LA-ICP-MS heavy metal analyses of fish scales from sediments of the Oxbow Lake Certak of the Morava River (Czech Republic)

Heavy metal concentrations were studied in the scales of recent and subrecent (2–25 years old) fish buried in the oxbow lake sediments of the Morava River. The samples were taken from two cores up to 4-m deep and analysed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and an electron microprobe analysis (EMPA). The results were compared with heavy metal concentrations of bulk samples of the embedding sediment. The study has revealed substantial differences in heavy metal contents existing between the recent and subrecent fish scales documenting an extreme rapidity of the diagenesis/fossilization processes. The most apparent features of the early fossilization include the quick loss of the mucous envelope, collagen and magnesium and an enormous increase in the heavy metal concentrations in particular iron, which is connected with a colour change. The variations in heavy metal contents in fish scales within a sample are attributed to variations in heavy metal content in the environment and variable amounts of organic matter in the embedding sediment. In contrast to the contamination of the embedding sediment, no general increase in heavy metal concentrations in fish scales was observed down to the cores. It is inferred that the rapid sorption stabilizes the biologic hydroxyapatite of the fish scales, which thus rapidly attain a thermodynamic equilibrium with the embedding water-saturated sediment. The results show that the processes of sorption, fossilization and stabilization of hydroxyapatite can act very quickly over a time scale of several years and represent thus a great advantage in the preservation of the original signals of the ancient environments.     

Modeling microclimate environments: A verification study

A numerical model is developed for simulating microclimate of plants and bare soil. The model evaluates heat, mass, momentum, and radiative fluxes in the soil-plant-atmosphere system. Its vertical domain may extend throughout the whole Planetary Boundary Layer (PBL). The model requires, either, temporal meteorological data of solar radiation, wind speed, air temperature and humidity measured over the field, or, when applied to the whole PBL, initial values of the latter three at its top. Vegetation parameters (leaf area index, photometric properties, root distribution and density) as well as soil texture, hydraulic and photometric properties are considered. The model was verified with meteorological data taken from two different climatological regions, above a bare soil and two cotton fields.For all case studies, observed and calculated values of air (except for within-canopy) and soil temperatures, wind speed, net radiation, and soil-, latent-, and sensible heat fluxes, agreed well with measurements.     

The rapid variability of blazars at optical wavelengths

We monitored five active galactic nuclei in the R optical band with a CCD mounted on the 1-m Zeiss-1000 telescope of the Special Astrophysical Observatory from April 2001 to August 2003. Three sources displayed intraday variability on several nights. Stronger variability was detected on time scales from two days to a week. The two-year light curves are presented for four of the observed objects.     

Variations in the near-ground electric field at high latitudes and the potential drop across the polar cap during morning polar substorms

This paper studies time variations in the near-ground atmospheric electric field (Ez) at the geomagnetic latitude of 74° (Hornsund observatory) during polar substorms. Ez variations are compared with those in the potential drop across the polar cap (Up), according to SuperDARN radar observations. It is found that in the morning sector, time variations in Ez are strongly driven by time variations in the electrojet and almost do not depend on time variations in Up, which is presumably due to the penetration of the electric field of the electrojet into tropospheric altitudes.     

Developing coastal adaptation to climate change in the New York City infrastructure-shed: process, approach, tools, and strategies

While current rates of sea level rise and associated coastal flooding in the New York City region appear to be manageable by stakeholders responsible for communications, energy, transportation, and water infrastructure, projections for sea level rise and associated flooding in the future, especially those associated with rapid icemelt of the Greenland and West Antarctic Icesheets, may be outside the range of current capacity because extreme events might cause flooding beyond today??s planning and preparedness regimes. This paper describes the comprehensive process, approach, and tools for adaptation developed by the New York City Panel on Climate Change (NPCC) in conjunction with the region??s stakeholders who manage its critical infrastructure, much of which lies near the coast. It presents the adaptation framework and the sea-level rise and storm projections related to coastal risks developed through the stakeholder process. Climate change adaptation planning in New York City is characterized by a multi-jurisdictional stakeholder?Cscientist process, state-of-the-art scientific projections and mapping, and development of adaptation strategies based on a risk-management approach.     

