Contributions from the 10th International Conference on Gas in Marine Sediments, Listvyanka (Russia), 6–11 September 2010

The 10th International Conference on Gas in Marine Sediments (GIMS10) took place from 6 to 11 September 2010 in Listvyanka (Russia), on the shores of Lake Baikal. The conference was organized as a double jubilee, celebrating both the fact that it was the 10th event in this series and the 20th anniversary of the series. A total of 72 oral and 47 poster presentations were given in eight thematic sessions and the presentations were discussed by 126 participants from academic, governmental and commercial institutions from 19 countries, consisting of geologists, biologists, microbiologists, geophysicists, geochemists, oceanographers and limnologists. Volume 32(5/6) of Geo-Marine Letters is a double issue containing 16 selected papers from GIMS10, and has been guest edited by M. De Batist and O. Khlystov. The papers reflect the broad-spectrum disciplines represented at the conference and cover a wide range of aspects of gas in marine sediments from many parts of the world, but with a special emphasis on the gas seeps, gas hydrates and mud volcanoes of Lake Baikal.     

Effect of pH and organic ligands on the kinetics of smectite dissolution at 25 °C

Forward dissolution rates of Na-Montmorillonite (Wyoming) SWy-2 smectite (Ca_0.06Na_0.56)[Al_3.08Fe(III)_0.38Mg_0.54] [Si_7.93 Al_0.07]O₂₀(OH)₄ were measured at 25 °C in a mixed-flow reactor equipped with interior dialysis compartment (6-8 kDa membrane) as a function of pH (1-12), dissolved carbonate (0.5-10 mM), phosphate (10⁻⁵ to 0.03 M), and nine organic ligands (acetate, oxalate, citrate, EDTA, alginate, glucuronic acid, 3,4-dihydroxybenzoic acid, gluconate, and glucosamine) in the concentration range from 10⁻⁵ to 0.03 M. In organic-free solutions, the Si-based rates decrease with increasing pH at 1 ? pH ? 8 with a slope close to −0.2. At 9 ? pH ? 12, the Si-based rates increase with a slope of ∼0.3. In contrast, non-stoichiometric Mg release weakly depends on pH at 1 ? pH ? 12 and decreases with increasing pH. The empirical expression describing Si-release rates [R, mol/cm²/s] obtained in the present study at 25 °C, I = 0.01 M is given by

     

1993年8月8日关岛地震前后ULF磁场异常变化

给出了1993年8月8日关岛地震(Ms=7.1,深度60km)前后ULF(Ultra Low Frequency:超低频信号,频段为O.005～10Hz)地磁信号的分析结果.ULF观测系统位于日本关岛,距离震中约65km.对观测数据进行分析后得出以下结论:①建议用非常细致的统计分析(月均值,标准偏差)来判断ULF信号的强度和极化值(比如:Z/H比值);②ULF信号活动强度和∑Kp的对比,有助于区别空间地磁脉动和非空间源地磁辐射;③发现Z/H比值的使用在把可能来自震源的辐射从空间等离子波中识别出来非常重要;④从对极化值的时间序列的统计分析发现极化值在震前仅一个月时有一个显著的增强,表明这期间的电磁异常现象很可能是震磁前兆信号;⑤Z分量的时间变化类似于Loma Prieta地震前的变化,即在震前10天到两周有明显的增强,在震前几天出现另一次增强;⑥可能与地震有关的电磁辐射是一种类似噪音的自然现象,它们的主要频带范围0.02～0.05Hz(最大幅值约为0.1nT).     

Water exchange of the Stockholm archipelago—a cascade framework modelling approach

The Stockholm archipelago spans roughly a semicircular area with a radius of approximately 60 km, traditionally partitioned into three parts: the inner, the middle and the outer archipelago. This subdivision coincides with differing water exchange regimes. The inner and middle archipelagos are characterised by comparatively larger basins which are interconnected by a limited number of straits. This configuration is well suited for a discrete basin (DB-) model approach by partitioning the area into a set of sub-basins that are only resolved vertically. The advantage of this approach over 3D-models is the possibility for enhanced vertical resolution and improved strait exchange formulation, outweighing the disadvantage of neglected horizontal gradients within the basins. In the inner archipelago the dominating exchange process is estuarine circulation, induced by the marked freshwater discharge and the vertical mixing. In the outer and middle archipelagos the density fluctuations due to Ekman pumping along the Baltic boundary interface produce another type of baroclinic process that clearly dominates. Measurements to adequately resolve these density variations do not exist. Missing forcing data are provided by linking the middle archipelago's boundary straits to a 3D-model of the Baltic with a grid resolution of 0.5 nautical miles (n.m.). This fine resolution model (FR-domain) is in turn driven by the atmospheric forcing and the density variation at the rectangular boundary of the FR-domain which acceptably resolves both the interfacial straits and the outer archipelago's complex hypsography. Massive computing resources would be demanded if the FR-domain were extended to comprise the entire Baltic. The FR-domain is thus interfaced with an existing coarse resolution model of the entire Baltic (CR-domain) with a grid size of 5 n.m., the open boundary of which is located in the Kattegat. This 3-fold model set-up has been run for one whole year (1992) with a one-year spin-up time to make up for the lack of initial data. The model concept is at this stage to be regarded as a framework for further development in anticipation of improved formulations, particularly for the strait exchange formulation. Therefore only primary validation experiments and a few sensitivity analyses have been performed.     

