The relief of the Swiss Alps and adjacent areas and its relation to lithology and structure: topographic analysis from a 250-m DEM

In this paper we discuss the large-scale geomorphological characteristics of the Swiss Alps based on numerical analysis of a digital elevation model and compare these to an erodibility map constructed from a geotechnical map of Switzerland and regional geomorphological studies. Comparing the erodibility map with the large-scale morphometry shows an intimate relationship between mountain-scale erodibility and topography. On average, higher mean elevations and steeper mean slopes correlate with regions where rocks of low erodibility prevail. Areas with high peaks as well as the main water divides are controlled by the presence of bedrock with low to very low detachability. The drainage network of the Swiss Alps shows a close relationship to the lithological differences as well. Major longitudinal valleys follow easily erodible units. In the eastern and western part of the Swiss Alps, the highest values of local relief are located to the south of the main water divide, whereas in the central part, local relief is higher to the north of the main water divide. The large-scale geomorphic characteristics regarded in the framework of the geological history of uplift and denudation suggest that low and very low erodibilities lead to the development of areas of high elevations which are likely to persist over periods of 10–15 Ma. As the analysis of the Lepontine area shows, 20 Ma after cessation of exhumation, such high elevations are likely to be worn down and to manifest themselves as high relief only.     

Some Problems of Clastogenic Mica Transformation during Anchimetamorphism (Metagenesis)

The transformation of clastogenic muscovite and biotite from the Tyumen superdeep well was studied with the SEM and microprobe techniques. It was shown that under conditions of anchimetamorphism (metagenesis), the white mica becomes unstable and may be replaced by several newly formed minerals. In particular, the brammallite, a sodic analogue of illite, is formed at the expense of sodic component of muscovite. The chloritization of mica provokes the removal of excess silica, which is present in the anchizone as a readily soluble in water modification rather than quartz. The release of excess silica as a result of clastogenic mica destruction may be a source of rock silification. As follows from the review of experimental data on silica solubility, the replacement of many silicate minerals leads to the formation of excess silica. This process can be highly extensive during the breakdown of clastogenic minerals.     

Separating anthropogenic from natural anomalies in environmental geochemistry

Environmental geochemistry has attracted increasing interest during the last decade. In Sweden, geochemical mapping is carried out with methods that allow the data to be used in environmental research, including sampling plant roots and mosses from streams, soils and bedrock. These three sample types form an integrated strategy in environmental research, as well as in geochemical exploration. However, one problem that becomes prominent in geochemical mapping is to distinguish the signals derived from natural sources from those derived from anthropogenic sources. So far, this has mostly been done by using different types of samples, for example, different soil horizons. This is both expensive and time-consuming.We are currently developing alternative statistical solutions to this problem. The method used here is PLSR (partial least squares regression analysis). In this paper, we present an initial discussion on the applicability of PLSR in differentiating anthropogenic anomalies from natural contents.PLSR performs a simultaneous, interdependent principal component analysis decomposition in both X- and Y-matrices, in such a way that the information in the Y-matrix is used directly as a guide for optimal decomposition of the X-matrix. PLSR thus performs a generalized multivariate regression of Y on X overcoming the multicollinearity problem of correlated X-variables. The advantage of PLSR is that it gives optimal prediction ability in a strict statistical sense.Bedrock geochemistry from different lithologies in the mapping area in southern Sweden (Y-matrix) is analyzed together with stream or soil data (X-matrix). By modelling the PLS-regression between these two data sets, separate multivariate geochemical models based on the different bedrock types were developed. This step is called the training or modelling stage of the multivariate calibration. These calibrated models are subsequently used for predicting new (X) geochemical samples and estimating the corresponding Y-variable values. Information is obtained on how much of the metal contents in each new geochemical sample correlate with the different modelled bedrock types.By computing the appropriate X-residuals, we obtain information on the anthropogenic impact that is also carried by these new samples. In this way, it is possible from one single geochemical survey to derive both conventional geochemical background data and anthropogenic data, both of which can be readily displayed as maps.The present study concerns development of data analysis methods. Examples of the applications of the methodology are presented using Pb and U. The results show the share of these contents in different sampling media that is derived from bedrock on the one hand, and from anthropogenic sources, on the other.     

Comparison of acoustic instruments in an atmospheric turbulent flow over water

In the fall of 1968 an International Intercomparison Experiment was conducted to compare, among other things, acoustic anemometers designed for measurements of atmospheric turbulence. Excellent agreement was obtained in measurements of the vertical component, but an important discrepancy was revealed in measurements of the downwind velocity. The discrepancy proved far more significant in the cospectra than in the spectra themselves. It is evident that great care must be taken in the design of such instruments. An acoustic instrument was shown to have insufficient signal-to-noise ratio to serve as a thermometer under the near-neutral conditions often encountered over water.Comparison of the data-handling and data-analysis techniques showed that although the methods differed widely, the results were essentially identical.     

