Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.     

Mixed layer variability in Northern Arabian Sea as detected by an Argo float

Seasonal evolution of surface mixed layer in the Northern Arabian Sea (NAS) between 17° N–20.5° N and 59° E-69° E was observed by using Argo float daily data for about 9 months, from April 2002 through December 2002. Results showed that during April - May mixed layer shoaled due to light winds, clear sky and intense solar insolation. Sea surface temperature (SST) rose by 2.3 °C and ocean gained an average of 99.8 Wm⁻². Mixed layer reached maximum depth of about 71 m during June - September owing to strong winds and cloudy skies. Ocean gained abnormally low ∼18 Wm⁻² and SST dropped by 3.4 °C. During the inter monsoon period, October, mixed layer shoaled and maintained a depth of 20 to 30 m. November - December was accompanied by moderate winds, dropping of SST by 1.5 °C and ocean lost an average of 52.5 Wm⁻². Mixed layer deepened gradually reaching a maximum of 62 m in December. Analysis of surface fluxes and winds suggested that winds and fluxes are the dominating factors causing deepening of mixed layer during summer and winter monsoon periods respectively. Relatively high correlation between MLD, net heat flux and wind speed revealed that short term variability of MLD coincided well with short term variability of surface forcing.     

Spatial and Temporal Variations of Sound Speed at the PN Section

Gridded sound speed data were calculated using Del Grosso's formulation from the temperature and salinity data at the PN section in the East China Sea covering 92 cruises between February 1978 and October 2000. The vertical gradients of sound speed are mainly related to the seasonal variations, and the strong horizontal gradients are mainly related to the Kuroshio and the upwelling. The standard deviations show that great variations of sound speed exist in the upper layer and in the slope zone. Empirical orthogonal function analysis shows that contributions of surface heating and the Kuroshio to sound speed variance are almost equivalent. This revised version was published online in July 2006 with corrections to the Cover Date.     

Seasonal variations of water system distribution and flow patterns in the southern sea area of Hokkaido,Japan

Hydrographic data and composite current velocity data (ADCP and GEK) were used to examine the seasonal variations of upper-ocean flow in the southern sea area of Hokkaido, which includes the “off-Doto” and “Hidaka Bay” areas separated by Cape Erimo. During the heating season (April–September), the outflow of the Tsugaru Warm Current (TWC) from the Tsugaru Strait first extends north-eastward, and then one branch of TWC turns to the west along the shelf slope after it approaches the Hidaka Shelf. The main flow of TWC evolves continuously, extending eastward as far as the area off Cape Erimo. In the late cooling season (January–March), part of the Oyashio enters Hidaka Bay along the shallower part of the shelf slope through the area off Cape Erimo, replacing almost all of the TWC water, and hence the TWC devolves. It is suggested that the bottom-controlled barotropic flow of the Oyashio, which may be caused by the small density difference between the Oyashio and the TWC waters and the southward migration of main front of TWC, permits the Oyashio water to intrude along the Hidaka shelf slope.     

Selenium distribution in the Rhône delta and the Gulf of Lions

Total dissolved selenium and selenium species have been measured in the Rhône river delta and the Gulf of Lions within the framework of the EROS-2000 project. The Rhône river concentration of total selenium averages 2.30 nM with important variations related to river discharge. During estuar-ine mixing, the concentrations of total dissolved selenium, selenite and selenate (calculated as the difference between total dissolved and selenite) decrease linearly with increasing salinity, without significant interconversion between selenium species. In the open Mediterranean waters of the Gulf of Lions the total dissolved selenium increases from 0.5 nM in the surface waters to 0.9 nM in the deep waters. Organic selenium has been observed in Mediterranean deep water, an observation which is different from those from the Atlantic and the Pacific Oceans. The distributions of total inorganic selenium (Σ5e), selenite and selenate are strongly related to phosphate and silicate concentrations as observed previously for the major oceans.     

