Initial volatilization temperatures and average volatilization rates of coal — Their relationship to coal rank and other characteristics

Two thermal parameters, initial volatilization temperature (IVT) and average volatilization rate (AVR), have been determined by thermogravimetric analysis in argon for 38 coal samples ranging in rank from lignite to low-volatile bituminous. Both IVT and AVR are correlated with percent volatile matter and vitrinite reflectance.The IVT values increase gradually from about 250 to 445°C with increasing rank; however, a change in slope is observed in the region of high-volatile bituminous coals (from about 340°C to about 380°C) when IVT's are plotted against percent volatile matter or percent fixed carbon. The changes in slope near 340°C and near 380°C occur at “coalification jumps” recognized on the basis of changes in the optical and chemical character of the macerals. In general, AVR values decrease gradually with increasing rank for the lignite and sub-bituminous coals and for the medium- and low-volatile bituminous coals; however, a sharp increase in AVR occurs in high-volatile bituminous coals. The change in slope of the IVT curves and sharp increase in the AVR values for high-volatile bituminous coals reflect the development of new, higher vapor pressure organic compounds produced during this stage of the coalification process.A plot of AVR vs IVT reveals three regions which correspond to: (1) lignite and sub-bituminous coals; (2) high-volatile bituminous coals; and (3) medium- to low-volatile bituminous coals.     

A fractal-multifractal approach to groundwater contamination. 2. Predicting conservative tracers at the Borden site

 In a companion paper (Puente et al., this issue), the capability of a deterministic fractal-multifractal (FM) approach to faithfully and compactly describe the geometry of chloride and bromide tracers gathered at the Borden site was illustrated. As trends in surrogate parameter space were found for successive plume contours (i.e. linear growth in coordinates by which fractal interpolating functions pass, nearly constant rotations and fairly high scalings), this article reports usage of a variety of prediction schemes, based on linear regressions and the aforementioned trends, in order to study the evolving plumes. It is shown that the FM representation leads to plausible non-Gaussian plume evolutions and yields predictions that closely approximate records for a period of time that extends even beyond one year. It is illustrated that such predicted geometries are also consistent with predictions made via stochastic theories (i.e. Dagan, 1984).     

Age and isotopic studies of some Pan-African granites from North-Central Nigeria

Twenty-nine Rb-Sr whole-rock isotopic analyses and three U-Pb zircon analyses on foliated granites and largely unfoliated charnockitic rocks indicate that the central part of the Pan-African belt in west Africa was characterised by intense orogenic plutonism. These data and Rb-Sr analyses on muscovite books from late cross-cutting pegmatites indicate that the peak of magmatic activity occurred 610 ± 10 m.y. ago.Initial ⁸⁷Sr/⁸⁶Sr ratios for the granitic and charnockitic rocks are in the range 0.7065–0.7125, and indicate a significantly older crustal component in the magmas.     

Heavy metal flows in aquatic systems of the Don and Kuban river deltas

This paper presents the calculated heavy metal (Fe, Mn, Zn, Ni, Cu, Cr, Co, Cd, and Pb) flows in suspended and dissolved forms in the main navigable branches of the Don and Kuban river deltas during the low-water period of 2013–2014. This work is based on the data of field studies in which water and suspended matter samples were collected and the turbidity and water discharge in deltas were measured. A quantitative estimate of heavy metal inflows into the deltas of the Don and Kuban rivers is provided. Transformation of flows of suspended and dissolved metal forms from the delta top to the sea edge is discussed. The influence of localities (Rostov-on-Don, Temryuk) on the increase in heavy metal flows downstream is shown, and the heavy metal flows in the deltas of the Don and Kuban rivers are compared.

     

Regional Problems in Water Use in Siberian Industrial Agglomerations

Water Resources - The basic indicators of regional water use have been identified and assessed as a component of a single social–natural–technogenic system. These indicators have been...     

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.     

Aragonite and calcite preservation in sediments from Lake Iznik related to bottom lake oxygenation and water column depth

This study examines the forcing mechanisms driving long‐term carbonate accumulation and preservation in lacustrine sediments in Lake Iznik (north‐western Turkey) since the last glacial. Currently, carbonates precipitate during summer from the alkaline water column, and the sediments preserve aragonite and calcite. Based on X‐ray diffraction data, carbonate accumulation has changed significantly and striking reversals in the abundance of the two carbonate polymorphs have occurred on a decadal time scale, during the last 31 ka cal bp . Different lines of evidence, such as grain size, organic matter and redox sensitive elements, indicate that reversals in carbonate polymorph abundance arise due to physical changes in the lacustrine setting, for example, water column depth and lake mixing. The aragonite concentrations are remarkably sensitive to climate, and exhibit millennial‐scale oscillations. Extending observations from modern lakes, the Iznik record shows that the aerobic decomposition of organic matter and sulphate reduction are also substantial factors in carbonate preservation over long time periods. Lower lake levels favour aragonite precipitation from supersaturated waters. Prolonged periods of stratification and, consequently, enhanced sulphate reduction favour aragonite preservation. In contrast, prolonged or repeated exposure of the sediment–water interface to oxygen results in in situ aerobic organic matter decomposition, eventually leading to carbonate dissolution. Notably, the Iznik sediment profile raises the hypothesis that different states of lacustrine mixing lead to selective preservation of different carbonate polymorphs. Thus, a change in the entire lake water chemistry is not strictly necessary to favour the preservation of one polymorph over another. Therefore, this investigation is a novel contribution to the carbon cycle in lacustrine systems.     

Planetary nebulae in the Galaxy

It is shown that the planetary nebulae can be divided into three types according to the values of the mass of shell and a central star. The criteria are given using which one can determine the mass type of the nebula. The distance scale of each mass-type planetary nebulae is given. The distribution of planetary nebulae in the Galaxy, their formation rate, scale-height and other physical and kinematic characteristics are investigated. A catalogue of planetary nebulae emitting in the radio range is given.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

Nonstationary pearl pulsations as a signature of magnetospheric disturbances

We analyse long-lasting (several hours) Pc1 pearl pulsations with decreasing, increasing or constant central frequencies. We show that nonstationary pearl events (those with either decreasing or increasing central frequency) are observed simultaneously with increasing auroral magnetic activity at the nightside magnetosphere while the stationary events (constant central frequency) correspond to quiet magnetic conditions. Events with decreasing central frequency are observed mostly in the late morning and daytime whereas events with increasing central frequency appear either early in the morning or in the afternoon. We explain the diurnal distribution of the nonstationary pearl pulsations in terms of proton drifts depending on magnetic activity, and evaluate the magnetospheric electric field based on the variation of the central frequency of pearl pulsations.