East Asia: Seismotectonics,magmatism and mantle dynamics

In this article, we review the significant recent results of geophysical studies and discuss their implications on seismotectonics, magmatism, and mantle dynamics in East Asia. High-resolution geophysical imaging revealed structural heterogeneities in the source areas of large crustal earthquakes, which may reflect magma and fluids that affected the rupture nucleation of large earthquakes. In subduction zone regions, the crustal fluids originate from the dehydration of the subducting slab. Magmatism in arc and back-arc areas is caused by the corner flow in the mantle wedge and dehydration of the subducting slab. The intraplate magmatism has different origins. The continental volcanoes in Northeast Asia (such as Changbai and Wudalianchi) seem to be caused by the corner flow in the big mantle wedge (BMW) above the stagnant slab in the mantle transition zone and the deep dehydration of the stagnant slab as well. The Tengchong volcano in Southwest China is possibly caused by a similar process in BMW above the subducting Burma microplate (or Indian plate). The Hainan volcano in southernmost China seems to be a hotspot fed by a lower-mantle plume associated with the Pacific and Philippine Sea slabs’ deep subduction in the east and the Indian slab’s deep subduction in the west down to the lower mantle. The occurrence of deep earthquakes under the Japan Sea and the East Asia margin may be related to a metastable olivine wedge in the subducting Pacific slab. The stagnant slab finally collapses down to the bottom of the mantle, which may trigger upwelling of hot mantle materials from the lower mantle to the shallow mantle beneath the subducting slabs and cause the slab–plume interactions. Some of these issues, such as the origin of intraplate magmatism, are still controversial, and so further detailed studies are needed from now.     

Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Stability of dense hydrous magnesium silicate phases in the systems Mg2SiO4-H2O and MgSiO3-H2O at pressures up to 27 GPa

We conducted high-pressure phase equilibrium experiments in the systems MgSiO₃ with 15 wt% H₂O and Mg₂SiO₄ with 5 wt% and 11 wt% H₂O at 20 ∼ 27 GPa. Based on the phase relations in these systems, together with the previous works on the related systems, we have clarified the stability relations of dense hydrous magnesium silicates in the system MgO-SiO₂-H₂O in the pressure range from 10 to 27 GPa. The results show that the stability field of phase G, which is identical to phase D and phase F, expands with increasing water contents. Water stored in serpentine in the descending cold slabs is transported into depths greater than 200 km, where serpentine decomposes to a mixture of phase A, enstatite, and fluid. Reaction sequences of the hydrous phases which appear at higher pressures vary with water content. In the slabs with a water content less than about 2 wt%, phase A carries water to a depth of 450 km. Hydrous wadsleyite, hydrous ringwoodite, and ilmenite are the main water reservoirs in the transition zone from 450 to 660 km. Superhydrous phase B is the water reservoir in the uppermost part of the lower mantle from 670 to 800 km, whereas phase G appears in the lower mantle only at depths greater than 800 km. In cold slabs with local water enrichment greater than 2 wt%, the following hydrous phases appear with increasing depths; phase A to 450 km, phase A and phase G from 450 km to 550 km, brucite, superhydrous phase B, and phase G from 550 km to 800 km, and phase G at depths greater than 800 km. Received: 4 August 1999 / Accepted: 1 March 2000     

Interaction of Fe and Fe<Subscript>3</Subscript>C with hydrogen and nitrogen at 6–20 GPa: a study by in situ X-ray diffraction

A method of in situ X-ray diffraction at Spring-8 (Japan) was used to analyze simultaneously the hydrogen incorporation into Fe and Fe₃C, as well as to measure the relative stability of carbides, nitrides, sulfides, and hydrides of iron at pressures of 6–20 GPa and temperatures up to 1600 K. The following stability sequence of individual iron compounds was established in the studied pressure and temperature interval: FeS > FeN > FeC > FeH > Fe. A change in the unit-cell volume as compared to the known equations of state was used to estimate the hydrogen contents in carbide Fe₃C and hydride FeH_x. Data on hydride correspond to stoichiometry with x ≈ 1. Unlike iron sulfides and silicides, the solubility of hydrogen in Fe₃C seemed to be negligibly low—within measurement error. Extrapolating obtained data to pressures of the Earth’s core indicates that carbon and hydrogen are mutually incpompatible in the iron–nickel core, while nitrogen easily substitutes carbon and may be an important component of the inner core in the light of the recent models assuming the predominance of iron carbide in its composition.     