Particle-bound phosphorus along an urbanized coastal plain estuary

The distribution of particle-bound phosphorus in the suspended sediment of the Delaware Estuary was examined with a sequential chemical leaching technique. The phosphorus content of particles was highest in the tidal river (140–250 μmol g⁻¹) near major anthropogenic inputs. Despite this enrichment of river particles with phosphorus, suspended particles within the salinity gradient had a phosphorus content more similar to the world's average. Sequential chemical leaches revealed that particulate phosphorus was associated with organic matter, aluminum oxides, iron oxides, and apatite in all areas of the estuary. However, ‘excess’ particle-bound phosphorus in the tidal river was associated mainly with iron oxides (27%), aluminum oxides (23%), and organic matter (50%). Within the salinity gradient, particulate phosphorus associated with iron oxides, aluminum oxides, and apatite all decreased with increasing salinity. Estuarine mixing was simulated to determine whether the observed decreases in particle-bound phosphorus pools in field samples were due to release into solution. During simulated mixing, particulate phosphorus associated with iron and aluminum oxides decreased, but no change was observed in apatite-bound phosphorus. The results of the mixing study combined with the observed particle-bound phosphorus distributions suggest that phosphate concentrations along the Delaware Estuary may be partially ‘buffered’ by aluminum and iron oxide phases.     

Atmospheric forcing of fine-sand transport on a low-energy inner shelf: south-central Louisiana,USA

Hydrodynamic and sediment transport measurements from instrumentation deployed during a 54-day winter period at two sites on the Louisiana inner shelf are presented. Strong extratropical storms, with wind speeds of 7.8 to 15.1 m s^-1, were the dominant forcing mechanism during the study. These typically caused mean oscillatory flows and shear velocities about 33% higher than fair weather (averaging 12.3 and 3.2 cm s^-1 at the landward site, and 11.4 and 2.7 cm s^-1 at the seaward site, respectively). These responses were coupled with mean near-bottom currents more than twice as strong as during fair weather (10.3 and 7.5 cm s^-1 at the landward and seaward sites, respectively). These flowed in approximately the same direction as the veering wind, causing a net offshore transport of fine sand. Weak storms were responsible for little sediment transport whereas during fair weather, onshore sand transport of approximately 25-75% of the storm values appears to have occurred. This contradicts previous predictions of negligible fair-weather sediment movement on this inner shelf.     

Tectonic control over topography and channel sedimentation across the forearc slope of the southern Kurile Trench

A high-resolution seismic survey covering more than 2,000 km² has revealed the processes responsible for the slope morphology and channel sedimentation across the forearc slope-basin of the Kurile Arc–NE Japan Arc collision zone, offshore from Tokachi (Hokkaido, Japan). The dominant slope contours parallel the trench but, in the middle and lower reaches of the southern slope, contours are convex-shaped with an offshore trend. This sector of the slope is traversed diagonally by the Hiroo submarine channel. The offshore-trending convex contours and the channel course have developed through the interplay of tectonic and sedimentary processes, including the development of anticlines, anticline-induced lobe sedimentation and channel avulsion. In its upper reaches, the channel is restricted by a topographic low associated with NNW–SSE-trending anticlines which developed within the upper and middle slope sectors during late Miocene uplift. The uplift timing and trend of these anticlines indicate that they resulted from collision, the channel sedimentology and slope morphology of the middle and lower slopes having been influenced by Pliocene uplift of NE–SW-trending anticlines. The trends of these anticlines parallel those of the Kurile Trench. The Pliocene and early Pleistocene strata of the middle and lower slopes consist of ponded lobe sediments deposited along the palaeo-Hiroo submarine channel on the landward side of the anticlines. As a lobe pile accumulated, the channel thalweg shifted to the north of the stack, allowing the channel to bypass the topographic high formed by the growing stack. Thick levee deposits built up along the channel course during the late Pleistocene and Holocene. These levees, along with the Pliocene and early Pleistocene lobes, are reflected in the present-day sigmoid-shaped, convex offshore-trending contours. Thus, the interplay of subduction- and collision-related anticlines, tectonic-related channel ponding, and avulsion has contributed to the slope morphology of the southern Kurile Trench.