Effects of oilfield brine effluent on sediments and benthic organisms in trinity bay,Texas

Field studies have established the concentrations of naphthalenes in bay sediments and water in the vicinity of an oil separator platform and their effects on the benthic fauna. Fifteen stations were occupied monthly, from July, 1974 to December, 1975, along three transects extending from the separator platform outfall outwards for a distance of 4·0 to 5·6 km. A lesser number of stations were occupied from April, 1974 to June, 1974. Bottom sediments at each station were analysed for total naphthalenes content and for number of species and individuals. All stations were located in 2 to 3 m of water. The outfall was located 1 m off the bay bottom.There was a definite correlation between sediment naphthalenes concentration and number of species and individuals. As expected, the first station, located 15 m from the outfall, had the highest concentration of naphthalenes of all stations sampled. The naphthalenes levels dropped sharply from the outfall to the stations located 75 m from the platform where levels were about 20–50% of those found 15 m from the outfall. Naphthalenes concentrations then decreased gradually to near background levels at stations farther out. Hydrocarbon concentrations in bottom water 15 m from the outfall were three orders of magnitude lower than those in the full strength effluent, but sediments 15 m from the outfall had hydrocarbon concentrations four times as great as in the full strength effluent. There were approximately four orders of magnitude more hydrocarbons in the sediment than in the overlying water.The bay bottom was almost completely devoid of organisms within 15 m of the effluent outfall. Stations located 150 m from the outfall had severely depressed benthic faunas but not to the extent of stations nearer the outfall. Stations located 455 m from the platform were unaffected. Both numbers of species and individuals increased with distance from the platform and reached a peak at the first station medial to the control on each transect (685 to 1675 m from the platform) and then dropped at the control station. Physical environmental factors such as temperature, salinity, water depth and sediment type were essentially the same at all stations.The temporary use of a second outfall located 275 m from the main platform outfall resulted in a rapid build up of naphthalenes in surrounding sediments which persisted for at least six months following the termination of use of the second outfall. The benthic fauna was also severely depressed in the vicinity of the second outfall. The use of multiple outfalls, located some distance apart, appears to be more harmful than the use of a single outfall.Trinity Bay, Texas, the site of this investigation, has a mean depth of 2·5 m. The bay water is highly turbid due to the presence of a high concentration of clay-sized particulate material. The brine outfall was located approximately 1 m above the bay bottom. These special conditions undoubtedly contributed significantly to the observed impact of the brine. Therefore, extrapolations from the results of this study to offshore oil production and brine disposal should be made with extreme caution.     

Upwelling front and two-cell circulation in a two-dimensional model

The intensification of upwelling front and two-cell circulation is studied numerically in a two dimensional level model. Upwelling front is set initially with longshore geostrophic flow. The uniform wind stress forces the ocean which has an infinite north-south coast line. Two-cell circulation, downwelling just inshore-side of the front and upwelling offshore-side, is induced, and the front is intensified. It is found that the intensification is occurred in the inshore-side of the front, and the intensification is basically due to the deviation from the thermal-wind balance, as is shown bySuginohara (1977). It is found that the inshore-side cell intrudes under the pycnocline. It seems to reproduce the observed two-cell circulation.     

Spatial Heterogeneity in Distributions of Chlorophyll a Derivatives in the Subarctic North Pacific during Summer

