9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.     

Lead contamination of small cetaceans in European waters--the use of stable isotopes for identifying the sources of lead exposure

Lead concentrations and isotopic composition have been measured in bone and teeth of small cetaceans belonging to three species (Delphinus delphis, Phocoena phocoena and Stenella coeruleoalba), to evaluate the toxicological risk and to determine sources of lead in the European waters. Lead concentrations, far lower than threshold value inducing toxic effects in human, were higher in teeth than in bones, but highly correlated between the two tissues (r=0.92, p<0.001). Large variations of 206Pb/207Pb values in bone tissue showed that cetaceans must be submitted to various atmospheric influences. No geographical differences appeared which is consistent with studies on their distribution indicating seasonal movements between Brittany waters and the Bay of Biscay. The negative correlation between 206Pb/207Pb ratios and age of the individuals reflected the decrease in the production of alkyl lead in Europe, i.e., the increasing use of unleaded gasoline.     

Late Miocene evaporite geochemistry of Lorca and Fortuna basins (Eastern Betics,SE Spain): Evidence of restriction and continentalization

The Lorca and Fortuna basins are two intramontane Neogene basins located in the eastern Betic Cordillera (SE Spain). During the Late Tortonian—Early Messinian, marine and continental evaporites precipitated in these basins as a consequence of increased marine restriction and isolation. Here we show a stratigraphic correlation between the evaporite records of these basins based on geochemical indicators. We use SO₄ isotope compositions and Sr isotopic ratios in gypsum, and halite Br contents to characterize these units and to identify the marine or continental source of the waters feeding the evaporite basins. In addition, we review the available chronological information used to date these evaporites in Lorca (La Serrata Fm), including a thick saline deposit, that we correlate with the First Evaporitic Group in Fortuna (Los Baños Fm). This correlation is also supported by micropalaeontological data, giving a Late Tortonian age for this sequence. The Second Evaporitic Group, (Chicamo Fm), and the Third Evaporitic Group (Rambla Salada Fm) developed only in Fortuna during the Messinian. According to the palaeogeographical scheme presented here, the evaporites of the Lorca and Fortuna basins were formed during the Late Tortonian—Early Messinian, close to the Betic Seaway closure. Sulphate isotope compositions and Sr isotopic ratios of the Ribera Gypsum Mb, at the base of the Rambla Salada Fm (Fortuna basin), match those of the Late Messinian selenite gypsum beds in San Miguel de Salinas, in the near Bajo Segura basin (40 km to the East), and other Messinian Salinity Crisis gypsum deposits in the Mediterranean. According to these geochemical indicators and the uncertainty of the chronology of this unit, the assignment of the Rambla Salada Fm to the MSC cannot be ruled out.     

Copper Ore Quality Tracking in a Belt Conveyor System Using Simulation Tools

Natural Resources Research - The ore quality at mining faces in the KGHM underground copper ore mines can be determined based on channel samples and block models built in the Datamine system....     

Seismic‐stratigraphic constraints on the age of the Faroe Islands Basalt Group,Faroe–Shetland region,Northeast Atlantic Ocean

Lower Palaeogene extrusive igneous rocks of the Faroe Islands Basalt Group (FIBG) dominate the Faroese continental margin, with flood basalts created at the time of breakup and separation from East Greenland extending eastwards into the Faroe‐Shetland Basin. This volcanic succession was emplaced in connection with the opening of the NE Atlantic; however, consensus on the age and duration of volcanism remains lacking. On the Faroe Islands, the FIBG comprises four main basaltic formations (the pre‐breakup Lopra and Beinisvørð formations, and the syn‐breakup Malinstindur and Enni formations) locally separated by thin intrabasaltic sedimentary and/or volcaniclastic units. Offshore, the distribution of these formations remains ambiguous. We examine the stratigraphic framework of these rocks on the Faroese continental margin combining onshore (published) outcrop information with offshore seismic‐reflection and well data. Our results indicate that on seismic‐reflection profiles, the FIBG can be informally divided into lower and upper seismic‐stratigraphic packages separated by the strongly reflective A‐horizon. The Lower FIBG comprises the Lopra and Beinisvørð formations; the upper FIBG includes the Malinstindur and Enni formations. The strongly reflecting A‐horizon is a consequence of the contrast in properties of the overlying Malinstindur and underlying Beinisvørð formations. Onshore, the A‐horizon is an erosional surface, locally cutting down into the Beinisvørð Formation; offshore, we have correlated the A‐horizon with the Flett unconformity, a highly incised, subaerial unconformity, within the juxtaposed and interbedded sedimentary fill of the Faroe‐Shetland Basin. We refer to this key regional boundary as the A‐horizon/Flett unconformity. The formation of this unconformity represents the transition from the pre‐breakup to the syn‐breakup phase of ocean margin development in the Faroe–Shetland region. We examine the wider implications of this correlation considering existing stratigraphic models for the FIBG, discussing potential sources of uncertainty in the correlation of the lower Palaeogene succession across the Faroe–Shetland region, and implications for the age and duration of the volcanism.     

