Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin,eastern central Europe

A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km³) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.     

The seasonal cycle in coupled ocean-atmosphere general circulation models

We examine the seasonal cycle of near-surface air temperature simulated by 17 coupled ocean-atmosphere general circulation models participating in the Coupled Model Intercomparison Project (CMIP). Nine of the models use ad hoc “flux adjustment” at the ocean surface to bring model simulations close to observations of the present-day climate. We group flux-adjusted and non-flux-adjusted models separately and examine the behavior of each class. When averaged over all of the flux-adjusted model simulations, near-surface air temperature falls within 2?K of observed values over the oceans. The corresponding average over non-flux-adjusted models shows errors up to ～6?K in extensive ocean areas. Flux adjustments are not directly applied over land, and near-surface land temperature errors are substantial in the average over flux-adjusted models, which systematically underestimates (by ～5?K) temperature in areas of elevated terrain. The corresponding average over non-flux-adjusted models forms a similar error pattern (with somewhat increased amplitude) over land. We use the temperature difference between July and January to measure seasonal cycle amplitude. Zonal means of this quantity from the individual flux-adjusted models form a fairly tight cluster (all within ～30% of the mean) centered on the observed values. The non-flux-adjusted models perform nearly as well at most latitudes. In Southern Ocean mid-latitudes, however, the non-flux-adjusted models overestimate the magnitude of January-minus-July temperature differences by ～5?K due to an overestimate of summer (January) near-surface temperature. This error is common to five of the eight non-flux-adjusted models. Also, over Northern Hemisphere mid-latitude land areas, zonal mean differences between July and January temperatures simulated by the non-flux-adjusted models show a greater spread (positive and negative) about observed values than results from the flux-adjusted models. Elsewhere, differences between the two classes of models are less obvious. At no latitude is the zonal mean difference between averages over the two classes of models greater than the standard deviation over models. The ability of coupled GCMs to simulate a reasonable seasonal cycle is a necessary condition for confidence in their prediction of long-term climatic changes (such as global warming), but it is not a sufficient condition unless the seasonal cycle and long-term changes involve similar climatic processes. To test this possible connection, we compare seasonal cycle amplitude with equilibrium warming under doubled atmospheric carbon dioxide for the models in our data base. A small but positive correlation exists between these two quantities. This result is predicted by a simple conceptual model of the climate system, and it is consistent with other modeling experience, which indicates that the seasonal cycle depends only weakly on climate sensitivity.     

Understanding Perturbation on the Simplex: A Simple Method to Better Visualize and Interpret Compositional Data in Ternary Diagrams

Perturbation is an operation defined on the simplex and can be used for centering compositional data in a ternary diagram, applying objective criteria. Because a straight line in the original diagram is still astraight line in the perturbed diagram, gridlines or compositional fields defined by straight lines can easily be included in the operation. Simultaneous perturbation of data, gridlines, and/or compositional fields is shown to improve both visualization and graphical interpretation of compositions in ternary diagrams. This is illustrated by some examples using simulated as well as real data.     

Star Formation in Violent and Normal Evolutionary Phases

Mergers of massive gas-rich galaxies trigger violent starbursts that - over timescales of > 100 Myr and regions > 10 kpc - form massive and compact star clusters comparable in mass and radii to Galactic globular clusters. The star formation efficiency is higher by 1–2 orders of magnitude in these bursts than in undisturbed spirals, irregulars or even BCDs. We ask the question if star formation in these extreme regimes is just a scaled-up version of the normal star formation mode of if the formation of globular clusters reveals fundamentally different conditions. This revised version was published online in September 2006 with corrections to the Cover Date.     

Variations of vertical velocity in the deep oceans simulated by a 1/10° OGCM

This paper analyzes variations of vertical velocity w simulated by the 1/10° Ocean General Circulation Model for the Earth Simulator (OFES). Strong w-variability is found in the deep oceans. When w is WKBJ-normalized, the standard deviation averaged over the Southern Ocean increases with depth and is larger than 8 × 10^− 3 cm/s throughout the water column below 1,500 m. Evidences are presented that link this w-variability to internal waves generated by quasi-steady currents over topography. The aliasing errors in lag-3-day correlations suggest a bottom generation of near-inertial waves. A scale analysis indicates that vertically propagating waves that can be resolved by the OFES model are waves with frequencies of the order of inertial frequency and wavelengths comparable to the order of the grid size. The vertical energy flux associated with these waves is substantial. When integrated globally, the vertical energy flux is upward in the upper 4 km and reaches maximum values of about 0.8 TW at about 1 to 2 km depth. Thus, the w-variability in the 1/10° OFES integration points not only to a strong bottom generation of near-inertial internal waves in the deep Southern Ocean but also to the possibility that the power provided by internal waves generated by non-tidal currents over topography can be comparable to the power provided by internal waves generated by tidal flows over topography.     

