Characteristics,genesis and classification of a basin peat soil under negative human impact in Turkey

The objective of this research was to investigate the morphology, genesis and classification of organic soils formed on depression and flat land around Lake Yenicaga, west-central Turkey. Formation of the area has been influenced by tectonic and karst processes. This peatland is important in this area due to its extensive use as a horticultural plant growth medium resulting from positive physical and chemical properties. Organic soils in the study area were formed in nutrient-rich conditions and it is classified as typical basin peat. Four representative pedons were excavated in the study area based on extensive observations performed with random grid method using an auger. Samples were taken from horizons in each profile for laboratory analyses. Organic matter contents ranged from 12.5 to 91.5% across all four pedons. Fiber contents were between 4.3 and 91.5%, and N ranged from 0.56 to 2.19%. Cation exchange capacity ranged from 37 to 222 cmol kg⁻¹, bulk density from 0.09 to 0.78 g cm⁻³, lime from 0.15 to 2.62%. The pH and EC_e values ranged from 5.38 to 7.92 and 0.50 to 3.80 dS m⁻¹, respectively. Sand, silt and clay contents of the organic soils ranged between 0.75–3.92, 40.70–74.77 and 24.15–57.30%, respectively. Differences in organic soils were found to depend on the environment, botanical origins, decomposition degrees, and groundwater composition. The organic soils of the research area were classified in the typic, hemic and hydric subgroups of Medifibrists (Soil Taxonomy 1999).     

Fluid infiltration effects on stable isotope systematics of the Susurluk skarn deposit,NW Turkey

A calcic skarn deposit occurs along the contact zone between Oligo-Miocene Çatalda? Granitoid and Mesozoic limestones in Susurluk, northwestern Turkey. The skarn zone with little or no retrograde stage is represented by fluid inclusions with high homogenization temperatures (up to >600 °C) and a wide range of salinity (12 to >70 wt.% NaCl). Pluton-derived fluids facilitated occurrence of continuous prograde reactions in the country rocks (particularly in the proximal zone) and oxygen isotopic depletion in calc-silicate and calcite minerals. δ¹⁸O of anhydrous minerals within proximal and distal zones indicate that skarn-forming fluids had a magmatic origin. The δ¹⁸O values are 5.93–9.08‰ (mean 6.8‰) for garnet, 4.08–9.94‰ (mean 6.4‰) for pyroxene, 4.89–7.92‰ (mean 6.4‰) for wollastonite and 6.65–8.28‰ (mean 7.5‰) for vesuvianite. Temperatures estimated by isotopic compositions of mineral pairs are significantly lower than those measured from the fluid inclusions, indicating that isotopic equilibrium is not preserved between the skarn minerals. δ¹⁸O and δ¹³C values are systematically depleted from marbles to skarn carbonates. Calc-silicate forming reactions and permeability increase triggered by volatilization and consequent strong infiltration of H₂O-rich siliceous fluids into the system promoted fluid–rock interaction causing isotopic resetting and isotopic depletion of silicates (e.g. pyroxene and wollastonite) and skarn calcites.     

Municipal solid waste landfill site selection using geographical information systems: a case study from Çorlu,Turkey

The rapid population growth due to fast urbanization in developing countries leads to environmentally sustainable and efficient management of solid waste. Insufficient solid waste landfill sites, in particular, require new areas because of rapid urbanization. This reveals the need to select appropriate landfill sites, in terms of pollution, that meet the requirements of curbing pollution. In this study, a new solid waste site selection tool was presented for the assessment and selection of areas for a municipal solid waste (MSW) landfill using a combination of point count index and constraint overlaying method with a geographical information system (GIS). For this purpose, factors affecting the site selection tool development were gathered under three groups, namely geological and natural, environmental and social–economical. For the first group, weighting for each criterion—depending upon its relative importance—was assigned, and ratings were given appropriately with their relative magnitude of impact. For the second and third groups, buffer zones were created in order to perform overlay analysis. This tool was used to perform MSW landfill selection of Çorlu District. According to the final map produced with this tool, two areas were identified within the district limits. This procedure was time saving as it was quite easy and did not require too much time and money to collect data. However, besides the usefulness of the procedure, at the final stage of decision-making, some further investigations should also be made.     

Petrogenesis of the Neogene alkaline volcanics with implications for post-collisional lithospheric thinning of the Eastern Pontides, NE Turkey

Whole-rock geochemistry, Sr–Nd–Pb isotopes and K–Ar data are reported for alkaline samples collected from the Neogene alkaline volcanics (NAVs) in the Eastern Pontides, northeastern Turkey, in order to investigate their source and petrogenesis and geodynamic evaluation of the region. The NAVs were made of three groups that comprise of basanite–tephrite (feldspar-free; Group A), tephrite–tephriphonolite (feldspar and feldspathoid-bearing; Group B) and alkaline basalt–rhyolite (feldspathoid-free; Group C) series. These rocks cover a broad compositional range from silica-undersaturated to silica-oversaturated types, almost all of which are potassic in character. They show enrichment of LREE and LILE and depletion of HFSE, without a Eu anomaly in most of the mafic samples. Textural features and calculated pressures based on the Cpx-barometer in each series indicate that the alkaline magma equilibrated at shallow crustal depths under a pressure of about 3–4.5 kbar and approximating a crystallization depth of 9–14 km. The NAVs are slightly depleted in isotopic composition, with respect to ⁸⁷Sr/⁸⁶Sr (ranging from 0.705018 to 0.705643) and ¹⁴³Nd/¹⁴⁴Nd (ranging from 0.512662 to 0.512714) that indicate young Nd model ages (0.51–059 Ga). This may indicate that the parent melts tapped a homogeneous and young lithospheric mantle source which was metasomatized by subduction-derived sediments during the Late Mesozoic. Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.85–18.95; ²⁰⁷Pb/²⁰⁴Pb = 15.60–15.74; ²⁰⁸Pb/²⁰⁴Pb = 38.82–39.25) may also be consistent with a model for an enriched subcontinental lithospheric mantle source. Lithospheric thinning and resultant upwelling of asthenosphere induced by lithospheric delamination may have favoured partial melting of chemically enriched, young lithospheric mantle beneath the Eastern Pontides. Then, the melt subsequently underwent a fractional crystallization process along with or without minor amounts of crustal assimilation, generating a wide variety of rock types in a post-collision extensional regime in the Eastern Pontides during the Neogene.     

