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91.
To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S2O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO2 and UV-visible radiation simulating that of Io's surface. Our experiments show that S2O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S2O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S2O diluted in sulfur dioxide frost (i.e., S2O/SO2 < 0.1%). Thus S2O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S2O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S8 sulfur and SO2 reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S8 and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas. 相似文献
92.
Charlotte Prud'homme Olivier Moine Jerome Mathieu Segolene Saulnier‐Copard Pierre Antoine 《Boreas: An International Journal of Quaternary Research》2019,48(1):257-268
High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with 14C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy. 相似文献
93.
Tectonometamorphic evolution of the Atbashi high‐P units (Kyrgyz CAOB,Tien Shan): Implications for the closure of the Turkestan Ocean and continental subduction–exhumation of the South Kazakh continental margin 下载免费PDF全文
Chloé Loury Yann Rolland Stéphane Guillot Pierre Lanari Clément Ganino Raphael Melis Anthony Jourdon Carole Petit Olivier Beyssac Sylvain Gallet Patrick Monié 《Journal of Metamorphic Geology》2018,36(8):959-985
The South Tien Shan (STS) belt results from the last collision event in the western Central Asian Orogenic Belt (CAOB). Understanding its formation is of prime importance in the general framework of the CAOB. The Atbashi Range preserves high‐P (HP) rocks along the STS suture, but still, its global metamorphic evolution remains poorly constrained. Several HP units have been identified: (a) a HP tectonic mélange including boudins of mafic eclogites in a sedimentary matrix, (b) a large (>100 km long) high‐P metasedimentary unit (HPMU) and (c) a lower blueschist facies accretionary prism. Raman Spectroscopy on carbonaceous material combined with phengite and chlorite multiequilibria and isochemical phase diagram modelling indicates that the HPMU recorded homogeneous P–T conditions of 23–25 kbar and 560–570°C along the whole unit. 40Ar/39Ar dating on phengite from the HPMU ranges between 328 and 319 Ma at regional scale. These ages are interpreted as (re‐) crystallization ages of phengite during Tmax conditions at a pressure range of 20–25 kbar. Thermobarometry on samples from the HP tectonic mélange provides similar metamorphic peak conditions. Thermobarometry on the blueschist to lower greenschist facies accretionary prism indicates that it underwent P–T conditions of 5–6 kbar and 290–340°C, highlighting a 17–20 kbar pressure gap between the HPMU‐tectonic mélange units and the accretionary prism. Comparison with available geochronological data suggests a very short time span between the prograde path (340 Ma), HP metamorphic peak (330 Ma), the Tmax (328–319 Ma) and the final exhumation of the HPMU (303–295 Ma). Extrusion of the HPMU, accommodated by a basal thrust and an upper detachment, was driven by buoyant forces from 70–75 km up to 60 km depth, which directly followed continental subduction and detachment of the HPMU. At crustal depths, extrusion was controlled by collisional tectonics up to shallow levels. Lithological homogeneity of the HPMU and its continental‐derived character from the North Tien Shan suggest this unit corresponds to the hyper‐extended continental margin of the Kazakh continent, subducted southward below the north continental active margin of the Tarim craton. Integration of the available geological data allows us to propose a general geodynamic scenario for Tien Shan during the Carboniferous with a combination of (a) N‐dipping subduction below the Kazakh margin of Middle Tien Shan until 390–340 Ma and (b) S‐dipping subduction of remaining Turkestan marginal basins between 340 and 320 Ma. 相似文献
94.
Pierre Lanari Yann Rolland Stéphane Schwartz Olivier Vidal Stéphane Guillot Pierre Tricart Thierry Dumont 《地学学报》2014,26(2):130-138
Pressure–Temperature–time (P–T–t) estimates of the syn‐kinematic strain at the peak‐pressure conditions reached during shallow underthrusting of the Briançonnais Zone in the Alpine subduction zone was made by thermodynamic modelling and 40Ar/39Ar dating in the Plan‐de‐Phasy unit (SE of the Pelvoux Massif, Western Alps). The dated phengite minerals crystallized syn‐kinematically in a shear zone indicating top‐to‐the‐N motion. By combining X‐ray mapping with multi‐equilibrium calculations, we estimate the phengite crystallization conditions at 270 ± 50 °C and 8.1 ± 2 kbar at an age of 45.9 ± 1.1 Ma. Combining this P–T–t estimate with data from the literature allows us to constrain the timing and geometry of Alpine continental subduction. We propose that the Briançonnais units were scalped on top of the slab during ongoing continental subduction and exhumed continuously until collision. 相似文献
95.
Moored fish aggregating devices (MFADs) are used by small-scale fishers to access fish species difficult to harvest in large numbers. In the case of Guadeloupe (Caribbean area), the use of MFADs has increased considerably and this is causing congestion in these fishing areas and creating conflict between fishers. The aim of this article is to understand how informal fishing territories around the La Desirade Island were established and examine these territories through the lens of economic defendability theory. Results of semistructured interviews show that MFAD fishers display territoriality along MFAD tract lines forming quasi-privatized areas. Territoriality in this article is based on the following factors: the type of targeted resources, the cost of harvesting, the defending of territories, and the acknowledgment of territories by the fishing community. Conflicts and utilization of MFADs (overcapacity) have raised an opportunity to create co-managed legalized territorial use rights for fisheries. 相似文献
96.
