Thermodynamics of feldspathoid solutions

We have developed models for the thermody-namic properties of nephelines, kalsilites, and leucites in the simple system NaAlSiO₄?KAlSiO₄?Ca_0.5AlSiO₄?SiO₂?H₂O that are consistent with all known constraints on subsolidus equilibria and thermodynamic properties, and have integrated them into the existing MELTS software package. The model for nepheline is formulated for the simplifying assumptions that (1) a molecular mixing-type approximation describes changes in the configurational entropy associated with the coupled exchange substitutions □Si?NaAl and □Ca? Na₂ and that (2) Na⁺ and K⁺ display long–range non-convergent ordering between a large cation and the three small cation sites in the Na₄Al₄Si₄O₁₆ formula unit. Notable features of the model include the prediction that the mineral tetrakalsilite (“panunzite”, sensu stricto) results from anti-ordering of Na and K between the large cation and the three small cation sites in the nepheline structure at high temperatures, an average dT/dP slope of about 55^°/kbar for the reaction over the temperature and pressure ranges 800–1050 ^°C and 500–5000 bars, roughly symmetric (i.e. quadratic) solution behavior of the K–Na substitution along joins between fully ordered components in nepheline, and large positive Gibbs energies for the nepheline reciprocal reactions and and for the leucite reciprocal reaction      

Mineral chemistry constraints on the evolution of the 1.88–1.87 Ga post-kinematic granite plutons in the Central Finland Granitoid Complex

A suite of post-kinematic, 1.88–1.87 Ga, silicic plutons crosscut 1.89–1.88 Ga synkinematic granitoids in the Central Finland Granitoid Complex (CFGC) in south-central Finland. The plutons range from biotite±hornblende quartz monzonite to syenogranite and include pyroxene- and olivine-bearing varieties. Mineral chemical data on feldspars, biotite, amphibole, pyroxenes, olivine, and oxides of the post-kinematic plutons are presented. The data are interpreted to show that these plutons register (1) a considerable range in pressure from 2–4 kbar (amphibole barometry) to 5–7 kbar (olivine–pyroxene barometry), (2) temperatures mostly reflecting resetting during cooling (450–800°C; QUIlF thermometry), and (3) low fO₂ (log fO₂ ΔFMQ −0.3 to −1.5; QUIlF equilibria). In particular, plutons with olivine- and pyroxene-bearing margins and amphibole-dominated central parts record progressive oxidation and hydration upon cooling, shifting from the QUIlF equilibrium toward KUIlB. The post-kinematic granites can be considered post-collisional in regard to compressional events in the CFGC and display many of the characteristics of the anorogenic 1.6 Ga rapakivi granites further south. They were presumably derived from a deep and dry crustal source, like the rapakivi granites.     

A thin orogenic wedge upon thick foreland lithosphere and the missing foreland basin

Along the Caledonian front in central Scandinavia, the expected peripheral or pro-foreland basin is neither physically present nor are there any significant traces in the sedimentary record. In order to explain and quantify this situation, the authors assess the major geometric and mechanical constraints on the Caledonian orogenic wedge and model the orogenic load and its influence on the foreland lithosphere of Baltica. Geologic and geophysical data show a strong foreland lithosphere with a flexural parameter (α) of approximately 100 km. The shape of the orogenic wedge and its critical taper angle are dependent mainly on basal friction and wedge strength. In the external part organic-rich black shales provide a low-friction horizon both at the basal detachment surface and within the wedge itself. The more internal part of the wedge is composed of metamorphic and crystalline rocks, which cooled and strengthened prior to thrusting. As a result, the external part of the wedge had a lower strength and a smaller critical taper angle than its internal part, so the orogenic load is upward concave. Modelling of the effect of such a load on the Baltica lithosphere shows a very small depression in front of the load (2 km). The flexural depression produced by the main part of the orogenic load is filled up by the thickening thrust-and-fold belt, so that there is little space left for a foreland basin. These results imply that the missing foreland basin in front of the central Scandinavian Caledonides is not due to subsequent erosion, but is a primary feature.     