On the onset of the instability of a three-dimensional jet in a stratified fluid

The onset of a three-dimensional jet flow in a stratified fluid is studied with the aid of a direct numerical simulation. An initially cylindrical jet with a Gaussian velocity profile is considered in a fluid with stable linear density stratification. The results indicate that, if an initial small perturbation of the velocity field has a wide spectrum, an exponential growth of the isolated quasi-two-dimensional mode occurs and its spectral maximum is shifted toward smaller wave numbers in comparison with the maximum of the helical mode of the instability of a nonstratified jet. The growth rate is proportional to Ri^0.5, where Ri is the global Richardson number. The onset of the instability leads to the formation of the flow’s vortex structure, which consists of a collection of different-polarity quasi-two-dimensional vortices located in a horizontal plane near the longitudinal axis of the jet. At sufficiently long times (Nt > 100, where N is the buoyancy frequency and t is time), the growth of instability reaches the saturation stage and further fluctuations in velocity and density decay under the effect of viscous diffusion. At this stage, the flow becomes self-similar and the time dependences of the transverse and vertical widths of the jet are consistent with the asymptotic behaviors of integral parameters of the flow that are observed experimentally in the far stratified wake. The results suggest that the onset of the instability of a quasitwo-dimensional mode can play the determining role in the dynamics of flow in the far stratified wake.     

Permeability and degassing of dome lavas undergoing rapid decompression: An experimental determination

The gas permeability of volcanic rocks may influence various eruptive processes. The transition from a quiescent degassing dome to rock failure (fragmentation) may, for example, be controlled by the rocks permeability, in as much as it affects the speed by which a gas overpressure in vesicles is reduced in response to decompression. Using a modified shock-tube-based fragmentation bomb (Alidibirov and Dingwell 1996a,b; Spieler et al. 2003a), we have measured unsteady-state permeability at a high initial pressure differential. Following sudden decompression above the rock cylinder, pressurized gas flows through the sample. Two pressure transducers record the pressure signals above and below the sample. A transient 1D filtration code has been developed to calculate permeability using the experimental decay curve of the lower pressure transducer. Additionally an analytical steady-state method to achieve permeability is presented as an alternative to swiftly predict the sample permeability in a sufficiently precise manner. Over 100 permeability measurements have been performed on samples covering a wide range of porosity. The results show a general positive relationship between porosity and permeability with a high data scatter. Our preferred interpretation of the results is a combination of two different, but overlapping effects. We propose that at low porosities, gas escape occurs predominantly through microcracks or elongated micropores and therefore could be described by simplified forms of Kozeny–Carman relations (Carman 1956) and fracture flow models. At higher porosities, the influence of vesicles becomes progressively stronger as they form an increasingly connected network. Therefore, a model based on the percolation theory of fully penetrable spheres is used, as a first approximation, to describe the permeability-porosity trend. In the data acquired to date it is evident, that in addition to the porosity control, the samples bubble size, shape and distribution strongly influence the permeability. This leads to a range of permeability values up to 2.5 orders of magnitude at a given porosity.     

The North Taymyr ice-marginal zone, Arctic Siberia—a preliminary overview and dating

The North Taymyr ice-marginal zone (NTZ) is a complex of glacial, glaciofluvial and glaciolacustrine deposits, laid down on the northwestern Taymyr Peninsula in northernmost Siberia, along the front of ice sheets primarily originating on the Kara Sea shelf. It was originally recognised from satellite radar images by Russian scientists; however, before the present study, it had not been investigated in any detail. The ice sheets have mainly inundated Taymyr from the northwest, and the NTZ can be followed for 700–750 km between 75°N and 77°N, mostly 80–100 km inland from the present Kara Sea coast.The ice-marginal zone is best developed in its central parts, ca. 100 km on each side of the Lower Taymyr River, and has there been studied by us in four areas. In two of these, the ice sheet ended on land, whereas in the two others, it mainly terminated into ice-dammed lakes. The base of the NTZ is a series of up to 100-m-high and 2-km-wide ridges, usually consisting of redeposited marine silts. These ridges are still to a large extent ice-cored; however, the present active layer rarely penetrates to the ice surface. Upon these main ridges, smaller ridges of till and glaciofluvial material are superimposed. Related to these are deltas corresponding to two generations of ice-dammed lakes, with shore levels at 120–140 m and ca. 80 m a.s.l. These glacial lakes drained southwards, opposite to the present-day pattern, via the Taymyr River valley into the Taymyr Lake basin and, from there, most probably westwards to the southern Kara Sea shelf.The basal parts of the NTZ have not been dated; however, OSL dates of glaciolacustrine deltas indicate an Early–Middle Weichselian age for at least the superimposed ridges. The youngest parts of the NTZ are derived from a thin ice sheet (less than 300 m thick near the present coast) inundating the lowlands adjacent to the lower reaches of the Taymyr River. The glacial ice from this youngest advance is buried under only ca. 0.5 m of melt-out till and is exposed by hundreds of shallow slides. This final glaciation is predated by glacially redeposited marine shells aged ca. 20,000 BP (¹⁴C) and postdated by terrestrial plant material from ca. 11,775 and 9500 BP (¹⁴C)–giving it a last global glacial maximum (LGM; Late Weichselian) age.