Sylvie Kelner Michel Bouchon & Olivier Coutant 《Geophysical Journal International》1999,137(1):197-206
We study the propagation of P waves through media containing open fractures by performing numerical simulations. The important parameter in such problems is the ratio between crack length and incident wavelength. When the wavelength of the incident wavefield is close to or shorter than the crack length, the scattered waves are efficiently excited and the attenuation of the primary waves can be observed on synthetic seismograms. On the other hand, when the incident wavelength is greater than the crack length, we can simulate the anisotropic behaviour of fractured media resulting from the scattering of seismic waves by the cracks through the time delay of the arrival of the transmitted wave. The method of calculation used is a boundary element method in which the Green's functions are computed by the discrete wavenumber method. For simplicity, the 2-D elastodynamic diffraction problem is considered. The rock matrix is supposed to be elastic, isotropic and homogeneous, while the cracks are all empty and have the same length and strike direction. An iterative method of calculation of the diffracted wavefield is developed in the case where a large number of cracks are present in order to reduce the computation time. The attenuation factor Q −1 of the direct waves passing through a fractured zone is measured in several frequency bands. We observe that the attenuation factor Q −1 of the direct P wave peaks around kd = 2, where k is the incident wavenumber and d the crack length, and decreases proportionally to ( kd ) −1 in the high-wavenumber range. In the long-wavelength domain, the velocity of the direct P wave measured for two different crack realizations is very close to the value predicted by Hudson's theory on the overall elastic properties of fractured materials. 相似文献
97.
98.
François Baudin Nicolas Tribovillard Fatima Laggoun-Défarge Eric Lichtfouse Olivier Monod & Silvia Gardin 《Sedimentology》1999,46(4):589-602
The Upper Jurassic Akkuyu Formation of south-western Turkey consists of pale-coloured carbonate facies, but includes a peculiar ‘black band’ at its base. In order to characterize the depositional environment of this level, a sedimentological, organic and inorganic geochemical study was performed on 30 samples. Three units are distinguished. Unit 1 consists of black marlstones, very rich in organic carbon (22–30%) with HI (hydrogen index) values around 600. The organic matter is an amorphous homogeneous material even at nanoscopic scale. This unit is also characterized by a very high concentration of V ( >1000 p.p.m.) and a δ13Corg value around ?26·5‰. Unit 2 shows thin-bedded black limestones with chert layers. Its organic content varies from 2% to 6%. As in unit 1, the HI values are uniformly high (600), and gas chromatography shows a high quantity of hopanes. The V concentration is also high (≈400 p.p.m.). The unit has a high Sr/Ca ratio, an organic carbon isotopic ratio close to ?28·7‰ and diffuse, nanoscopically amorphous organic material that is closely associated with pyrite. Unit 3 corresponds to the white limestones overlying the ‘black band’. This calcitic facies is almost devoid of organic carbon (<0·1%). The δ13Corg values are similar to those of unit 1 (?25·5‰ to ?26‰). Deposition occurred in a basinal environment surrounded by a carbonate platform. Primary productivity was high but not exceptional; terrestrial organic inputs were scarce. Bottom waters were probably euxinic during the deposition of unit 1. The presence of both hopane-rich and sulphur-rich nanoscopically amorphous organic matter may be the result of strong sulphate-reducing bacterial activity. Coupled with low amounts of iron, this led to intense vulcanization of the organic matter and thus good preservation. With the onset of unit 2 deposition, environmental conditions became less extreme, perhaps because of cooler water temperatures. Finally, the depositional conditions became oxic, leading to the accumulation of pale-coloured organic-poor limestones of unit 3. 相似文献
99.
Amir?NafiEmail author Eric?Crastes Rehan?Sadiq Denis?Gilbert Olivier?Piller 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(2):527-544
Performing a comprehensive risk analysis is primordial to ensure a reliable and sustainable water supply. Though the general framework of risk analysis is well established, specific adaptation seems needed for systems such as water distribution networks (WDN). Understanding of vulnerabilities of WDN against deliberate contamination and consumers’ sensitivity against contaminated water use is very vital to inform decision-maker. This paper presents an innovative step-by-step methodology for developing comprehensive indicators to perform sensitivity, vulnerability and criticality analyses in case of absence of early warning system (EWS). The assessment and the aggregation of these indicators with specific fuzzy operators allow identifying the most critical points in a WDN. Intentional intrusion of contaminants at these points can potentially harm both the consumers as well as water infrastructure. The implementation of the developed methodology has been demonstrated through a case study of a French WDN unequipped with sensors. 相似文献
100.
Pierre Bosser Olivier Bock Christian Thom Jacques Pelon Pascal Willis 《Journal of Geodesy》2010,84(4):251-265
This paper investigates the impact of rapid small-scale water vapor fluctuations on GPS height determination. Water vapor
measurements from a Raman lidar are used for documenting the water vapor heterogeneities and correcting GPS signal propagation
delays in clear sky conditions. We use data from four short observing sessions (6 h) during the VAPIC experiment (15 May–15
June 2004). The retrieval of wet delays from our Raman lidar is shown to agree well with radiosonde retrievals (bias and standard
deviation (SD) were smaller than 1 and 2.8 mm, respectively) and microwave radiometers (from two different instruments, bias
was 6.0/−6.6 mm and SD 1.3/3.8 mm). A standard GPS data analysis is shown to fail in accurately reproducing fast zenith wet
delay (ZWD) variations. The ZWD estimates could be improved when mean post-fit phase residuals were removed. Several methodologies
for integrating zenith lidar observations into the GPS data processing are also presented. The final method consists in using
lidar wet delays for correcting a priori the GPS phase observations and estimating a scale factor for the lidar wet delays
jointly with the GPS station position. The estimation of this scale factor allows correcting for a mis-calibration in the
lidar data and provides in the same way an estimate of the Raman lidar instrument constant. The agreement of this constant
with an independent determination using radiosonde data is at the level of 1–4%. The lidar wet delays were derived by ray-tracing
from zenith pointing measurements: further improvement in GPS positioning is expected from slant path lidar measurements that
would properly account for water vapor anisotropy. 相似文献