The influence of colloidal material on aluminium speciation and estimated acid neutralising capacity (ANC)

Cationic Al species (Al_i) cause toxic effects towards fish in acidified water. As several factors can influence the Al_i-speciation, acid neutralising capacity (ANC) has been applied as an alternative indicator for acidification and effects towards fish. However, the critical range of ANC for biological stress has been shown to be dependent upon the concentration of organic material (DOC). Using in situ size fractionation techniques the influence of particulate and colloidal DOC (0–400 μM) on Al_i-speciation and ANC-values was investigated in Norwegian streams. During high flow events with high river transport of DOC the Al_i concentration increased by a factor of 2 due to retention of colloidal Al species (>10 kDa), probably organic, in the chromatography column. Ultrafiltration (?10 kDa) of water prior to chromatography reduced the influence of non-toxic organic Al-species, on Al_i-speciation. The charge balanced ANC-values (ANC_cb) were also significantly lower (on average 34 μeq L⁻¹) in ultrafiltered water compared to unfiltered water samples, as base cations were associated with colloidal DOC (>10 kDa to 0.45 μm) and organic acids were not incorporated in the ANC_cb estimate. Thus, ANC_cb will underestimate the acidification effects towards fish in organic waters increasing with concentration of colloidal DOC present. Alkalinity based ANC-values (ANC_alk), which include a fraction of organic acids, were similar in unfiltered and ultrafiltered waters, but higher than ANC_cb-values of ultrafiltered samples. Thus, ANC_alk-values also underestimate the acidification effects on fish in organic waters. Based on ultrafiltered samples, however, ANC_cb-values was negatively correlated with Al_i independent of the DOC present and thus a more correct indicator for toxic Al-species.     

Monitoring the freely dissolved concentrations of polycyclic aromatic hydrocarbons (PAH) and alkylphenols (AP) around a Norwegian oil platform by holistic passive sampling

In order to assess the environmental impact of aquatic discharges from the offshore oil industry, polar organic chemical integrative samplers (POCIS) and semipermeable membrane devices (SPMDs) were deployed around an oil platform and at reference locations in the North Sea. Exposure to polycyclic aromatic hydrocarbons (PAH) and alkylated phenols (AP) was determined from passive sampler accumulations using an empirical uptake model, the dissipation of performance reference compounds and adjusted laboratory derived sampling rates. Exposure was relatively similar within 1–2 km of the discharge point, with levels dominated by short chained C1–C3 AP isomers (19–51 ng L⁻¹) and alkylated naphthalenes, phenanthrenes and dibenzothiophenes (NPD, 29–45 ng L⁻¹). Exposure stations showed significant differences to reference sites for NPD, but not always for more hydrophobic PAH. These concentrations are several orders of magnitude lower than those reported to give both acute and sub-lethal effects, although their long term consequences are unknown.     

Continental margin off Western India and Deccan Large Igneous Province

Massive, transient late syn-rift-to-breakup volcanism during separation between the Seychelles microcontinent and India formed the Deccan continental flood basalts and their equivalents on the Seychelles-Mascarene Plateau and on the conjugate continental margins, i.e. the Deccan Large Igneous Province. We estimate an original extrusive area of at least 1.8×10⁶ km², and a volume >1.8×10⁶ km³, and suggest a plate tectonic model comprising: (1) development of the Seychelles microplate by fan-shaped spreading in the Mascarene Basin, and continental extension followed by fan-shaped spreading between India and the Seychelles during A29-27 time. (2) Cessation of fan-shaped spreading just after A27 time, followed by spreading along the India-Seychelles plate boundary. (3) Margin subsidence, modified south of Goa by the persistent, time-transgressive effects along the plume trail. The margin is divided into three regional provinces by the prolongation of regional transforms which formed the east and west boundaries of the Seychelles microplate during breakup and early sea floor spreading. In some aspects, the conjugate margins are different from other volcanic margins; e.g. regional wedges of seaward dipping reflectors along the continent-ocean transition have not yet been reported. We ascribe this to the eruption of the most voluminous lavas during chron 29r, i.e on continental lithosphere in a late syn-rift setting. The enigmatic Laxmi Ridge is a complex marginal high comprised of both continental and oceanic crust. It was probably created during breakup, but may have experienced later magmatic and/or tectonic deformation.     

Norwegian marine geodetic projects

The hitherto promising finds of oil and gas on the Norwegian continental shelf have increased the general activity in this area considerably. Consequently, the need for better charts and more precise navigational systems have become more pertinent. During the past few years a number of marine geodetic projects have either been planned or embarked upon by various organizations within both the public and private sectors. This article gives a brief review of the Norwegian projects which have special relevance to marine geodesy; this includes the following areas: recommendations, requirements, precision navigation, satellite positioning, reference systems, boundary problems, bathymetry, geological mapping, marine geoid determination, and data base developments. The reference list will give the reader more detailed sources of information.     

