青藏高原东部新生代钾质碱性系列岩石地球化学特征:岩石成因及其地质意义

青藏高原东部新生代钾质碱性系列的岩石,包括深成岩、火山岩和煌斑岩,在时空上具有一致性,岩石化学成分均富碱、高钾、K2O/Na2O比值远大于1,高度富集Sr、Ba等大离子亲石元素(LILE)和轻稀土元素(LREE),亏损Nb、Ta等高场强元素(HFSE),及物质来源于富集地幔源区的Sr、Nd、Pb同位素组成等,均显示钾质碱性系列的岩石特有的特征,其形成与印度和欧亚两大陆碰撞,导致青藏高原北、东部在40Ma左右出现的大型走滑拉分带,致使地壳变薄以及地幔上拱的构造背景有关。     

青藏高原东缘构造演化的SHRIMP锆石U-Pb年代学框架

青藏高原东缘一直被普遍认为是一个吸收印度—欧亚大陆碰撞变形的调节带。本文所获得的最新SHRIMP锆石U-Pb测年结果显示:青藏高原东缘具有更加复杂的地质历史。测年结果表明,高原东缘最古老的前寒武纪结晶基底形成于古元古代(2401~1912Ma)。这一古老基底首先受到中元古代构造热事件(1361~1040Ma)的影响,随后受到新元古代与弧岩浆活动有关构造热事件(791~817Ma)的强烈改造。松潘—甘孜复理石杂岩的基底是亲洋壳型的,形成于晚新元古代的大陆裂解作用(681~655Ma)。高原东缘的前寒武纪微地块可能是由这次裂解作用从扬子或青藏地块拉裂出去形成的。这些微陆块先增生拼贴于东冈瓦纳大陆、然后又从中裂离,并最终卷入高原东缘的特提斯构造演化过程中。伴随东冈瓦纳大陆裂解,高原东缘古特提斯洋于石炭纪至二叠纪早期拉开(328~292Ma),经早中生代弧-陆碰撞作用闭合(224~213Ma)。中侏罗世这一地区发育显著的构造岩浆活动(175Ma),但其动力学背景仍不十分清楚。晚白垩世岩浆活动(97Ma)可能是印度板块初始俯冲阶段的产物。新生代岩浆作用(18Ma)与陆-陆碰导致的大规模走滑断层作用所引起的同熔作用有关。     

CCSD主孔榴辉岩中磷灰石的矿物化学特征及对榴辉岩中F、Cl、Sr等元素地球化学行为的影响

为探讨榴辉岩中磷灰石的矿物化学特征及榴辉岩中某些相关元素的地球化学行为,对中国大陆科学钻探(CCSD)主孔500~540m深度的榴辉岩样品进行了岩石化学及磷灰石的矿物化学分析。这些榴辉岩具有不同的矿物组成和化学成分,并可据此分为上下两段,上段500~530m为正常榴辉岩,下段530~540m为高Ti榴辉岩和高Ti-Fe榴辉岩,其原岩可能为类似于辉长质和苦橄质的基性—超基性岩石。其中的磷灰石成分没有明显差别,均为氟—磷灰石,其富F贫Cl的特征可能是造成榴辉岩中高盐度流体包裹体和全岩高F低Cl的主要原因。磷灰石普遍含有一定的Sr、S、Fe元素,多数还含有Cu、Pb、Zn等元素。榴辉岩中P2O5含量与其F、Cl、Sr、S元素的相关程度表明,磷灰石是榴辉岩中F元素的最主要储存库,也是Sr元素的重要储存库之一,而对于Cl元素则只是部分控制,与S元素则没有相关性。榴辉岩中F、Sr及Cl元素的地球化学行为主要受控于磷灰石,因此,在榴辉岩从进变质—退变质过程中,这些元素的活动性直接受控于磷灰石的稳定性。     

上地幔超高压流体的金刚石压砧实验研究

地球深部流体主要是NaCl-H2O溶液,越到地球深部,它赋存的温度、压力越高,性质状态也不断变化,反之,亦然。当NaCl-H2O流体进入和脱离(上升过程)超临界状态时,其性质会发生截然不同的变化,影响着各种地质过程。使用金刚石压砧在高温高压下原位观测流体的实验,用谱学方法,结合同步辐射光源技术,成为定量化研究地球深部高温超高压流体的有效方法。作者使用同步辐射光源的红外谱研究了10GPa下的NaCl-H2O溶液;在地球化学动力学实验室研究了3GPa,650℃下的NaCl-H2O溶液红外谱,此测量方法可以提供温度压力和体积等数据,能研究其状态。NaCl-H2O溶液红外谱表明水分子主要振动谱受压力和温度影响是不同的。压力增加促使水分子主要振动谱向低波数变化。但是温度增加的效应相反。常温高压下水被压缩,结晶向紧密堆积变化。高温高压下的水有气、液、固和超临界流体各相。水分子间的氢键在近临界态开始减弱,氢键网络被破坏。     