The distribution of chlorophyll a derivatives was examined in samples collected from the subarctic North Pacific during July to September 1997. Pheophorbide a, pheophytin a and pyropheophorbide a as determined by high performance liquid chromatography (HPLC) were the major derivatives recorded. The distribution patterns of chlorophyll a and its derivatives showed a strong vertical and horizontal heterogeneity. Patches with high concentration of derivatives seemed to be associated with high concentration of chlorophyll a. A clear east-west gradient was observed in both chlorophyll a and pheophorbide a integrated from the surface to 100 m depth with significantly higher amounts of both the pigments in the Western Subarctic Gyre and in the Bering Sea than in the Alaskan Gyre. In contrast, no apparent gradient was observed in the integrated pyropheophorbide a and pheophytin a. Grazing experiments conducted with the copepod (Neocalanus cristatus) and salp (Cyclosalpa bakeri) fed on five species of phytoplankton cultures, showed a marked difference in the composition of the derivatives in their fecal pellets. Pyropheophorbide a was dominant in the copepod fecal pellet regardless of the phytoplankton species fed on. In the salp, however, pheophytin a and pheophorbide a were found in the fecal pellets, the relative concentrations varying with the algal food. Spatial heterogeneity in the distribution of the derivatives is considered to reflect local variations in dominant herbivorous processes.     

Tectonics of the Nereus Deep,Red Sea: A deep-tow investigation of a site of initial rifting

The Nereus Deep (23°N) lies in the central portion of the Red Sea, in a region which marks a transition between the nearly continuous axial rift valley of the southern Red Sea and the northern Red Sea, where a well defined axial rift is absent. The deep-tow survey and associated heat flow measurements reported here show that the Nereus Deep is a short segment of axial rift, and it is the northernmost deep where petrology, heat flow, magnetics, and morphology all indicate classic seafloor spreading. Heat flow measured in the Nereus Deep is characterized by non-linear gradients and closely-spaced variability indicative of active hydrothermal circulation associated with seafloor spreading. The two axial highs which we have mapped in Nereus differ markedly in that the southernmost appears younger or at least has had a more recent phase of volcanism. The two axial highs are offset left laterally approximately 2 km. This small offset or bend in the axial course has been labelled the Nereus shear zone, and, despite its small extent, it mimics many of the major features of small offset, slow-slipping transform faults. This shear zone may result from shear stresses associated with misalignments in succeeding volcanic episodes. The Nereus Deep appears to represent one of the earliest phases of seafloor spreading. The Red Sea seems to be opening towards the north, and the Nereus Deep is near the tip of propagation, but it is clear from this study that rift propagation in a site of initial rifting differs greatly from that observed along a well developed, fast spreading center like the East Pacific Rise.     

Distribution of riverine sediment chemistry on the shelf,slope and rise of the Gulf of Papua

The tectonically active islands of the Indo-Pacific Archipelago deliver much sediment to the ocean margins. In the Gulf of Papua on the south coast of Papua New Guinea (PNG), the chemical composition of surface sediment from grab samples indicates that Fly River muds are dispersed to the north and east, where they are joined by sediment plumes from the other large rivers along the south coast of PNG. This is the likely source of terrestrial sediment on the Papuan Plateau and the northern Coral Sea Abyssal Plain. The sediment is transported through submarine troughs and canyons offshore, far to the east of the riverine inputs. Immediately south and 30–50 km offshore from the Fly and Purari deltas is a platform of algal and reef carbonate materials, containing little or no terrestrial surface sediment.     

A time-series study of particulate matter export in the North Pacific Subtropical Gyre based on Th : U disequilibrium

Depth profiles of total ²³⁴Th (dissolved+particulate) were collected at Station ALOHA (22°45N, 158°00W) in the North Pacific Subtropical Gyre during 9 cruises from April 1999 to March 2000. Samples were collected and processed by a new 2 L technique that enables more detailed depth resolution then previous ²³⁴Th studies. Significant zones of particle export (²³⁴Th deficiency) and particle remineralization (²³⁴Th excess) were measured both temporally and with depth. ²³⁴Th derived particulate carbon (PC) and nitrogen (PN) fluxes were determined with steady-state and non-steady-state models and PC/²³⁴Th and PN/²³⁴Th ratios measured with both in situ pumps and free-drifting particle interceptor traps deployed at 150 m. ²³⁴Th based export estimates of 4.0±2.3 mmol C m⁻² d⁻¹ and 0.53±0.19 mmol N m⁻² d⁻¹, were approximately 60% higher than those measured in PIT style sediment traps from the same time period, 2.4±0.2 mmol C m⁻² d⁻¹ and 0.32±0.08 mmol N m⁻² d⁻¹. Most of this difference is attributable to two large export events that occurred during October and December 1999, when traps undercollected for ²³⁴Th by a factor of 2 to 4. ²³⁴Th export (ThE) ratios based on ²³⁴Th derived PC flux/¹⁴C based primary production ranged from 4% to 22% (average=8.8%). Our results confirm the recent estimates of C export by Emerson et al. (Nature 389 (1997) 951) and Sonnerup et al. (Deep-Sea Research I 46 (1999) 777) and indicate that C export from the oligotrophic ocean must be considered when discussing C sequestration in global climate change.     