The Rio Sassito sedimentary succession (Ordovician): a pinpoint in the geodynamic evolution of the Argentine Precordillera

In the Precordillera of western Argentina, an isolated outcrop of Llandeilian siliciclastics and Caradocian limestones (Rio Sassito succession) reveals a complex interplay between the tectonic and the sedimentary history of the Precordillera during Middle and Late Ordovician times. The succession is composed of a lower siliciclastic interval and an upper carbonate interval and is bounded below and above by erosional unconformities. Dating of these unconformities, which in many places merged to form one single surface, demonstrates that the most important erosional event took place prior to the deposition of the Rio Sassito succession. This erosional event is correlated to extensional tectonics during continental breakup and the separation of the Precordillera from Laurentia. Block faulting with the formation of horst and graben structures provided the topography for the establishment of a pelagic carbonate platform during the Caradoc. In our view, there are no indications that these phenomena are related to the accretion of the Precordillera to Gondwana or to the formation of an Ordovician supercontinent. The carbonate sediments are typical of temperate-water settings, characterized by the absence of ooids, oncoids, and algae, and by the presence of abundant abraded bioclasts, intraclasts, and peloids. The inference of a temperate-water environment does not, as previously supposed, indicate the accretion of the Precordillera to Gondwana, but is more likely related to global cooling prior to the Ashgillian glaciation.     

Geology of the Bozdag area, central Menderes massif, SW Turkey: Pan-African basement and Alpine deformation

The Menderes massif consists of a Precambrian Core Series that preserves evidence for a polymetamorphic history and a Paleozoic/Mesozoic Cover Series that experienced only the Alpine tectonometamorphic evolution. Structural, petrographic, and geochronologic investigations in the central Menderes massif demonstrate that (a) part of the metamorphic and structural evolution of the Precambrian basement is older than the undeformed 551±1.4-Ma-old Birgi metagranite, and (b) inferred Alpine fabrics overprinting the Cover Series largely have the same attitudes as the old structures in the much older Core Series. The inferred Alpine fabrics include both contractional and extensional structures. Contraction under greenschist to amphibolite facies conditions resulted in the imbrication of the Core and Cover Series and generated an inverted metamorphic sequence by north-directed thrusting. During Alpine extension, most of the south-dipping thrust faults were reactivated as extensional shear zones under decreasing greenschist facies conditions.     

The metamorphosed mafic-ultramafic complex of Mokuro, Ilesha Schist Belt, southwestern Nigeria

In the Proterozoic Schist Belt of Nigeria, lenticular bodies of metabasites and meta-ultramafics are frequently intercalated within staurolite bearing metapelitic schists. Such a metamorphosed mafic-ultramafic complex is particularly well exposed in the Mokuro riverbed between the towns of Ife and Ilesha. These outcrops display contact relationships with the surrounding metasediments, as well as between the individual mafic and ultramafic rock types. The most common mafic rocks are indistinctly layered amphibolites, accompanied by apatite rich amphibolites and massive amphibolites, in part rich in ilmenite and pyrrhotite. Among the generally massive ultramafic rocks, nearly monomineralic amphibole rocks predominate, while chlorite-amphibole, talc-chlorite-amphibole and talc bearing olivine-chlorite-amphibole rocks occur in subordinate amounts.Field, textural and geochemical evidence suggest that the mafic-ultramafic complex derived from a thick, structurally differentiated basaltic sill that contained doleritic portions in its interior. Slow cooling rates in these inner parts enabled crystal settling with the formation of ultramafic cumulates. Due to the enrichment of volatiles during the crystallisation process, higher amounts of apatite and sulphides, as well as late magmatic amphibole, were formed in parts of the mafic-ultramafic body.Mineral assemblages in the mafic-ultramafic complex testify to a metamorphic overprint under amphibolite-facies conditions. Thermodynamic modelling in the system CMFASH leads to an estimated P–T range of 1.5–3 kbar and 550–620°C for the metamorphic peak assemblage talc-olivine-chlorite-Ca amphibole-orthoamphibole.     