四川会理大岩子铂钯矿的地质地球化学特征及找矿前景浅析

四川会理县大岩子铂钯矿床是目前国内品位最高的独立铂族元素矿床之一,也是一个独特的热液成因矿床。矿区及区域上的镁铁质岩浆岩可能是铂族元素的初始来源,震旦系白云岩是其有利的容矿围岩,构造控制下的热液活动促使了铂族元素的迁移富集。地表氧化带蓝铜矿化白云岩矿石的PGE含量最高可达27.13×10-6,坑道中相对新鲜橄辉岩的PGE含量为1.068×10-6,强烈蚀变橄辉岩含PGE0.528×10-6,地表蚀变后橄辉岩的PGE含量为0.435×10-6,表明铂族元素可能发生了活化转移。整个攀西地区基性超基性岩发育,后期构造活动强烈,有利的围岩广泛分布,因而具备形成热液型铂族元素矿床的条件,找矿前景看好。     

白云鄂博矿床东矿段深部及白云向斜核部探矿的可行性探讨

白云鄂博东矿（铁矿石）已属于轻度危机矿山,解决白云鄂博东矿的资源接续问题已迫在眉睫。依据老地质资料和生产过程中的新发现,参考多位矿床成因研究专家的成果,笔者等认为在白云鄂博东矿体深部及白云向斜核部探矿是可行的。     

Mesozoic Bimodal Volcanic Suite in Zhalantun of the Da Hinggan Range and Its Geological Significance： Zircon U-Pb Age and Hf Isotopic Constraints

1 Introduction Mesozoic volcano-intrusive rocks are widely distributed in the Da Hinggan Range of northeastern China, and are considered as one of the most spectacular geological sights in eastern Asia. Recently, studies on granites with high εNd(t) values and Phanerozoic crustal growth in the Centra Asian Orogenic Belt have greatly promoted fundamental research into the geology of this area (Jahn et al., 2000, 2001, 2004; Wu et al., 2000, 2002, 2003). However, work on the eruption time,…     

Discovery of Paleogene Sporopollen from the Matrix Strata of the Naij Tal Group-Complex in the Eastern Kunlun Orogenic Belt

The Naij Tal Group-complex is a suite of tectonic-sedimentary melange aggregation of the Eastern Kunlun orogenic belt, which is composed of two parts, i.e. the exotic blocks of various ages and the matrix strata. On the basis of coral, brachiopod and gastropod fossils found in the exotic blocks, the age of this group-complex was once defined to the Late Ordovician or the Paleozoic. This paper reports for the first time 44 genera and 31 species of Mid-Late Oligocene sporopollen in samples from the matrix strata in this group-complex and the Paleogene Quercoidites-Persicarioipollis assemblage is named. The paper aims to provide some detailed evidence for determining the age of the matrix strata in this group-complex based upon a study at the Caiyuanzigou section, which would be of great geological significance for further understanding this group-complex as a suite of tectonic-sedimentary melange aggregation. The new finding will certainly benefit from now on the investigation of formation and evolution mechanism for the Eastern Kunlun orogenic belt.     

Estimates of global M_2 internal tide energy fluxes using TOPEX/POSEIDON altimeter data

TOPEX/POSEIDON altimeter data from October 1992 to June 2002 are used to calculate the global barotropic M2 tidal currents using long-term tidal harmonic analysis. The tides calculated agree well with ADCP data obtained from the South China Sea (SCS). The maximum tide velocities along the semi-major axis and semi-minor axis can be computed from the tidal ellipse. The global distribution of M2 internal tide vertical energy flux from the sea bottom is calculated based on a linear internal wave generation model. The global vertical energy flux of M2 internal tide is 0.96 TW, with 0.36 TW in the Pacific, 0.31 TW in the Atlantic and 0.29 TW in the Indian Ocean, obtained in this study. The total horizontal energy flux of M2 internal tide radiating into the open ocean from the lateral boundaries is 0.13 TW, with 0.06 TW in the Pacific, 0.04TW in the Atlantic, and 0.03 TW in the Indian Ocean. The result shows that the principal lunar semi-diurnal tide M2 provides enough energy to maintain the large-scale thermohaline circulation of the ocean.     

Isolation and Characterization of Collagen from Squid(Ommastrephes bartrami) Skin

Collagen of squid(Ommastrephes bartrami) skin was examined in the present study. Histology showed that collagen fiber in the skin was partially cross-linked with muscle fiber. Acid-solubilized collagen(ASC) and pepsin-solubilized collagen(PSC) were extracted from the skin and characterized. The results of amino acid composition and electrophoretic patterns revealed that ASC and PSC were both type Ⅰ collagen,containing α1 and α2 chains. FTIR(fourier transform infrared spectroscopy) investigations confirmed t...