On Seasonal and Year to Year Variation in Flow of the Alaskan Stream in the Central North Pacific

The Alaskan Stream is the westward boundary current of the North Pacific subarctic gyre. In the central region of the North Pacific, the Alaskan Stream serves as a connection between the Alaskan gyre, Western subarctic gyre and Bering Sea gyre. Its volume transport is very important in estimating the magnitude of the subarctic circulation in the North Pacific. In order to clarify its seasonal and interannual variation, we conducted observations along a north-south section at 180° during June from 1990 to 1997. Moorings were deployed from 1995 to 1997. Hydrographic casts were made at intervals of 37 km to a depth of 3000 m. Moorings were set between CTD stations, with Moor1 (Moor2) at the center (southern edge) of the Alaskan Stream. Geostrophic volume transport (referred to 3000 m) revealed large interannual variability in the Alaskan Stream. Average volume transport over the 8 years was 27.5 × 10⁶ m³s^-1 with a standard deviation of 6.5 × 10⁶ m³s^-1. Maximum transport was 41.0 × 10⁶ m³s^-1 (1997) and minimum was 21.7 × 10⁶ m³s^-1 (1995). Stable westward flows were observed at Moor1 1500 m (259°, 11.7 cm s^-1) and 3000 m (240°, 3.7 cm s^-1, 1996–1997 year average). The ratio of eddy to mean kinetic energy (KE/ ) was very small (<0.6) throughout the year. A relatively weak and unstable westward flow was observed at Moor2 at 3000 m depth. Conversely, the average flow direction at Moor2 5000 m was eastward.     

Volume transport of the Tsushima Warm Current, west of Tsugaru Strait bifurcation area

Northern and southern latitudinal transects were conducted west of Tsugaru Strait to estimate the volume transport in this area. It was found that the Tsushima Warm Current is the northward volume transport across the southern transect and the Northward Current is the northward volume transport across the northern transect. The current in Tsugaru Strait,viz. the Tsugaru Warm Current, is the flow remaining when the Northward Current is subtracted from the Tsushima Warm Current. Both CTD transects covered from near-shore to west of the subarctic front, and observed depths were from the surface to the bottom or to 1000-1500 m depth. Our estimations indicate that large interannual variations of volume transport occur, relative to the seasonal ones, with interannual variations sometimes exceeding seasonal variations in the Tsushima Warm Current and the Northward Current. The Tsugaru Warm Current has near-steady transport. Fluctuations in the Tsushima Warm Current are thus transmitted to the Northward Current. Further, our results revealed seasonal variations in the flow: the baloclinic structure became deeper in April and the current axis tended to shift in a near-shore direction in October. Therefore, previous studies, which had shallow reference levels and lacked nearshore stations, may have underestimated the transport and excessive seasonal variations.     

Transformation textures,mechanisms of formation of high‐pressure minerals in shock melt veins of L6 chondrites,and pressure‐temperature conditions of the shock events

Abstract— The high‐pressure polymorphs of olivine, pyroxene, and plagioclase in or adjacent to shock melt veins (SMVs) in two L6 chondrites (Sahara 98222 and Yamato 74445) were investigated to clarify the related transformation mechanisms and to estimate the pressure‐temperature conditions of the shock events. Wadsleyite and jadeite were identified in Sahara 98222. Wadsleyite, ringwoodite, majorite, akimotoite, jadeite, and lingunite (NaAlSi₃O₈‐hollandite) were identified in Yamato 74445. Wadsleyite nucleated along the grain boundaries and fractures of original olivine. The nucleation and growth of ringwoodite occurred along the grain boundaries of original olivine, and as intracrystalline ringwoodite lamellae within original olivine. The nucleation and growth of majorite took place along the grain boundaries or fractures in original enstatite. Jadeite‐containing assemblages have complicated textures containing “particle‐like,” “stringer‐like,” and “polycrystalline‐like” phases. Coexistence of lingunite and jadeite‐containing assemblages shows a vein‐like texture. We discuss these transformation mechanisms based on our textural observations and chemical composition analyses. The shock pressure and temperature conditions in the SMVs of these meteorites were also estimated based on the mineral assemblages in the SMVs and in comparison with static high‐pressure experimental results as follows: 13–16 GPa, >1900 °C for Sahara 98222 and 17–24 GPa, >2100 °C for Yamato 74445.     