Zur permischen Vereisung der Salt Range (W.-Pakistan)

Zusammenfassung Die unterpermischen Geröll-Packungen der östlichen Salt Range führen fazettierte und geschrammte Geschiebe unzweifelhaft glazialer Entstehung, die zusammen mit anderen Hinweisen eine Deutung der Boulder Beds als fluviatile Konglomerate (nachLotze) nicht überzeugend erscheinen lassen. Die ausgezeichnete Erhaltung der Schrammung schließt zum mindesten einen längeren Flußtransport aus. Das vereiste Gebiet muß sich daher in der Salt Range selbst oder in seiner unmittelbaren Nachbarschaft befunden haben.

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The Lower Permian boulder beds of the eastern Salt Range contain facetted and scratched boulders of unquestionably glacial origin. Their excellent preservation seems to tell in favour of a glacial tillite rather than of a fluviatile conglomerate, as supposed by F.Lotze. At least a fluvial transport of the glacial boulders over a longer distance is to be excluded. The Salt Range itself or its immediate surroundings must have been covered by the Permian glaciers.

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Résumé Les boulder beds du Permien inférieur de la Salt Range orientale contiennent des galets nettement facettés et striés d'origine glaciale. Leur préservation excellente exclut un long transport fluviatile. Par conséquent la Salt Range elle-même ou ses environs immédiats doivent avoir été couverts de glaciers permiens.

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Die vorstehenden Zeilen sind nicht als Selbstverteidigung, sondern in dem Wunsche geschrieben, den von Tübingen ausgegangenen Arbeiten E.Kokens und denen F.Noetlings, der in seinen späteren Jahren gleichfalls in Tübingen wirkte, zur Anerkennung zu verhelfen. Herrn Koll. G.Einsele danke ich verbindlichst für die Durchmusterung der von den abgebildeten Geschieben angefertigten Dünnschliffe. Unsere Bild-Erläuterungen beruhen auf seinen Bestimmungen.     

Rutile occurrence and trace element behavior in medium-grade metasedimentary rocks: example from the Erzgebirge, Germany

Metamorphic textures in medium-grade (~500–550°C) metasedimentary rocks from the Erzgebirge give evidence of prograde rutile crystallization from ilmenite. Newly-crystallized grains occur as rutile-rich polycrystalline aggregates that pseudomorph the shape of the ilmenites. In-situ trace element data (EMP and SIMS) show that rutiles from the higher-grade samples record large scatter in Nb content and have Nb/Ti ratios higher than coexisting ilmenite. This behavior can be predicted using prograde rutile crystallization from ilmenite and indicates that rutiles are reequilibrating their chemistry with remaining ilmenites. On the contrary, rutiles from the lowest grade samples (~480°C) have Nb/Ti ratios that are similar to the ones in ilmenite. Hence, rutiles from these samples did not equilibrate their chemistry with remaining ilmenites. Our data suggest that temperature may be one of the main factors determining whether or not the elements are able to diffuse between the phases and, therefore, reequilibrate. Newly-crystallized rutiles yield temperatures (from ~500 to 630°C, Zr-in-rutile thermometry) that are in agreement with the metamorphic conditions previously determined for the studied rocks. In quartzites from the medium-grade domain (~530°C), inherited detrital rutile grains are detected. They are identified by their distinct chemical composition (high Zr and Nb contents) and textures (single grains surrounded by fine grained ilmenites). Preliminary calculation, based on grain size distribution of rutile in medium-grade metapelites and quartzites that occur in the studied area, show that rutiles derived from quartzites can be anticipated to dominate the detrital rutile population, even if quartzites are a minor component of the exposure.     

Turnover of Eastern Caribbean deep water from 14C measurements

A¹⁴C balance for the Eastern Caribbean deep water indicates the average inflow of Atlantic water into the basin to be 2.3 × 10⁵ m³/sec (±30%), or about 2–4 times the values estimated previously. The balance uses a model representation of the deep-water turnover, and is based on¹⁴C concentrations at a station in the Venezuelan Basin which average Δ¹⁴C= 89‰ below 800 m depth with a total range of only 9‰, as well as on a¹⁴C concentration of the Atlantic inflow of Δ¹⁴C= ?71%. as obtained from measurements outside the Antilles Arch. The turnover time of the basin water below 2500 m depth is 55 years, which corresponds to an average upwelling velocity at this depth of about 35 m/year. With such upwelling, the temperature profile below 1800 m (the depth of the sill determining the inflow of new water) requires a vertical eddy diffusivity of about 5 cm²/sec. The oxygen consumption, and silica and CO₂ regeneration, rates below 2500 m depth are obtained as ?0.18, + 0.08, and + 0.2 μmole kg^?1 yr^?1, respectively. The CO₂ regeneration has but a negligible effect on the¹⁴C balance.     

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