赤峰撰山子花岗岩年代学、地球化学特征及其成岩动力学背景

撰山子角闪二长花岗岩位于华北克拉通与兴蒙造山带结合部位的中生代构造岩浆活动带,对其开展了主量元素、稀土和微量元素分析以及LA-ICP-MS锆石U-Pb定年等工作,目的在于精确厘定岩体的形成时代和研究其形成的动力学背景。结果表明：花岗岩的LA-ICP-MS锆石U-Pb谐和年龄为（245.8±3.1）Ma（MSWD=3.7,n=17）,属早三叠世。岩石地球化学成分特征显示为,其具有高硅（w（SiO₂）=71.68%~72.85%）、富碱（w（Na₂O+K₂O）=8.98%~9.20%）、高铝（w（Al₂O₃）=13.45%~13.77%）、低钙（w（CaO）=0.81%~0.99%）及低TFeO/MgO值（平均值为6.55）的特征,属高钾钙碱性、高分异I型弱铝质花岗岩;稀土配分曲线呈现向右倾斜的配分模式,Eu具有明显的亏损（δEu=0.66~0.68）,表明斜长石发生了明显的分离结晶作用;在微量元素原始地幔标准化图谱上呈现清晰的Th、U、La、P富集,Ba、Nb、Ti、Sr、Ta等相对亏损的特征。综合分析认为,撰山子角闪二长花岗岩主要形成于下地壳部分熔融作用,可能有少量的地幔组分加入,其形成于华北板块和西伯利亚板块最终拼合后的后碰撞/后造山伸展作用构造环境。     

Sorption behaviour of pentachlorophenol in sub-Saharan tropical soils: soil types sorption dynamics

In order to predict exposure risks as well as appropriate remediation strategies for pesticides in soils, knowledge of pesticides sorption processes onto various representative soils is vital. Hence, laboratory batch experiments were carried out to study sorption of a pesticide, pentachlorophenol (PCP), on five soils obtained from different sub-Saharan agro-ecological zones (AEZs) in order to understand sorption equilibrium, kinetics, and thermodynamics. Experimental data showed that sorption equilibrium was attained within 24 h. The fitting of kinetic results and equilibrium data to different models suggested partly surface adsorption and partly partitioning of PCP within voids of the various soil components. Sorption was mainly attributed to sharing or exchange of valence electrons between negatively charged PCP molecules and positively charged soil sorption sites. The sorption process was spontaneous and accompanied by decreased entropy, but was pH and temperature dependent, reducing with increase in pH and temperature. The various soils’ PCP sorption capacities were directly proportional to their cation exchange capacities. The low PCP sorption observed in these soils suggested high risk of PCP being present in soil water solution, especially at higher temperatures, which can lead to contamination of the aquifer. This risk may be higher for soils obtained from AEZs with warmer natural temperatures.     

Formation of the adakite-like granitoid complex and porphyry copper-gold deposit in Shaxi from southern Tancheng-Lujiang fault belt： A clue to the West Pacific plate subduction

On the basis of the geological and geochemical studies, including chemical analysis of bulk rocks, rare-earth and trace element studies, fluid inclusion, and S and O isotopic analyses, the authors described the geo-logical background of the deposit in detail and presented significant proofs for the conditions of formation of the Shaxi porphyry copper-gold deposit. Compared with other large and supper-large porphyry copper deposits in China and the adjacent Cu-Au mineralized areas, the ore-forming processes and conditions were analyzed; and the possibil-ity of forming large porphyry copper deposits in the Shaxi area was discussed. The present study indicated that the ore-forming fluid and material were mainly of magmatic origin, while meteoric water played a certain role in the ore-forming processes. Interactions between subducting and overriding plates provided a major driving force for the formation of igneous rocks and the deposition of metal elements in East China since Jurassic. Based on the geo-chemical data of the Shaxi intrusive, it is found that the copper (gold) mineralization is closely related to the genesis of adakite-like intrusive in the Shaxi area. This adakite-like intrusive was formed in the subduction environment as a result of the subduction of the West Pacific plate toward the East China continent, where there is a great potential-ity to form a large porphyry copper deposit.     

焉耆盆地侏罗系低渗透储层敏感性评价

焉耆盆地侏罗系具近物源沉积特点，储层成分成熟度和结构成熟度均较低，粘土矿物含量高，物性较差，属低渗透储层。“五敏”实验结果表明，储层均表现为强水敏特征，物性相对较好的储层还表现出强盐敏和中等偏弱速敏、碱敏等敏感性特征，盐酸对储层具有一定程度的改善，并进一步探讨钻探施工过程中油层保护的措施及应用效果。     

皖南休宁地区恐龙脚印等化石的产出特征

皖南休宁地区发现“三位一体”的恐龙骨骼化石、恐龙蛋化石、恐龙足迹和尾迹化石。本文着重描述这批化石的形态大小和结构特点，并从古生态学方面对化石进行了探讨分析；按化石产出层位，对应的各类恐龙活动时间总计约为40Ma。     

Continuous zircon growth during long-lived granulite facies metamorphism: a microtextural,U–Pb,Lu–Hf and trace element study of Caledonian rocks from the Arctic

