Multi-scale characterization of swelling behaviour of compacted Maryland clay

This paper presents a comprehensive experimental investigation on time-dependent swelling behaviour at both macroscale and microscale of a natural Australian expansive soil in compacted state. A number of one-dimensional swelling tests under different vertical pressures, different initial void ratios and initial water contents were performed. The characterization at macroscale was complemented by extensive microstructural investigations through mercury intrusion porosimetry and scanning electron microscope observation on both as-compacted and swollen specimens. The results were discussed at two different scales within a framework of double-porosity, which was finalized by linking the macrostructural–microstructural strains ratio with secondary swelling/compression coefficients. The multi-scale correlation appears to be largely independent of the specimen initial conditions. The study showed that the secondary swelling and primary swelling are governed by the same factors and that secondary swelling takes place mainly in macropores, of which the change magnitude depends on the level of confinement applied. The microstructural investigations show that swelling is accompanied by significant microfabric changes.     

Geochronology of the Tore-Madeira Rise seamounts and surrounding areas: a review

We present new ⁴⁰Ar/³⁹Ar data for two of the Tore-Madeira Rise (TMR) volcanic seamounts. A sample from Tore East seamount on the northern part of the TMR yielded an ultra-precise age of 80.50 ± 0.13 Ma (2σ) that is similar within uncertainties to a published age obtained by U–Pb TIMS technique on titanites and zircons extracted from Tore NW seamount. Another sample from Isabelle seamount, located on the southern part of the TMR failed to produce a plateau age but yielded a minimum age estimate of >85 Ma. We filtered the published ages available on the TMR, the surrounding seamounts and the massifs of southwest Portugal to better understand the origin of this magmatic province. Together with this dataset, our new data suggest that: (1) a hypothetical Madeira hot-spot track spanning from Serra de Monchique on the continent to Madeira Archipelago is difficult to reconcile with the occurrence of several seamounts geographically located within or very close to this alleged hot-spot track yet being much older than the age predicted by the age trend.

(2) The geographical distribution and age pattern of the TMR and surrounding areas magmatism are still best explained by the interaction of a mantle melting anomaly emitting magma pulses and the different motion phases of the Iberia plate since 103 Ma.

     

Cretaceous paleomargin tilted blocks geometry in northern Tunisia: stratigraphic consideration and fault kinematic analysis

New stratigraphic data, lithostratigraphic correlations, and fault kinematic analysis are used to discuss the basin geometry and sedimentation patterns of the northeastern Tunisia during Cretaceous times. Significant facies and thickness variations are deduced along the northeastern Atlas of Tunisia. The NW-SE 80-km-long regional correlation suggests a high sedimentation rate associated with irregular sea floor. The fault kinematic analysis highlights N-S to NE-SW tectonic extension during Early Cretaceous. During Aptian–Albian times, an extensional regime is recognized with NE-SW tectonic extension. The Cenomanian–Turonian fault populations highlight a WNW-ESE to NW-SE extension, and Campanian–Maastrichtian faults illustrate an NW-SE extension. The normal faulting is associated to repetitive local depocenters with a high rate of sedimentation as well as abundant syntectonic conglomeratic horizons, slump folds, and halokinetic structures. The sequence correlation shows repetitive local depocenters characterizing the basin during Early Cretaceous times. All the above arguments are in favor of basin configuration with tilted blocks geometry. This geometry is shaped by major synsedimentary intra-basin listric normal faults, themselves related to the extensional setting of the southern Tethyan paleomargin, which persisted into the Campanian–Maastrichtian times. The results support a predominant relationship between tilted blocks geometry and sedimentation rather than E-W “Tunisian trough” as it was previously accepted.     

Coral- and oyster-microbialite patch reefs in the aftermath of the Triassic–Jurassic biotic crisis (Sinemurian,Southeast France)

The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.     

Geostatistical Modelling of Cyclic and Rhythmic Facies Architectures

A Pluri-Gaussian method is developed for facies variables in three dimensions to model vertical cyclicity related to facies ordering and rhythmicity. Cyclicity is generally characterised by shallowing-upward or deepening-upward sequences and rhythmicity by the repetition of facies at constant intervals along sequences. Both of these aspects are commonly observed in shallow-marine carbonate successions, especially in the vertical direction. A grid-free spectral simulation approach is developed, with a separable covariance allowing a dampened hole-effect to capture rhythmicity in the vertical direction and a different covariance in the lateral plane along strata, as in space-time models. In addition, facies ordering is created by using a spatial shift between two latent Gaussian functions in the Pluri-Gaussian approach. Rapid conditioning to data is performed via Gibbs sampling and kriging using the screening properties of separable covariances. The resulting facies transiograms can show complex patterns of cyclicity and rhythmicity. Finally, a three dimensional case study of shallow-marine carbonate deposits at outcrop shows the applicability of the modelling method.     

Seismic‐stratigraphic record of a deglaciation sequence: from the marine Laflamme Gulf to Lake Saint‐Jean (late Quaternary,Québec,Canada)