A method for checking the quality of geographic metadata based on ISO 19157

With recent advances in remote sensing, location-based services and other related technologies, the production of geospatial information has exponentially increased in the last decades. Furthermore, to facilitate discovery and efficient access to such information, spatial data infrastructures were promoted and standardized, with a consideration that metadata are essential to describing data and services. Standardization bodies such as the International Organization for Standardization have defined well-known metadata models such as ISO 19115. However, current metadata assets exhibit heterogeneous quality levels because they are created by different producers with different perspectives. To address quality-related concerns, several initiatives attempted to define a common framework and test the suitability of metadata through automatic controls. Nevertheless, these controls are focused on interoperability by testing the format of metadata and a set of controlled elements. In this paper, we propose a methodology of testing the quality of metadata by considering aspects other than interoperability. The proposal adapts ISO 19157 to the metadata case and has been applied to a corpus of the Spanish Spatial Data Infrastructure. The results demonstrate that our quality check helps determine different types of errors for all metadata elements and can be almost completely automated to enhance the significance of metadata.     

Variations of young oceanic intraplate seismic energy released with relation to lithosphere age. Implications in the East Pacific Rise and its convergence with the Rivera subduction zone

Marine Geophysical Research - We have estimated empirical relationships that associate the age of the Pacific oceanic lithosphere with the seismic energy released on both flanks of the East Pacific...     

Synergetic efficiency of Lidar and WorldView-2 for 3D urban cartography in Northeast Mexico

Three-dimensional urban cartography is needed for city changes’ assessment. The variety of studies using 3D calculations of urban elements grows each year. Building and vegetation volumes are necessary to assess and understand spatio-temporal urban changeable environments. However, there are technical questions as to which method can improve 3D urban cartographic accuracy. The innovative part of this current study is the creation of a six-band hybrid obtained from LIDAR and WorldView2 synergy. Two different enhancement algorithms demonstrated the most important spectral features for the urban development and vegetation classes. Results indicated an improvement in accuracy by up to 21.3%, according to the Kappa coefficient. Both infra-red band and intensity band were the most significant, according to the principal components analysis. The synergy delimited classes and polygons, as well as the direct display of information regarding heights of elements and improving the extraction of roads, buildings and vegetation classes.     

Dynamics of arrays of floating point-absorber wave energy converters with inter-body and bottom slack-mooring connections

If point absorbers are employed in the extensive exploitation of the offshore wave energy resource, they should be deployed in arrays, the distance between the elements in the array being possibly tens of meters. In such cases, it may be more convenient that the array is spread moored to the sea bottom through only some of its elements, located in the periphery, while the other array elements are prevented from drifting and colliding with each other by connections to adjacent elements. An array of identical floating point absorbers located at the grid points of an equilateral triangular grid is considered in the paper. A spread set of slack-mooring lines connect the peripheric floaters to the bottom. A weight is located at the centre of each triangle whose function is to pull the three floaters towards each other and keep the inter-body mooring lines under tension. The power take-off system (PTO) is a linear damper activated by the buoy heaving motion. The whole system–buoys, moorings and power take-off systems–is assumed linear, so that a frequency domain analysis may be employed. Hydrodynamic interference between the oscillating buoys in array is accounted for. Equations are presented for a set of three identical point absorbers. This is then extended to more complex equilateral triangular grid arrays. Results from numerical simulations, with regular and irregular waves, are presented for the motions and power absorption of hemispherical converters in arrays of three and seven elements and for different mooring parameters and wave incidence angles. Comparisons are given with the unmoored and independently-moored buoy situations.