Microtextural, U–Pb, trace element and Lu–Hf analyses of zircons from gneisses dredged from the Chukchi Borderland indicate a long-lived, Cambrian–Ordovician, granulite facies metamorphism. These results reveal a complete prograde, peak and cooling history of zircon growth during anatexis. Early increasing temperatures caused modification and Pb-loss of Precambrian zircons by recrystallization and dissolution/re-precipitation of existing grains. Small variations in initial ¹⁷⁶Hf/¹⁷⁷Hf results (0.282325–0.282042) and flat HREE patterns of these zircons indicate that they grew by dissolution/re-precipitation in the presence of garnet. Zircons subsequently crystallized from a partial melt during peak to post-peak metamorphism from 530 to 485 Ma. A broad range of initial ¹⁷⁶Hf/¹⁷⁷Hf ratios (0.282693–0.282050) and mineral inclusions within zircons suggest that this phase of growth incorporated Zr and Hf obtained from the breakdown of Zr-enriched phases. Microtextural evidence along with trace element and isotopic data suggests that final growth of metamorphic rims on zircon occurred during slow cooling and crystallization of residual partial melts during the early Ordovician (485–470 Ma). Younger, late Ordovician–Silurian (420–450 Ma) euhedral, oscillatory-zoned, trace element-enriched zircons crystallized within leucocratic veins that intrude the gneisses. Their age corresponds to granitoids dated from this same dredge. The intrusives and veins provide evidence that the Chukchi Borderland rifted from a position near Pearya and northwest Svalbard, which represent the northern continuation of the Caledonian orogen. Evidence for earlier Cambrian metamorphism has not been reported from this region. The age of granulite facies metamorphism reported here represents the earliest phase of deformation in the Arctic Caledonides.     

Geochemistry and Nd,Sr isotopes of the Pohrenk fluorites (Kırsehir-Turkey)

The Pohrenk fluorite mineralisation which makes up Central Anatolia’s most extensive fluorite region is Lutetian aged, and hosted in carbonate rocks that have undergone occasional karstification and silicification along a N–S fault trend. Fluid inclusion values and the position of fluorites in the Tb/La–Tb/Ca diagram show that mineralisation occurred in a hydrothermal environment with homogenisation temperatures ranging from 78.1–363°C. The presence of fluorite as a space filler in carbonate rocks and its association with silicification indicates that the solutions contained considerable amounts of Si alongside F (fluorine). The Pohrenk fluorite samples have ¹⁴³Nd/¹⁴⁴Nd values of between 0.512349 and 0.512497, whilst ⁸⁷Sr/⁸⁶Sr values vary between 0.708161 and 0.708772. These values indicate a mantle origin where continental contamination could occur. When the Nd–Sr values are compared to magmatic and young volcanics, the Pohrenk fluorites are seen to be enriched and exhibit similar isotopic signatures to Upper Cretaceous aged magmatics, Early-Middle Miocene volcanics and Mio-Quaternary volcanics.     

李坝式金矿床成矿作用及矿床类型探讨

李坝式金矿床成矿作用过程分为成矿元素初始富集期和构造叠加热液改造成矿期，岩浆活动主号是通过改变矿床地质体物化条件而促进矿化体的形成，并有部分岩浆物质参与成矿。该矿床与国内外经典卡林型金矿床具有较大的可比性，但是由于缺乏低温矿物组合以及与岩浆活动的亲密性证据，该矿床应属广义上的卡林型金矿床。     

花岗岩的成岩时代、地球化学特征和成因青海祁漫塔格地区虎头崖矿床Ⅵ矿带

利用 LA ICP MS 锆石 U Pb 法,测得与成矿有关的青海祁漫塔格地区虎头崖矿床Ⅵ矿带花岗岩的成岩年龄为(233.6±1.8)Ma(MSWD=1.2,n=17)。地球化学特征显示：花岗岩属高钾钙碱性、弱过铝质花岗岩;样品的稀土元素组成以总体右倾,轻、重稀土分异明显和具明显的负铕异常为特征;微量元素具有富集 Rb、Th、U、La、Nd 等大离子亲石元素,亏损 Ba、Sr、Nb、P、Ti 等元素的特点。Sr Nd 同位素组成特征显示,花岗岩的源区可能是富集岩石圈地幔。初步研究认为,虎头崖矿床Ⅵ矿带花岗岩可能形成于中、晚三叠世碰撞后碰撞的构造背景下。     

地震勘探频率中近抛物线型衰减的物理解释

几十年来,人们对地震波在真实介质中传播发生的衰减进行了理论与实践两方面研究。文中综述了前人工作,包括机制与测试工作,同时给以评论,指出对于传播距离与频率之间关系研究不够,并且对实测结果作物理解释较少。作者用VSP技术进行了不同距离上衰减与频率之间关系的研究,提出了反射补偿的具体方法,采用了多项式拟合技术,得到了近抛物线型衰减的结果。然后,利用波前压力与振动的固有频率思想对测试结果进行了讨论,得出一些有益的结论。