Thermal expansion and high-temperature P21/c–C2/c phase transition in clinopyroxene-type LiFeGe2O6 and comparison to NaFe(Si,Ge)2O6

A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) ų, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?³, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P2₁/c expands more than the C2/c phase. The evolution of Q ² (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe a jump of Q ₀² = 0.538(2) at T _tr, with T _c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe³⁺Si₂O₆) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P2₁/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron. The tetrahedra behave as rigid units with neither a significant change of volume at T > T _tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T _tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This deformation is related to a strong change by 51.4° at T _tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)° to 194.7(6)°]. The A-chain is S-rotated at T < T _tr [206.8(5)° at 703 K] and extends by 12° at the transition.     

Pseudosection modelling for a selected eclogite body from the Koralpe (Hohl), Eastern Alps

In the Kor-, Saualpe and Pohorje regions of the Eastern Alps eclogite bodies occur within metapelitic gneisses. The bodies are between 1 meter and several hundreds of meters in size and some of them were defined by Haüy (1822) as the type locality for the rock type “eclogite”. A growing body of petrological work has documented the metamorphic evolution of the metapelites surrounding the eclogites. However, few phase diagrams have been constructed for the eclogite bodies themselves. Here we use recently available activity models for amphiboles to present new thermodynamic pseudosections for the Hohl locality of the Koralpe eclogites. We show that this eclogite reached peak conditions in a narrow PT field obliquely oriented in PT space between 16.5 and 20.5 kbar and 620°C to 720°C and that its metamorphic evolution was likely to have occurred under water saturated conditions. We conclude that eclogite and the surrounding metapelites have certainly undergone the same metamorphic peak in Eo-alpine time. Comparison of our results with different PT estimates on the eclogite from Pohorje, suggest that a PT gradient from Koralpe to Pohorje is likely.     

Melt extraction pathways and stagnation depths beneath the Madeira and Desertas rift zones (NE Atlantic) inferred from barometric studies

The Madeira and Desertas Islands (eastern North Atlantic) show well-developed rift zones which intersect near the eastern tip of Madeira (São Lourenço peninsula). We applied fluid inclusion barometry and clinopyroxene-melt thermobarometry to reconstruct levels of magma stagnation beneath the two adjacent rifts and to examine a possible genetic relationship during their evolution. Densities of CO₂-dominated fluid inclusions in basanitic to basaltic samples from São Lourenço yielded frequency maxima at pressures of 0.57–0.87 GPa (23–29 km depth) and 0.25–0.32 GPa (8–10 km), whereas basanites, basalts and xenoliths from the Desertas indicate 0.3–0.72 GPa (10–24 km) and 0.07–0.12 GPa (2–3 km). Clinopyroxene-melt thermobarometry applied to Ti-augite phenocryst rim and glass/groundmass compositions indicates pressures of 0.45–1.06 GPa (15–35 km; São Lourenço) and 0.53–0.89 GPa (17–28 km; Desertas Islands) which partly overlap with pressures indicated by fluid inclusions. We interpret our data to suggest a multi-stage magma ascent beneath the Madeira Archipelago: main fractionation occurs at multiple levels within the mantle (>15 km depth) and is followed by temporary stagnation within the crust prior to eruption. Depths of crustal magma stagnation beneath São Lourenço and the Desertas differ significantly, and there is no evidence for a common shallow magma reservoir feeding both rift arms. We discuss two models to explain the relations between the two adjacent rift systems: Madeira and the Desertas may represent either a two-armed rift system or two volcanic centres with separate magma supply systems. For petrological and volcanological reasons, we favour the second model and suggest that Madeira and the Desertas root in distinct regions of melt extraction. Magma focusing into the Desertas system off the hotspot axis may result from lithospheric bending caused by the load of the Madeira and Porto Santo shields, combined with regional variations in melt production due to an irregularly shaped plume.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: J. Hoefs     

A comparison of the GIS based landslide susceptibility assessment methods: multivariate versus bivariate

