Empirical determination of diffusion coefficients and geospeedometry

Geospeedometry allows to estimate the cooling rate (s_init) of metamorphic rocks at the beginning of the cooling history using diffusion data. But the choice of a diffusion activation energy (E) and a preexponential factor (D₀) from experimental results can be difficult. We propose a method to obtain E directly from the rock itself by studying the variation of the average concentration of elements or isotopes (〈C〉) as a function of mineral grain size (d). An appropriate value of D₀ can then be estimated using an existing compensation rule, a linear relationship between log D₀ and E. Consequently, uncertainties on s_init are markedly reduced. All parameters of this analytical model and their sensitivity on s_init can be estimated from 〈C〉 of the mineral grains under study. As a test we apply our model to a study by Edwards and Valley (1998)**** on ¹⁸O/¹⁶O fractionation between diopside and calcite in Adirondacks marbles, and find a cooling rate in agreement with previous works, without choosing experimental values for E and D₀.     

Dating carbonate rocks with in-situ produced cosmogenic Be: Why it often fails

Surface exposure dating of carbonate rocks using cosmogenic ¹⁰Be is problematic. We have performed step-wise leaching of calcite-rich samples in order to investigate the reasons for this. Results on different grain size fractions clearly indicate the source of atmospheric ¹⁰Be is clay. We demonstrate that partial-leaching procedures, which result in moderate pH levels will not release ¹⁰Be (in-situ produced or atmospheric) due to the instant re-absorption on grain surfaces. By contrast, under strongly acidic conditions, all absorbed ¹⁰Be is leached from aluminosilicates giving abnormally high ¹⁰Be concentrations and consequently exposure ages that are too old. Dating is only possible if samples do not contain any clay minerals or if they can be removed prior to carbonate dissolution.     

Frasnian rugose and tabulate corals from the eastern Taurus (Kozan region,Turkey)

A section near the Kilgen Lake (Adana Province) has yielded a fauna of rugose and tabulate corals including Disphyllum cf. rugosum (Wedekind, 1922), D. cf. curtum Hill, 1954, Wapitiphyllum sp., Thamnopora sp., and Alveolites sp. This coral assemblage is consistent with the previous Frasnian age assigned to the limestones of the Gümü?ali Formation. The rather well-preserved material provides new data on the structure and microstructure of Disphyllum and allows to describe in Thamnopora unusual calicinal morphology (septal ridges, median teeth, and pseudopercula) as well as new structures linked to the lateral increase (basal low wall, apical cul-de-sac).     

Metasomatism and melting history of a Variscan lithospheric mantle domain: evidence from the Puy Beaunit xenoliths (French Massif Central)

Mantle xenoliths from Puy Beaunit (French Massif Central) are compositionally varied, ranging from relatively fertile spinel lherzolites to refractory spinel dunites. Fertile peridotites have registered a modal (amphibole-bearing lherzolites) and cryptic metasomatic event that took place before the last Permian (257 Ma) melting episode. Depletion processes have been constrained by chemical modelling: the depletion is related to different degrees of partial melting, but two major melt extraction episodes are needed to explain the range of major element composition. The second event was responsible for the local large-scale dunitification of former residues. The first melting event (F25%) and metasomatic enrichment are attributed to an ancient fluid and/or liquid infiltration that could be related to a pre-Variscan regional subduction (located to the north of the Beaunit area). Texture acquisition and major deformation of the mantle xenoliths were sub-contemporaneous of the subduction and would result from lithospheric delamination. The second melting event (F17%) produced high-Mg basalts with calc-alkaline trace element signature that gave rise to the Permian underplating episode recognised in western Europe.     

Contribution of climatic and anthropogenic effects to the hydric deficit of peatlands

The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay‐rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two‐year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 1·10^?7 to 3·10^?9 m.s^?1) and does not form a hydraulic barrier. Moreover, the vertical hydraulic gradients are downward between the peat and the sand aquifer, leading to high flows of groundwater through the clay layer (20–48% of the precipitation). The observed hydric deficit of the peatland results from a combination of dry climatic conditions during the study period and groundwater extraction. The climatic effect is mainly expressed through drying out of the peatland, while the anthropogenic effect leads to an enhancement of the climatic effect on a global scale, and a modification of fluxes at a local scale. The drying out of the peatland can lead to its mineralisation, which thus gives rise to environmental impacts. The protection of such wetlands in the context of climate change should take account of anthropogenic pressures by considering the wetland‐aquifer interaction. Copyright © 2011 John Wiley & Sons, Ltd.     