Melting of iron–silicon alloy up to the core–mantle boundary pressure: implications to the thermal structure of the Earth’s core

The melting temperature of Fe–18 wt% Si alloy was determined up to 119 GPa based on a change of laser heating efficiency and the texture of the recovered samples in the laser-heated diamond anvil cell experiments. We have also investigated the subsolidus phase relations of Fe–18 wt% Si alloy by the in-situ X-ray diffraction method and confirmed that the bcc phase is stable at least up to 57 GPa and high temperature. The melting curve of the alloy was fitted by the Simon’s equation, P(GPa)/a = (T _m(K)/T ₀) ^c , with parameters, T ₀ = 1,473 K, a = 3.5 ± 1.1 GPa, and c = 4.5 ± 0.4. The melting temperature of bcc Fe–18 wt% Si alloy is comparable with that of pure iron in the pressure range of this work. The melting temperature of Fe–18 wt% Si alloy is estimated to be 3,300–3,500 K at 135 GPa, and 4,000–4,200 K at around 330 GPa, which may provide the lower bound of the temperatures at the core–mantle boundary and the inner core–outer core boundary if the light element in the core is silicon.     

Melting temperature distribution and fractionation in the lower mantle

The melting curve of perovskite MgSiO₃ and the liquidus and solidus curves of the lower mantle were estimated from thermodynamic data and the results of experiments on phase changes and melting in silicates.The initial slope of the melting curve of perovskite MgSiO₃ was obtained as $\text{d}\text{T}{}_{\mathrm{<mtext>m</mtext>}}\text{/}\text{d}\text{P?77}\text{K}\text{GPa}{}^{\mathrm{?1}}$ at 23 GPa. The melting curve of perovskite was expressed by the Kraut-Kennedy equation as $\text{T}{}_{\mathrm{<mtext>m</mtext>}}\text{(}\text{K}\text{)=917(}\text{1+29.6ΔV}\text{V}{}_0\text{)}$, where T_m?2900 K and P?23 GPa; and by the Simon equation, $\text{P(}\text{GPa}\text{)?23=21.2[}\text{(T}{}_{\mathrm{<mtext>m</mtext>}}\text{(}\text{K}\text{)}\text{2900)}{}^{1.75}\text{?1}\text{]}$.The liquidus curve of the lower mantle was estimated as $\text{T}{}_{\mathrm{<mtext>liq</mtext>}}\text{? 0.9 T}{}_{\mathrm{<mtext>m</mtext>}}$ (perovskite) and this gives the liquidus temperature T_liq=7000 ±500 K at the mantle-core boundary. The solidus curve of the lower mantle was also estimated by extrapolating the solidus curve of dry peridotite using the slope of the solidus curve of magnesiowüstite at high pressures. The solidus temperature is ～ 5000 K at the base of the lower mantle. If the temperature distribution of the mantle was 1.5 times higher than that given by the present geotherm in the early stage of the Earth's history, partial melting would have proceeded into the deep interior of the lower mantle.Estimation of the density of melts in the MgOFeOSiO₂ system for lower mantle conditions indicates that the initial melt formed by partial fusion of the lower mantle would be denser than the residual solid because of high concentration of iron into the melt. Thus, the melt generated in the lower mantle would tend to move downward toward the mantle-core boundary. This downward transportation of the melt in the lower mantle might have affected the chemistry of the lower mantle, such as in the D″ layer, and the distribution of the radioactive elements between mantle and core.     

Space group and hydrogen sites of δ-AlOOH and implications for a hypothetical high-pressure form of Mg(OH)<Subscript>2</Subscript>

The space group and hydrogen positions of -(Al_0.84Mg_0.07Si_0.09)OOH are investigated using a single crystal synthesized using a multi-anvil apparatus under conditions of 1000 °C and 21 GPa. The space group determined by single-crystal X-ray diffraction is to Pnn2, with unit-cell parameters of a=4.6975(8) Å, b= 4.2060(6) Å, c=2.8327(4) Å, and V=55.97(1) ų. Partial occupancy of the Al site by Mg and Si suggests the possibility of a limited solid solution between -AlOOH, stishovite, and a hypothetical CaCl₂-type Mg(OH)₂ that is 16% denser than brucite. Difference-Fourier maps reveal two small but significant Fourier peaks attributable to hydrogen atoms. Atomic distances and angles around the first peak indicate a hydrogen bond with O···O distances of 2.511 Å, while those around the second peak are suggestive of a bifurcated hydrogen bond with O···O distances of 2.743 and 2.743 Å.