The spatial and seasonal variation of trace metals in coastal seawater and soft tissue of <Emphasis Type="Italic">Chthamalus montagui</Emphasis> around the northwest coast of Portugal

Metal concentrations (Cd, Cr, Cu, Fe, Mn and Zn) were determined in seawaters and soft tissues of Chthamalus montagui from the northwest coast of Portugal during the four seasons of 2011. The main objectives of this work were to assess seasonal and spatial variations of metals in order to detect hot spots of contamination, to establish correlations between metals in coastal seawaters and C. montagui and to calculate metal bioaccumulation factors (BAFs) in each season. Metal concentrations in coastal seawaters ranged within Cd: 1.2–35 ng L^?1; Cr: 15–87 ng L^?1; Mn: 77–1763 ng L^?1; Cu: 126–1819 ng L^?1; Fe: 430–4048 ng L^?1 and Zn: 2889–16867 ng L^?1 and in C. montagui ranged for Cd: 0.39–1.98 mg kg^?1; Cr: 0.45–3.13 mg kg^?1; Cu: 0.93–5.70 mg kg^?1; Mn: 2.2–20.4 mg kg^?1; Fe: 135–707 mg kg^?1 and Zn: 119–782 mg kg^?1. Significant spatial and seasonal variations were found between: (i) metal concentrations in seawaters and C. montagui tissues; (ii) the distribution of metal concentrations in C. montagui tissues were Fe > Zn > Mn > Cu > Cr > Cd and (iii) C. montagui showed higher bioaccumulation factors for Fe and Cd than for Cu, Mn and Zn in all seasons. Regarding the metal concentrations accumulated in C. montagui tissues during each season of 2011, the ecological quality classifications of the NW coast of Portugal varied from “Class I–Unpolluted” to “Class III–Remarkably Polluted”.     

The Variscan belt: correlations and plate dynamics

International Journal of Earth Sciences -     

Ongoing research on seismic safety assessment

Research on seismic safety assessment has been the centre of great interest among the scientific community in recent years. Although the devastating impact of earthquakes on current society should be incentive enough to increase research, the development of more realistic mechanical behaviour models and the continuous enhancement of computation capabilities are paramount factors contributing a great deal to the increase of such interest. In this context, three research areas can be identified as currently leading to important developments: code related research, especially in Europe where new design codes are in the implementation process; risk analysis, namely concerning the definition of methodologies for safety assessment that involve the evaluation of the failure probability and could be included in future generations of codes; and experimental characterization of constitutive laws which provides support for the development and calibration of accurate and realistic numerical models for seismic analysis and for the adequate characterization of limit state capacities. The paper will present some of the current scientific research trends on these three seismic safety assessment related topics. Studies addressing the seismic safety assessment of structures, either probabilistically or based on code provisions, and that consider realistic nonlinear mechanical behaviour models will be focussed. Reference will also be made to experimental research on the seismic behaviour of structural elements, emphasizing its crucial role to support the development of numerical models simulating the effects of different seismic strengthening techniques. Finally, given the development of studies leading to new trends and perspectives for performance based earthquake engineering, a possible scenario for seismic design in the future is presented, emphasizing the key issues for its implementation.     

Application of Multiple Point Geostatistics to Non-stationary Images

Simulation of flow and solute transport through aquifers or oil reservoirs requires a precise representation of subsurface heterogeneity that can be achieved by stochastic simulation approaches. Traditional geostatistical methods based on variograms, such as truncated Gaussian simulation or sequential indicator simulation, may fail to generate the complex, curvilinear, continuous and interconnected facies distributions that are often encountered in real geological media, due to their reliance on two-point statistics. Multiple Point Geostatistics (MPG) overcomes this constraint by using more complex point configurations whose statistics are retrieved from training images. Obtaining representative statistics requires stationary training images, but geological understanding often suggests a priori facies variability patterns. This research aims at extending MPG to non-stationary facies distributions. The proposed method subdivides the training images into different areas. The statistics for each area are stored in separate frequency search trees. Several training images are used to ensure that the obtained statistics are representative. The facies probability distribution for each cell during simulation is calculated by weighting the probabilities from the frequency trees. The method is tested on two different object-based training image sets. Results show that non-stationary training images can be used to generate suitable non-stationary facies distributions.     

Thermal desorption of CH4 retained in CO2 ice

CO₂ ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO₂ traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH₄ in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO₂ ice.     

Natural radiation and its hazard in copper ore mines in Poland

The doses of gamma radiation, concentrations of radium isotopes in water and sediments, radon concentration and concentration of alpha potential energy of radon decay products in the copper ore mine and in the mining region in the vicinity of Lubin town in Poland are presented. These data served as a basis for the assessment of radiological hazard to the mine workers and general public. The results of this assessment indicate that radiological hazard in the region does not differ substantially from typical values associated with natural radiation background. The calculated average annual effective dose for copper miners is 1.48 mSv. In general, copper ore mines can be regarded as radiologically safe workplaces.     

Changes in the Diffuse CO2 Emission and Relation to Seismic Activity in and around El Hierro, Canary Islands

Significant changes in the diffuse emission of carbon dioxide were recorded in a geochemical station located at El Hierro, Canary Islands, before the occurrence of several seismic events during 2004. Two precursory CO₂ efflux increases started thirteen and nine days before two seismic events of magnitude 2.3 and 1.7, which took place near El Hierro Island, Canary Islands, on March 23 and April 15, reaching a maximun value of 51.1 and 46.2 g m⁻² d⁻¹, respectively, five and eight days before the two seismic events. Other similar increases started thirteen and five days before the occurrence of two seismic events of magnitude 1.3 and 1.5 which took place on October 15 and 21 respectively, reaching the maximum values four and one day before the earthquakes. These changes were not related to variations in atmospheric or soil parameters. The Material Failure Forecast Method (FFM), which analyzes the rate of precursory phenomena, was successfully applied to forecast the first seismic event that took place in El Hierro Island in 2004.     

Short-term effects of changes in water management on the limnological characteristics and zooplankton of a eutrophic Mediterranean coastal lagoon (NE Iberian Peninsula)

The Ter Vell (NE Iberian Peninsula) is a eutrophic coastal lagoon which has been flooded by the excess irrigation water and the agricultural runoff during the last decades. Between 1999 and 2003, restoration measures were applied to improve its water quality. At the same time, but independently, agricultural water management drastically reduced the freshwater inflow. The short-term effects of these management actions on the limnological characteristics of the lagoon were analysed by comparing two hydrological cycles, one before (1999/2000) and the other one after (2002/2003) the actions. The two cycles are illustrative of opposite situations in the hydrological functioning of coastal wetlands. In the first, the lagoon was exorheic, with prolonged flooding periods and a low residence time; in the second, it had a more endorheic character, with scarce water inputs and prolonged periods of confinement. Consequently, nitrogen inputs diminished and organic load and salinity increased as the internal loading and the accumulation effects became more relevant. These effects were actually caused by the drastic reduction in the freshwater inflow which prevented, in turn, the success of the restoration measures. The zooplankton community of the Ter Vell lagoon was not significantly altered by the hydrological change, at least in the short-term, and rotifers and cladocerans, mainly those species indicative of eutrophy, dominated the community.