Effect of weathering on the geomechanical properties of andesite, Ankara – Turkey

Andesite exposed in different parts of Ankara has different weathering categories varying from fresh to residual soil. The geomechanical properties of the andesite are significantly affected by weathering. Buildings constructed especially in completely weathered and residual soil levels of the andesite have some geotechnical problems. In this study, the variation of the geomechanical properties of the andesite due to weathering is investigated in three selected sites of Ankara, through optical microscope, X-ray diffraction analyses, major element analyses, pressuremeter tests, physicomechanical tests, and seismic refraction method. The data gathered from the field and laboratory studies were used to assess the characteristics of the weathering zones. Based on the data obtained from this study, an idealized weathering profile is assessed. No bearing capacity and consolidation settlement problems exist in the area. However, care should be taken for immediate settlement of the buildings. Slopes with heights less than 8 m are not expected to cause any significant problems for buildings. There exists a ground amplification problem in the study area. The natural period of the building should not match that of the weathered rock. The ground response analyses reveal that the buildings with four to seven stories may be adversely affected from earthquakes due to resonance phenomenon. Therefore, this has to be taken into account when designing new buildings.     

Mapping and assessment-based modeling of soil fertility differences in the central and eastern parts of the Black Sea region using GIS and geostatistical approaches

This study was carried out on arable lands of the central and eastern Black Sea regions including eight provinces (Artvin, Giresun, Gümü?hane, Ordu, Rize, Samsun, Sinop, and Trabzon). The present study aims to generate a soil fertility map for agricultural lands in the central and eastern parts of the Black Sea region. The main objective of this research is to quantify soil fertility by developing a soil fertility index (SFI) model at the regional level. The related objectives were to map the spatial distribution of soil fertility by using auxiliary variables and to model soil fertility within the study region. To accomplish this, a data set for soil fertility differences was collected and a model was developed to predict the spatial distribution of differences across the region. The study area was divided into 2.5 × 2.5-km grid squares. A total of 3400 soil samples were collected from the surface (0–20 cm) of each grid intersection point. The geostatistical method was used to generate the SFI distribution map of the study area for surface soils. Of the total study area, 93.76% had good (S1) or moderately fertile (S2) soil while 6.15% of the area had marginally fertile (S3) soil. Only a very small area (N) had low-fertility soil.     

Selective Preconcentration of Trace Amounts of Cu(II) With Surface‐Imprinted Multiwalled Carbon Nanotubes

In this study, a new sorbent is synthesized using surface imprinting technique. Cu(II)‐imprinted multiwalled carbon nanotube sorbent (Cu(II)‐IMWCNT) is used as the solid phase in the solid‐phase extraction method. After the preconcentration procedure, Cu(II) ions are determined by high‐resolution continuum source atomic absorption spectrometry. A total of 0.1 mol L^?1 ethylenediaminetetraacetic acid (EDTA) is used to remove Cu(II) ions from the sorbent surface. The optimum experimental conditions for effective preconcentration of Cu(II), parameters such as pH, eluent type and concentration, flow rate, sample volume, sorbent capacity, and selectivity are investigated. The synthesized solid phase is characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. The maximum adsorption capacities of Cu(II)‐IMWCNT and non‐imprinted solid phases are 270.3 and 14.3 mg g^?1 at pH 5, respectively. Under optimum experimental conditions for Cu(II) ions, the limit of detection is 0.07 μg L^?1 and preconcentration factor is 40. In addition, it is determined to be reusable without significant decrease in recovery values up to 100 adsorption–desorption cycles. Cu(II)‐IMWCNT have a high stability. To check the accuracy of the developed method, certified reference materials, and water samples are analyzed with satisfactory analytical results.     

Temperature Trends and Changes in Rize,Turkey, for the Period 1975 to 2007

There is increasing evidence that the global climate is changing as a result of anthropogenic activity. Short‐term mean, maximum, and minimum temperatures of the city Rize located at the Eastern Black Sea Coast of Turkey were analyzed to reveal trends, change points, significant warming (cooling) periods, and trend rates per year. An increasing trend of approximately 1.27°C/33 years (α = 0.001) in the annual mean temperatures is found during the period from 1975 to 2007. Two periods, averaging 13.78 and 14.66°C, respectively, were detected from fluctuation in the annual mean temperatures. The trend of the first period (1975–1993) is towards a cooler climate, whereas the trend of the second period (1994–2007) is towards a warmer climate. Summer, autumn and, particularly, the spring mean temperatures have tended to increase strongly, whereas the winter mean temperatures have increased slightly over the whole period. For the winter mean temperature, the trend rate indicates a slight increase, which is insignificant. Maximum temperatures have dramatically increased with 1.61°C (α = 0.001) over the last 33 years. However, annual minimum temperatures have increased by 0.99°C (α = 0.01) over the same period.