Estimation of pore‐pressure change in a compacting reservoir from time‐lapse seismic data

An approach is developed to estimate pore‐pressure changes in a compacting chalk reservoir directly from time‐lapse seismic attributes. It is applied to data from the south‐east flank of the Valhall field. The time‐lapse seismic signal of the reservoir in this area is complex, despite the fact that saturation changes do not have an influence. This complexity reflects a combination of pressure depletion, compaction and stress re‐distribution throughout the reservoir and into the surrounding rocks. A simple relation is found to link the time‐lapse amplitude and time‐shift attributes to variations in the key controlling parameter of initial porosity. This relation is sufficient for an accurate estimation of pore‐pressure change in the inter‐well space. Although the time‐lapse seismic estimates mostly agree with reservoir simulation, unexplained mismatches are apparent at a small number of locations with lower porosities (less than 38%). The areas of difference between the observations and predictions suggest possibilities for simulation model updating or a better understanding of the physics of the reservoir.     

A continuous velocity field for Norway

In Norway, as in the rest of Fennoscandia, the process of Glacial Isostatic Adjustment causes ongoing crustal deformation. The vertical and horizontal movements of the Earth can be measured to a high degree of precision using GNSS. The Norwegian GNSS network has gradually been established since the early 1990s and today contains approximately 140 stations. The stations are established both for navigation purposes and for studies of geophysical processes. Only a few of these stations have been analyzed previously. We present new velocity estimates for the Norwegian GNSS network using the processing package GAMIT. We examine the relation between time-series length and precision. With approximately 3.5 years of data, we are able to reproduce the secular vertical rate with a precision of 0.5 mm/year. To establish a continuous crustal velocity field in areas where we have no GNSS receivers or the observation period is too short to obtain reliable results, either interpolation or modeling is required. We experiment with both approaches in this analysis by using (i) a statistical interpolation method called Kriging and (ii) a GIA forward model. In addition, we examine how our vertical velocity field solution is affected by the inclusion of data from repeated leveling. Results from our geophysical model give better estimates on the edge of the network, but inside the network the statistical interpolation method performs better. In general, we find that if we have less than 3.5 years of data for a GNSS station, the interpolated value is better than the velocity estimate based on a single time-series.     

The look of agricultural landscapes – How do non-crop landscape elements contribute to visual preferences in a large-scale agricultural landscape?

ABSTRACT

Efficiency in agricultural food production has long been in focus and this has affected the spatial structure of agricultural land use. One outcome has been extensive criticism based on a wide range of negative consequences, such as for biodiversity, accessibility, cultural heritage, and aesthetics. In line with the European Landscape Convention (ELC), management of people’s everyday landscapes is important. In Norway, agricultural landscapes are the ‘everyday landscape’ for a large proportion of the population. The aim of the article is to contribute to the understanding of landscape changes perceived as positive or negative by the inhabitants. The authors focused on grain-crop dominated landscapes and the impact of smaller non-crop elements on people’s landscape preferences. They administered a photo-based questionnaire using manipulated photos to assess preferences for different agricultural landscapes. Additionally, people’s perceived objectives for the agricultural sector and agriculture’s primary functions were assessed. The results documented positive perceptions of added landscape elements and that people were both aware of and agreed on the multifunctional role of agriculture. The authors conclude that if the public’s preferences are to be taken into consideration, such as during policymaking, it is important to maintain various landscape elements in the large-scale grain field landscapes of Norway.     

Quantifying sediment connectivity: Moving toward a holistic assessment through a mixed methods approach

The sediment connectivity concept is particularly suitable for tackling complex, multidisciplinary questions through systems thinking. However, it is unclear how to directly measure connectivity, and so proxy variables are often applied by indices to provide estimates. In this study, we critically evaluate a broad range of connectivity indices encompassing structural and functional connectivity as well as hillslope channel coupling. We then discuss their role in providing a more holistic estimation of connectivity within the Tahoma Creek Watershed, WA. Of the 14 km of channel below the glacier front, the upper 6 km (0–6 km) are coupled to the adjacent hillslopes. Coupled reaches correspond to regions with a high proportion of area contributing sediment and relatively high connectivity values, where all measures decrease in the downstream direction. A significant transition occurs near river kilometer 6. Here the valley bottom abruptly widens, deposition occurs, and the hillslopes become decoupled from the active channel. This transitional reach is also identified as a geomorphic hotspot based on the network structure. The lower 8 km of channel downstream of this reach are largely depositional and percent contributing area and connectivity values remain low, eventually reaching a minimum. Despite their limitations, we found each method to provide unique and useful information regarding connectivity. The effect of scale and event magnitude on connectivity is illustrated. We also found vegetation, topographic characteristics, and network structure to be important in high-gradient glacio-volcanic landscapes. The choice of an index will depend on the research objectives, data availability, and the proxy variables that best describe the variability within the defined area.