Relationship between waterfowl and the seagrassRuppia maritima in a Southwestern Atlantic coastal lagoon

We evaluated the distribution of waterfowl in relation to a seagrass (Ruppia maritima) patch, to infauna, and on its relationship with substrate characteristics. An experiment performed in the Mar Chiquita coastal lagoon (37°46′S, 57°27′W; Argentina) was used to evaluate the effect of herbivory on widgeon grass,R. maritima. Control plots of equal size, located between bird exclosures, were exposed to herbivory. The experiment ran for 31 d, starting on December 1, 1994. Censuses showed that black-necked swan ( $\bar x = 50$ birds ha^?1, SD = 37, n = 10) and coots ( $\bar x = 42$ birds ha^?1, SD = 28, n = 10) were the most important (always present) of the waterfowl seen feeding onR. maritima. The results of the experiment showed greater leaf lengths, lower belowground (rhizomes and roots) biomass, greater aboveground (leaves and shoots) biomass, and greater abundance of the polychaeteHeteromastus similis in exclosure plots. There were no exclosure effects on total biomass (belowground plus aboveground), reproductive parts (fruits and pre- and postpollination flowers), or abundance of most benthic infauna. Topographic surveys showed that sediment surface was higher within theR. maritima patches, but there were no significant differences in granulometric composition. Surveys also showed that bird distribution was strongly associated with the presence ofR. maritima.     

遥感技术在南盘江地区油气烃类检测中的应用

应用陆地卫星 TM 资料对南盘江地区进行了烃类微渗漏蚀变信息检测研究。岩石土壤地球化学特征分析表明,该区不同程度地存在着“褪红”、“粘土矿化”、“碳酸盐矿化”等烃类蚀变异常现象。选择 FeO/Fe_2O_3作为褪红的成分因子;(K_2O+Na_2O+Al_2O_3)、(K_2O+Na_2O)/Al_2O_3、(K_2O+Na_2O+Al_2O_3)/S∶O_2和 K_2O/Na_2O 等作为粘土矿化的成分因子;CaO+MgO 和 CaO/MgO 作为碳酸盐矿化的成分因子。利用 TM1/TM3、TM1/TM4识别褪红蚀变信息,TM5/TM7、TM5/TM4用干识别粘土矿化和碳酸盐矿化蚀变信息。建立了地球化学—光谱—遥感图像三位一体的遥感找油气模式,根据油气遥感色调异常对南盘江地区进行了评价和分类。     

Spectroscopic Survey of δ Sct Stars

The methods used to derive effective temperatures, projected rotational velocities and surface gravities of a sample of low and high-amplitude δ Sct stars are presented here. Effective temperatures were derived using Hα and Hβ line profiles whereas rotational velocities were calculated following the method described in Solano & Fernley (1997). Surface gravities were obtained using Hipparcos parallaxes and evolutionary models (Claret 1995). The results of this analysis will be published in a subsequent paper (Solano & Pintado 1999). This revised version was published online in July 2006 with corrections to the Cover Date.     

Modulation and symmetry changes in stellar dynamos

Stellar dynamos are governed by non-linear partial differential equations (PDEs) which admit solutions with dipole, quadrupole or mixed symmetry (i.e. with different parities). These PDEs possess periodic solutions that describe magnetic cycles, and numerical studies reveal two different types of modulation. For modulations of Type 1 there are parity changes without significant changes of amplitude, while for Type 2 there are amplitude changes without significant changes in parity. In stars like the Sun, cyclic magnetic activity is interrupted by grand minima that correspond to Type 2 modulation. Although the Sun's magnetic field has maintained dipole symmetry for almost 300 yr, there was a significant parity change at the end of the Maunder Minimum. We infer that the solar field may have flipped from dipole to quadrupole polarity (and back) after deep minima in the past and may do so again in the future. Other stars, with different masses or rotation rates, may exhibit cyclic activity with dipole, quadrupole or mixed parity. The origins of such behaviour can be understood by relating the PDE results to solutions of appropriate low-order systems of ordinary differential equations (ODEs). Type 1 modulation is reproduced in a fourth-order system while Type 2 modulation occurs in a third-order system. Here we construct a new sixth-order system that describes both types of modulation and clarifies the interactions between symmetry-breaking and modulation of activity. Solutions of these non-linear ODEs reproduce the qualitative behaviour found for the PDEs, including flipping of polarity after a prolonged grand minimum. Thus we can be confident that these patterns of behaviour are robust, and will apply to stars that are similar to the Sun.