The purpose of this study is to evaluate and to compare the results of multivariate (logical regression) and bivariate (landslide susceptibility) methods in Geographical Information System (GIS) based landslide susceptibility assessment procedures. In order to achieve this goal the Asarsuyu catchment in NW Turkey was selected as a test zone because of its well-known landslide occurrences interfering with the E-5 highway mountain pass.Two methods were applied to the test zone and two separate susceptibility maps were produced. Following this a two-fold comparison scheme was implemented. Both methods were compared by the Seed Cell Area Indexes (SCAI) and by the spatial locations of the resultant susceptibility pixels.It was found that both of the methods converge in 80% of the area; however, the weighting algorithm in the bivariate technique (landslide susceptibility method) had some severe deficiencies, as the resultant hazard classes in overweighed areas did not converge with the factual landslide inventory map. The result of the multivariate technique (logical regression) was more sensitive to the different local features of the test zone and it resulted in more accurate and homogeneous susceptibility maps.     

Life in the sublittoral zone of long-lived Lake Pannon: paleontological analysis of the Upper Miocene Szák Formation,Hungary

Life and depositional environments in the sublittoral zone of Lake Pannon, a large, brackish Paratethyan lake from the Late Miocene, were reconstructed from fossils and facies of the Szák Formation. This formation is exposed in several, roughly coeval (9.4–8.9 Ma) outcrops, located along strike of the paleo-shelf-break in northwestern Hungary. The silty argillaceous marl of the formation was deposited below storm wave base, at 20–30 to 80–90 m water depth. The abundance of benthic organisms indicates that the bottom water was usually well oxygenated. Interstitial dysoxia, however, may have occurred immediately below the sediment–water interface, as evidenced by occasional preservation of trace fossils such as Diplocraterion. The fauna comprised endemic mollusks, including brackish cockles of the subfamily Lymnocardiinae, dreissenid mussels (Congeria), and highly adapted, uniquely large-sized deep-water pulmonate snails (planorbids and lymnaeids). Ostracods were dominated by endemic species and, in some cases, endemic genera of candonids, leptocytherids, cypridids, and loxoconchids. Fish remnants include a sciaenid otolith and the oldest skeletal occurrence of Perca in Europe. The phytoplankton comprised exclusively endemic coccolithophorids, mostly endemic dinoflagellates (prevailingly Spiniferites), and cosmopolitan green algae. The Late Miocene fauna and flora of Lake Pannon were in many ways similar to the modern Caspian biota, and in particular cases can be regarded as its precursor.     

The potassium abundance in the solar photosphere

High precision center-limb spectrograms of the K i resonance doublet line at λ 7699 Å were used to study the line formation and to determine the abundance of potassium in the solar atmosphere. The LTE assumption is not valid for these lines. Synthetic profiles computed in NLTE reproduce very well the observed center-limb line behaviour and yield log? _K = 5.14±0.10 for the solar abundance of potassium (on the scale of log? _H = 12 for Hydrogen).     

On the structure of filaments from centimeter and millimeter observations

From filament observations at centimeter and millimeter wavelengths it is shown that the transition layer between the dense, cool filamentary material and the ambient hot, rarified corona is rather thin, of the order of some hundred kilometers. Hence, the difference in the sizes of filaments in the radio and optical domains is of the order of 1000 km or 2, thus not detectable by the instruments so far used for observations of filaments.NASINRC Resident Research Associate at NASA-GSFC.     

Common Proper Motion Search for Faint Companions Around Early-Type Field Stars – Progress Report

The multiplicity of early-type stars is still not well established. The derived binary fraction is different for individual star forming regions, suggesting a connection with the age and the environment conditions. The few studies that have investigated this connection do not provide conclusive results. To fill in this gap, we started the first detailed adaptive-optic-assisted imaging survey of early-type field stars to derive their multiplicity in a homogeneous way. The sample has been extracted from the Hipparcos Catalog and consists of 341 BA-type stars within ∼300 pc from the Sun. We report the current status of the survey and describe a Monte-Carlo simulation that estimates the completeness of our companion detection.