The stratigraphy of the last deglaciation sequence is investigated in Lake Saint‐Jean (Québec Province, Canada) based on 300 km of echo‐sounder two dimensional seismic profiles. The sedimentary archive of this basin is documented from the Late Pleistocene Laurentidian ice‐front recession to the present‐day situation. Ten seismic units have been identified that reflect spatio‐temporal variations in depositional processes characterizing different periods of the Saint‐Jean basin evolution. During the postglacial marine flooding, a high deposition rate of mud settling, from proglacial glacimarine and then prodeltaic plumes in the Laflamme Gulf, produced an extensive, up to 50 m thick mud sheet draping the isostatically depressed marine basin floor. Subsequently, a closing of the water body due to glacio‐isostatic rebound occurred at 8.5 cal. ka BP, drastically modifying the hydrodynamics. Hyperpycnal flows appeared because fresh lake water replaced dense marine water. River sediments were transferred towards the deeper part of the lake into river‐related sediment drifts and confined lobes. The closing of the water body is also marked by the onset of a wind‐driven internal circulation associating coastal hydrodynamics and bottom currents with sedimentary features including shoreface deposits, sediment drifts and a prograding shelf‐type body. The fingerprints of a forced regression are well expressed by mouth‐bar systems and by the shoreface–shelf system, the latter unexpected in such a lacustrine setting. In both cases, a regressive surface of lacustrine erosion (RSLE) has been identified, separating sandy mouth‐bar from glaciomarine to prodeltaic muds, and sandy shoreface wedges from the heterolithic shelf‐type body, respectively. The Lake Saint‐Jean record is an example of a regressive succession driven by a glacio‐isostatic rebound and showing the transition from late‐glacial to post‐glacial depositional systems.     

Numerical study of the soil–structure interaction within mining subsidence areas

Structures affected by mining subsidence are exposed to heavy damage potential in relation to the induced tensile or compressive horizontal ground strains. This study intends to specify and compare the mining subsidence effect in terms of building transmitted movements or induced stresses, given the soil–structure interaction phenomena produced at the interface between a “stiff” elastic structure and a “flexible” elastoplastic soil.     

Hydraulic conductivity distribution in crystalline rocks, derived from inflows to tunnels and galleries in the Central Alps, Switzerland

Inflow data from 23 tunnels and galleries, 136 km in length and located in the Aar and Gotthard massifs of the Swiss Alps, have been analyzed with the objective (1) to understand the 3-dimensional spatial distribution of groundwater flow in crystalline basement rocks, (2) to assess the dependency of tunnel inflow rate on depth, tectonic overprint, and lithology, and (3) to derive the distribution of fracture transmissivity and effective hydraulic conductivity at the 100-m scale. Brittle tectonic overprint is shown to be the principal parameter regulating inflow rate and dominates over depth and lithology. The highest early time inflow rate is 1,300 l/s and has been reported from a shallow hydropower gallery intersecting a 200-m wide cataclastic fault zone. The derived lognormal transmissivity distribution is based on 1,361 tunnel intervals with a length of 100 m. Such interval transmissivities range between 10^?9 and 10^?1 m²/s within the first 200–400 m of depth and between 10^?9 and 10^?4 m²/s in the depth interval of 400–1,500 m below ground surface. Outside brittle fault zones, a trend of decreasing transmissivity/hydraulic conductivity with increasing depth is observed for some schistous and gneissic geological units, whereas no trend is identified for the granitic units.     

Measuring Hg Isotopes in Bio-Geo-Environmental Reference Materials

With the emergence of new analytical techniques and the expansion of scientific fields explored by using mercury isotopes, the community needs reference materials (RM) to validate and assure the accuracy of the results. The present work investigates (1) the characterisation of secondary RM in order to validate analytical systems, (2) the effects of two complex matrices on isotopic determination using stannous chloride cold vapour generation coupled to MC-ICP-MS (CV-MC-ICP-MS), (3) the effects of multiple digestion techniques for total Hg extraction and (4) the characterisation of nine geo-bio-environmental RM. Two secondary mono-elemental RMs analysed using two different analytical setups yielded isotopic compositions on δ²⁰²Hg of −3.54 ± 0.27‰ (CRPG-F65A, 2SD, n = 38) and +2.59 ± 0.19‰ (CRPG-RL24H, 2SD, n = 30) relative to the CRM NIST SRM 3133. These two RMs cover the whole range of Hg isotopic fractionation in natural samples and are made available to the scientific community. Complex fly ash and hydroxysulfate green rust matrices were synthesised, spiked with NIST SRM 3133, then digested and finally analysed versus the mono-elemental NIST SRM 3133 to show potential effect of these complex matrices during CV-MC-ICP-MS. Three digestions techniques, including traditional acid digestion, microwave digestion and high pressure-high temperature digestion, were applied to the lichen RM BCR-482 in order to compare advantages and drawbacks of these methods. Finally, the isotopic compositions of nine RMs including soils (NIST SRM 2711; GXR-2; GSS-4), sediment (GSD-10), jasperoid (GXR-1), ore deposit (GXR-3), fly ashes (BCR-176; BCR-176R) and lichen (BCR-482) are reported. These selected materials have δ²⁰²Hg values ranging from −1.75‰ to +0.11‰. Some RMs also presented mass-independent fractionation with Δ¹⁹⁹Hg and Δ²⁰¹Hg of up to −0.6‰.     

Iron Isotope Variations in Coastal Seawater Determined by Multicollector ICP-MS

In this paper, we applied a reliable technique for measuring Fe isotope variations in coastal seawater at nanomolar levels. Iron was directly pre-concentrated from acidified seawater samples onto a nitrilotriacetic acid chelating resin and further purified using anion-exchange resin. Sample recovery, determined using a standard addition method, was essentially quantitative. Iron was then determined using a high-resolution multicollector ICP-MS (Neptune) coupled to an ApexQ desolvation introduction system. The external precision for δ⁵⁶Fe values was 0.11‰ (2s) when using total a Fe quantity between 25 and 100 ng. We initially applied this technique to measure the Fe isotope composition of dissolved Fe from several coastal environments in the north-eastern United States and we observed a range of δ⁵⁶Fe values between -0.9‰ and 0.1‰ relative to the IRMM-14 reference material. Iron isotope compositions of several reference water materials for inter-laboratory comparisons were also reported. Our results suggest that iron in coastal seawater, derived from benthic diagenesis and/or groundwater has negative Fe isotopic signatures that are distinct from other iron sources such as atmospheric deposition and rivers.