dioxide (CO₂) emissions reduce pH of marine waters due to the absorption of atmospheric CO₂ and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed 23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures. Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the decrease in biocalcification.     

Variations in electric and meteorological parameters in the near-Earth’s atmosphere at Kamchatka during the solar events in October 2003

The diurnal variations in the electric conductivity, electric-field strength, and meteorological parameters in the near-Earth’s atmosphere during the solar events in October 21–31, 2003, have been studied. It has been indicated that the conductivity and electric-field strength strongly depend on the air temperature and humidity. It has been found that the conductivity increased for 2 days before the geomagnetic storm on October 29–30 as a result of the effect of solar cosmic rays and decreased during a Forbush decrease in galactic cosmic rays, which was accompanied by a corresponding increase in the electric-field strength. It has been found that the air temperature and humidity anomalously increased in the process of solar activity, which resulted in the formation of different clouds, including thunderclouds accompanied by thunderstorm processes and showers. Simultaneous disturbances of the regular meteorological processes, solar flare series, and emission intensification in the near ultraviolet band, and visible and infrared spectral regions make it possible to consider these processes as a source of additional energy inflow into the lower atmosphere.     

Instability of the magnetosphere-ionosphere convection and formation of auroral arcs

In this paper we study an instability of the plasma moving towards the Earth near the inner plasma sheet boundary. We include both the interchange instability of the plasma sheet and the magnetosphere-ionosphere interaction instability caused by an effect of field-aligned currents (connected with electron precipitation) on ionospheric conductivity. The instability leads to the separation of steady-state magnetospheric convection into parallel layers. This instability may be responsible for the appearance of quiet auroral arcs inside region 2 of field-aligned currents flowing out of the ionosphere. This instability allows us to explain also the existence of crossing auroral arcs.     

The role of the hyporheic zone for a benthic fish in an intermittent river: a refuge, not a graveyard

In lotic systems, the hyporheic zone has been suggested as a potential refuge for aquatic organisms during disturbances (hyporheic refuge hypothesis). However, the supporting evidence is unclear, especially regarding the survival of hyporheic refugees and their contribution to the recovery of post-disturbance populations. Moreover, few studies have focused on the importance of the hyporheic refuge for aquatic vertebrates such as fish. In this study, we present evidence that the hyporheic zone acts as a refuge for a small benthic fish (Cobitis shikokuensis) following surface drying in an intermittent river. We examined its survival during and recolonization after dry periods by direct hyporheic sampling and mark-and-recapture surveys. When the streambed dried, hyporheic sampling was conducted 58 times across 33 locations in the intermittent reach and 31 individuals of C. shikokuensis were captured from extracted hyporheic water. Mark-and-recapture surveys revealed that recolonizers after re-wetting included C. shikokuensis individuals that had survived dry periods in the hyporheic refuge. The condition factor of C. shikokuensis significantly declined after dry periods, suggesting that most recolonizers suffered from physiological stress, probably within the hyporheic refuge. These results clearly support the long-debated, hyporheic refuge hypothesis, and provide a striking example of the critical role of the hyporheic zone in population maintenance of lotic organisms.     

Sedimentology and isotope geochemistry of lacustrine carbonates of the Oligocene Campins Basin, north-east Spain

The non-marine Campins Basin developed in the Oligocene, during a period of early rifting of the Catalan Coastal Ranges. Lacustrine deposits, interbedded between two alluvial units, comprise shallow and deep lacustrine facies. The lower, shallow lacustrine facies are made up of microbialite buildups and thin limestone beds. In the studied area, these facies are overlain by deep lacustrine facies which consist of alternations of several, metre-thick carbonate- and mudstone-dominated intervals. In addition to calcite, which is characteristic of the shallow lacustrine facies, aragonite and abundant dolomite are present in the deep lacustrine facies. This mineralogical change in the sequence reflects an overall increase in the Mg/Ca ratio of the lake waters. The deep lacustrine sequences are interpreted as having formed in a hydrologically closed basin that was subject to changes in the Mg/Ca ratio of the water, probably related to variations in the evaporation/precipitation rate. The sedimentological, mineralogical and isotopic characteristics of the Campins Basin dolomites suggest that, in general, they are primary in origin. The stable isotope data show an approximate covariance between δ¹³C and δ¹⁸O in the lower shallow lacustrine carbonates (calcite) which suggests that they formed during the onset of closure of the lake. The δ¹³C and δ¹⁸O values of the deep lacustrine carbonates display three different clusters that are roughly related to the carbonate mineralogy. Normalisation with respect to calcite of the isotopic compositions of dolomite and aragonite from the deep lacustrine carbonates allows the integration of all these isotope values into one covariant trend. The sequential appearance of different carbonate minerals and the isotopic covariant trend may indicate an overall evaporative concentration of the lake waters. The change in slope of the covariant trend for the isotope values between the shallow and the deep lacustrine carbonates might reflect the change in the waterbody morphology recorded in the basin fill sequence.     

Energy-dependent variability from accretion flows

We develop a formalism to calculate energy-dependent fractional variability (rms) in accretion flows. We consider rms spectra resulting from radial dependences of the level of local variability (as expected from the propagation of disturbances in accretion flows) assuming the constant shape of the spectrum emitted at a given radius. We consider the cases when the variability of the flow is either coherent or incoherent between different radial zones. As an example of local emission, we consider blackbody, Wien and thermal Comptonization spectra. In addition to numerical results, we present a number of analytical formulae for the resulting rms. We also find an analytical formula for the disc Wien spectrum, which we find to be a very good approximation to the disc blackbody. We compare our results to the rms spectrum observed in an ultrasoft state of GRS 1915+105.     

Resistivity profiles over quartz reefs of Dhanbad

Summary A number of resistivity profiles over quartz reefs have been taken using Wenner and Schlumberger configurations around Dhanbad in order tofind the potential of these for water accumulation. These reefs give rise to both resistivity highs and lows as compared to the background. The results are discussed in the light of known theories. Some suitable sites for water accumulation have been delineated.