Magnetic horizons of UHECR sources and the GZK feature

We study the effect of random extra-galactic magnetic fields on the propagation of protons of energy larger than 10¹⁹ eV. We show that for reasonable field values (in the 100 nG range) the transition between diffusive and ballistic regimes occurs in the same energy range as the GZK cutoff (a few 10¹⁹ eV). The usual interpretation of the flux reduction above the GZK energy in terms of a sudden reduction of the visible horizon is modified. Moreover, since the size of the diffusion sphere of a continuous source of cosmic rays is of the order of 10 Mpc, the local structure of the Universe and, therefore, of potential local astrophysical sources plays a dominant role in the expected spectrum. Under reasonable assumptions on the sources configurations the expected GZK cutoff is reduced.     

An ESA NEOCC Effort to Eliminate High Palermo Scale Virtual Impactors

In this work we summarize the initial results of a targeted effort of the ESA NEO Coordination Centre to obtain additional observational data in order to eliminate or reduce the impact probability estimate of a subset of the known near-Earth objects representing the highest fraction of the total known impact risk, as measured by the Palermo Scale.     

Water sorption on martian regolith analogs: Thermodynamics and near-infrared reflectance spectroscopy

The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10⁻⁵ to ∼0.3 mbar (relative humidity: 10⁻⁴ to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales.     

Using a Convection Model to Predict Altitudes of White Stork Migration Over Central Israel

Soaring migrants such as storks, pelicans and large birds of prey rely on thermal convection during migration. The convection model ALPTHERM was designed to predict the onset, strength, duration and depth of thermal convection for varying topographies for glider pilots, based on atmospheric conditions at midnight. We tested ALPTHERM predictions as configured for two topographies of central Israel, the Coastal Plains and the Judean and Samarian Mountains in order to predict altitudes of migrating white storks (Ciconia ciconia). Migrating flocks of white storks were tracked with a motorized glider, to measure maximum altitudes of migration during spring 2000. A significant positive correlation was found between the maximum daily altitudes of migration measured and the predicted upper boundary of thermal convection for the Coastal Plains and Samarian Mountains. Thirty-minute predictions for the Coastal Plains and Samarian Mountains correlated positively with measured maximum migration altitudes per thermal. ALPTHERM forecasts can be used to alter flight altitudes in both civil and especially military aviation and reduce the hazard of serious aircraft collisions with soaring migrants.     

An empirical model for transient crater growth in granular targets based on direct observations

The present paper describes observations of crater growth up to the time of transient crater formation and presents a new empirical model for transient crater growth as a function of time. Polycarbonate projectiles were impacted vertically into soda-lime glass sphere targets using a single-stage light-gas gun. Using a new technique with a laser sheet illuminating the target [Barnouin-Jha, O.S., Yamamoto, S., Toriumi, T., Sugita, S., Matsui, T., 2007. Non-intrusive measurements of the crater growth. Icarus, 188, 506-521], we measured the temporal change in diameter of crater cavities (diameter growth). The rate of increase in diameter at early times follows a power law relation, but the data at later times (before the end of transient crater formation) deviates from the power law relation. In addition, the power law exponent at early times and the degree of deviation from a power law at later times depend on the target. In order to interpret these features, we proposed to modify Maxwell’s Z-model under the assumption that the strength of the excavation flow field decreases exponentially with time. We also derived a diameter growth model as: d(t)∝[1-exp(-βt)]^γ, where d(t) is the apparent diameter of the crater cavity at time t after impact, and β and γ are constants. We demonstrated that the diameter growth model could represent well the experimental data for various targets with different target material properties, such as porosity or angle of repose. We also investigated the diameter growth for a dry sand target, which has been used to formulate previous scaling relations. The obtained results showed that the dry sand target has larger degree of deviation from a power law, indicating that the target material properties of the dry sand target have a significant effect on diameter growth, especially at later times. This may suggest that the previously reported scaling relations should be reexamined in order to account for the late-stage behavior with the effect of target material properties.