An overview of the ecosystems of the Barents and Norwegian Seas and their response to climate variability

The principal features of the marine ecosystems in the Barents and Norwegian Seas and some of their responses to climate variations are described. The physical oceanography is dominated by the influx of warm, high-salinity Atlantic Waters from the south and cold, low-salinity waters from the Arctic. Seasonal ice forms in the Barents Sea with maximum coverage typically in March–April. The total mean annual primary production rates are similar in the Barents and Norwegian Seas (80–90 g C m⁻²), although in the Barents, the production is higher in the Atlantic than in the ice covered Arctic Waters. The zooplankton is dominated by Calanus species, C. finmarchicus in the Atlantic Waters of the Norwegian and Barents Seas, and C. glacialis in the Arctic Waters of the Barents Sea. The fish species in the Norwegian Sea are mostly pelagics such as herring (Clupea harengus) and blue whiting (Micromesistius poutassou), while in the Barents Sea there are both pelagics (capelin (Mallotus villosus Müller), herring, and polar cod (Boreogadus saida Lepechin)) and demersals (cod (Gadus morhua L.) and haddock (Melanogrammus aeglefinus)). The latter two species spawn in the Norwegian Sea along the slope edge (haddock) or along the coast (cod) and drift into the Barents Sea. Marine mammals and seabirds, although comprising only a relatively small percentage of the biomass and production in the region, play an important role as consumers of zooplankton and small fish. While top-down control by predators certainly is significant within the two regions, there is also ample evidence of bottom-up control. Climate variability influences the distribution of several fish species, such as cod, herring and blue whiting, with northward shifts during extended warm periods and southward movements during cool periods. Climate-driven increases in primary and secondary production also lead to increased fish production through higher abundance and improved growth rates.     

Phytoplankton distribution in a frontal region of Tokyo Bay,Japan in November 1985

Phytoplankton distribution in a frontal region of Tokyo Bay was investigated in relation to hydrography in November 1985. The frontal region was observed from the central to the mouth area of the bay and consisted of a series of fine scale discontinuities of salinity and temperature. Among them the Kenzaki offshore front (KOF) and the Yokosuka inshore front (YIF) were most prominent in terms of the duration and the magnitudes of the hydrographic gaps. Three major phytoplankton assemblages were observed: (A) neritic and offshore diatoms in the mouth area of Tokyo Bay, (B) a diatomLeptocylindrus danicus and dinoflagellates in the central area, and (C) bloom forming cryptophyceans, dinoflagellates andL. danicus from the inner Tokyo Bay. The KOF was an approximate boundary of the outside assemblage (A) and the intermediate population (B), and the YIF was that of (B) and the inner bay population (C). Species changes across the fronts were rather gradual in the KOF making a strong contrast to distinct jumps in temperature, salinity,in vivo chlorophyll fluorescence and nitrate plus nitrite. An outward surface flow of the inside population along the western coast off Yokosuka was detected.     

A review of present techniques and methodological advances in analyzing Th in aquatic systems

The short-lived thorium isotope ²³⁴Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of ²³⁴Th in both marine and freshwater systems. The original ²³⁴Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of ²³⁴Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate ²³⁴Th analytical technique for a specific aquatic regime and known sampling constraints.