Lead orthophosphates—III. Stabilities of fluoropyromorphite and bromopyromorphite at 25°C

The reactions of secondary lead orthophosphate with approximately 10^?1 M sodium fluoride and sodium bromide solutions have been investigated at 25°C. Interpretation of the solubility data resulted in solubility product constants for fluoropyromorphite and bromopyromorphite of 10^?71.6 and 10^?78.1, respectively. According to these constants, the stability sequence for lead pyromorphites is Pb₅(PO₄)₃Cl > Pb₅(PO₄)₃Br > Pb₅(PO₄)₃OH > Pb₅(PO₄)₃F. The derived free energy data have been used to evaluate the respective stabilities of fluoro-pyromorphite and bromopyromorphite within the systems PbF₂-PbO-P₂O₅-H₂O and PbBr₂-PbO-P₂O₅-H₂O and to predict the equilibrium behavior of the Pb₅(PO₄)₃F-Pb₅(PO₄)₃OH solid solution under aqueous conditions.     

Effect of chelation on toxicity of copper

Metals in the sea may form complexes with organic compounds, a process known as chelation, and this may modify their properties very greatly. Here the effect of chelation on the toxicity of copper to algae has been studied in the laboratory using the powerful chelating agent EDTA. Similar phenomena in the sea have implications both for anti-fouling paints, which usually contain copper, and for metal pollution in waters with a high organic content.     

Mineral resource appraisal and mineral deposits computer files in the Geological Survey of Canada

The Geological Survey of Canada (G.S.C.) has been involved in national appraisal of resources of certain commodities for nearly two decades beginning with a national study of iron deposits in 1955. In 1972, the first national appraisal to rapidly estimate total resources of Cu, Pb, Zn, Ni, Fe, Mo, and U in Canada was carried out largely by economic geologists. This exercise produced, among other things, a better definition of G.S. C. needs for building computer files in support of mineral deposits studies and mineral resource appraisal. Objectives of this paper are threefold: (1) to outline general methodology for the kind of mineral resource appraisal carried out by the G.S.C. in 1972; (2) to identify types of information required in that appraisal; and (3) to indicate types of information on mineral deposits for which it seems advantageous for the G.S.C. to construct computer files, and how these files relate to mineral resource appraisal. Methodology is fairly straightforward for appraisal of reserves (known, measured resources), but is much more problematic for appraisal of undiscovered resources. For the latter, G.S.C. economic geologists make use of two basic concepts: the deposit model, which is a generalized deposit type, distinguished by its geological attributes and host rock environment, and containing characteristic amounts of specified commodities; and the metallogenic region, which is a geographic area of more or less homogeneous geology deemed favorable for the presence of a particular deposit model. Background information required for appraisal of undiscovered resources includes the following: (a) data on distribution and geology of Canadian deposits and occurrences; (6) data on geology of important, foreign deposits; (c) knowledge of Canadian geology, commensurate with metallogenic requirements; (d) knowledge of current theories of ore-forming processes; and (e) appreciation of the amount, location, and effectiveness of past exploration in Canada. At present, only identity, location, and certain simple geological features of Canadian deposits are considered practical for a general computer file of mineral deposits. The fundamental activity of the G.S.C. in the sphere of mineral deposits is a number of broad studies on the geology of certain commodities in Canada carried out by economic geologists. Appraisal of mineral resources is based directly on the results of those studies, and is done by the same economic geologists. Construction of G.S.C. computer files is in response to needs defined by economic geologists, mainly in the context of their broad studies.This paper was presented at the International Geological Correlation Program (IGCP) Project 98 entitled Standards for Computer Applications in Resource Studies held at Loen, Norway, September 27–October 1, 1976.     

The Structural geology of the Troms Area (Barents-Sea)

This paper reviews the exploration history of the Barents Sea part of the Norwegian continental shelf. The main structural elements which so far have been identified in the Troms/Finnmark/Barents Sea region are outlined and discussed. Special attention is given to the selected Area I outside Troms, where according to latest government plans, drilling will start in 1978.At least two different fault systems are discribed in Area I. The salt diapirs in the Tromsø Basin and their location relative to the fault pattern are discussed. A schematic structural model for Area I is suggested.     

Oxygen exchange between a ‘model’ pond and the atmosphere

Oxygen exchange between a sheltered ‘model’ farm pond (6 m diameter and 2.5 m deep) and the atmosphere averaged 0.33 m/day for measurements made from April to December. This value was similar to those reported for isolated surfaces in sheltered waters and in laboratory tanks but below those of large, inland waters. Low average wind velocity (0.7 m/sec) probably caused the low O₂ exchange rate. Interactions between air and water temperatures and precipitation may be important factors governing short-term O₂ exchange in highly sheltered waters.