Surface water quality evaluation in Odukpani, Calabar Flank, south-eastern Nigeria

 The present article is the second in a series of baseline water quality evaluation studies in parts of south-eastern Nigeria. Study results indicate that the water samples from the study are generally acidic, soft and fresh in addition to low sodium and salinity hazard. Regression equations indicate a good positive correlation between conductivity and Na, Ca, Mg and SO₄. Ca-SO₄ and Ca-Cl constitute the major facies in the area. Generally the waters in the area are good for most domestic and agricultural purposes. Received: 14 April 1997 · Accepted: 3 February 1998     

Geomagnetic Storm Effects at <Emphasis Type="Italic">F</Emphasis>1 Layer Altitudes in Various Periods of Solar Activity (Irkutsk Station)

The influence of geomagnetic disturbances on electron density Ne at F1 layer altitudes in different conditions of solar activity during the autumnal and vernal seasons of 2003–2015, according to the data from the Irkutsk digital ionospheric station (52° N, 104° Е) is examined. Variations of Ne at heights of 150–190 km during the periods of twenty medium-scale and strong geomagnetic storms have been analyzed. At these specified heights, a vernal–autumn asymmetry of geomagnetic storm effects is discovered in all periods of solar activity of 2003–2015: a considerable Ne decrease at a height of 190 km and a weaker effect at lower levels during the autumnal storms. During vernal storms, no significant Ne decrease as compared with quiet conditions was registered over the entire analyzed interval of 150?190 km.     

Continuous zircon growth during long-lived granulite facies metamorphism: a microtextural,U–Pb,Lu–Hf and trace element study of Caledonian rocks from the Arctic

Microtextural, U–Pb, trace element and Lu–Hf analyses of zircons from gneisses dredged from the Chukchi Borderland indicate a long-lived, Cambrian–Ordovician, granulite facies metamorphism. These results reveal a complete prograde, peak and cooling history of zircon growth during anatexis. Early increasing temperatures caused modification and Pb-loss of Precambrian zircons by recrystallization and dissolution/re-precipitation of existing grains. Small variations in initial ¹⁷⁶Hf/¹⁷⁷Hf results (0.282325–0.282042) and flat HREE patterns of these zircons indicate that they grew by dissolution/re-precipitation in the presence of garnet. Zircons subsequently crystallized from a partial melt during peak to post-peak metamorphism from 530 to 485 Ma. A broad range of initial ¹⁷⁶Hf/¹⁷⁷Hf ratios (0.282693–0.282050) and mineral inclusions within zircons suggest that this phase of growth incorporated Zr and Hf obtained from the breakdown of Zr-enriched phases. Microtextural evidence along with trace element and isotopic data suggests that final growth of metamorphic rims on zircon occurred during slow cooling and crystallization of residual partial melts during the early Ordovician (485–470 Ma). Younger, late Ordovician–Silurian (420–450 Ma) euhedral, oscillatory-zoned, trace element-enriched zircons crystallized within leucocratic veins that intrude the gneisses. Their age corresponds to granitoids dated from this same dredge. The intrusives and veins provide evidence that the Chukchi Borderland rifted from a position near Pearya and northwest Svalbard, which represent the northern continuation of the Caledonian orogen. Evidence for earlier Cambrian metamorphism has not been reported from this region. The age of granulite facies metamorphism reported here represents the earliest phase of deformation in the Arctic Caledonides.     

Über die Mischungsarbeit von stabil geschichteten Wassermassen

Zusammenfassung Es wird gezeigt, daß — entgegen der bisherigen Ansicht — die Mischungsarbeit von verschieden temperierten Wassermassen nicht unbegrenzt mit der Größe des Temperaturunterschiedes der Wassermassen anwächst, sondern daß sie für einen bestimmten Temperaturunterschied (bzw. bestimmten Temperaturgradienten) ein Maximum erreicht, für größere Temperaturunterschiede aber wieder auf wesentlich kleinere Beträge abnimmt.

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Summary It is shown that — in contradiction to the hitherto existing view — the energy resulting from the mixture of water-masses with different temperatures does not increase infinitely with the value of the temperature-difference of the water-masses, but that it reaches a maximum for a determined temperature-difference (respectively a determined temperature lapse rate), whereas it decreases to much smaller amounts for greater temperature-differences.

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Résumé On montre que, contrairement aux vues admises jusqu'ici, l'énergie résultant du mélange de masses d'eau à températures différentes ne croît pas sans limite avec l'écart de température, mais qu'elle atteint un maximum pour un écart déterminé (ou pour un gradient de température déterminé) et décroît de nouveau notablement pour des écarts plus grands.

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