Spatial distribution patterns and temporal trends of heavy-metal concentrations in a petroleum hydrocarbon-contaminated site: Karaduvar coastal aquifer (Mersin, SE Turkey)

The aim of this study was to investigate spatiotemporal variations in groundwater heavy-metal concentrations at the Karaduvar agricultural-industrial district (Mersin, SE Turkey), where parts of the underlying coastal aquifer has been polluted by petroleum hydrocarbons (PHCs) from diverse sources. The water chemistry data for the present study is comprised of 275 samples collected during 2006–2010 from 55 water-supply wells. The samples were analyzed in situ for physical parameters (EC, DO, pH, and temperature) and in the laboratory for As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn using the ICP-MS method. Box–whisker plots and principal components analysis (PCA) method were employed to determine the seasonal changes occurring in heavy-metal concentrations and to identify source apportionment of pollution parameters in groundwater. During the monitoring period, in many wells, heavy-metal concentrations (except for Cd) exceeded the limit values set by Turkish Water Pollution Control Directive (No: 25687). Results from the PCA suggest that elevated Mn, Fe, Co, Ni and As concentrations may be linked to oxidation–reduction of geogenic Mn/Fe oxyhydroxides in PHC-contaminated parts. The high concentrations of Cu, Mo and probably Cd in background areas result from the agricultural and petrochemical activities conducted in the recent past. At the site, high Pb and Zn concentrations are probably related to agricultural activities in PHC-contaminated areas, whereas Cr can be solely attributed to lithogenic sources. At the Karaduvar site, heavy-metal pollution in groundwater is found to be much more persistent than PHC contamination.     

Development of an earthquake loss model for Turkish catastrophe insurance

Following the devastating Kocaeli and Düzce earthquakes of August andNovember 1999, the Turkish Government was faced with an enormousfinancial burden as a result of its statutory obligation to cover the full costsof rebuilding. In order to offset this liability in the future – which has hadan adverse effect on the Government's economic programme – acompulsory earthquake insurance scheme has been introduced for allhouseholders in Turkey. A key element for successful implementation ofthis novel and ambitious programme is the transfer of the earthquake riskabsorbed by the Turkish Catastrophe Insurance Pool (TCIP) to theinternational reinsurance market. An earthquake loss model, described inthis paper, has been developed for the TCIP to serve as a basis for thedecision-making process with respect to the pricing of its insurance policy,risk control, the purchase of reinsurance, and the transfer of seismic risk.Sample results of the loss calculations are presented.     

Development of a GIS-based monitoring and management system for underground coal mining safety

Coal mine safety is of paramount concern to mining industry. Mine accidents have various causes and consequences including catastrophic failure of mine, substantial economic losses and most notably loss of lives. Therefore, any initiative in mine monitoring is of vital importance for progressing safety surveillance and maintenance.This paper presents the development of a geographic information system (GIS)-based monitoring and management system for underground mine safety in three levels as constructive safety, surveillance and maintenance, and emergency. The developed model integrates the database design and management to the monitoring system implementation which encompasses query and analysis operations with the help of web and desktop applications. Interactive object-oriented graphical user interfaces (GUIs) were developed to visualize information about the entities gathered from the model and also to provide analysis operations based on the graphical representations and demonstrations using data tables and map objects.The research methodology essentially encompasses five main stages: (i) designing a conceptual database model; (ii) development of a logical model in terms of entity-relationship (ER) diagrams; (iii) development of a physical model based on physical constraints and requirements; (iv) development of GUIs and implementation of the developed model, analysis and queries; (v) verification and validation of the created model for Ömerler underground coal mine in Turkey. The proposed system is expected to be an efficient tool for improving and maintaining healthy standards in underground coal mines which can possibly be extended to a national GIS infrastructure.     

The genesis of the carbonatized and silicified ultramafics known as listvenites: a case study from the Mihalıççık region (Eskişehir), NW Turkey

The Mihalıççık region (Eskişehir) in NW Turkey includes an ophiolitic assemblage with a serpentinite‐matrix mélange. The serpentinites of this mélange host silica‐carbonate metasomatites which were previously named as listvenites. Our mineralogical and geochemical studies revealed that these alteration assemblages represent members of the listvenitic series, mainly the carbonate rocks, silica‐carbonate rocks and birbirites, rather than true listvenites (sensu stricto). Tectonic activity and lithology are principal factors that control the formation of these assemblages. Carbonatization and silicification of the serpentinite host‐rock is generated by CO₂, SiO₂‐rich H₂O hydrothermal fluid which includes As, Ba, Sb and Sr. Low precious metal (Au, Ag) contents of the alteration assemblages indicate lack of these metals in the fluid. Primary assemblages of the alteration are carbonate rocks that are followed by silica‐carbonate rocks and birbirites, respectively. Petrographic studies and chemical analyses suggested an alkaline and moderate to high temperature (350–400°C) fluid with low oxygen and sulphur fugacity for the carbonatization of the serpentinites. The low temperature phases observed in the subsequent silicification indicated that the fluid cooled during progressive alteration. The increasing Fe‐oxide content and sulphur phases also suggested increasing oxygen and sulphur fugacity during this secondary process and silica‐carbonate rock formation. The occurrence of birbirites is considered as a result of reactivation of tectonic features. These rocks are classified in two sub‐groups; the Group 1 birbirites show analogous rare earth element (REE) trends with the serpentinite host‐rock, and the Group 2 birbirites simulate the REE trends of the nearby tectonic granitoid slices. The unorthodox REE trend of Group 2 birbirites is interpreted to have resulted from a mobilization process triggered by the weathering solutions rather than being products of enrichment by the higher temperature hydrothermal activity. Copyright © 2006 John Wiley & Sons, Ltd.     

Assessment of the impact of anthropogenic activities on the groundwater hydrology and chemistry in Tarsus coastal plain (Mersin,SE Turkey) using fuzzy clustering,multivariate statistics and GIS techniques

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Highlights? Four distinct groundwater classes resulted from the fuzzy c-means clustering method. ? Both geogenic and anthropogenic processes affect the groundwater quality in the area. ? Salinization in the area is due to seawater intrusion and dissolution of evaporites. ? Near the coastal zone, the groundwater level is lowered 2–5 m below the sea level. ? Ancient subsurface hydrological features act as conduits for groundwater flow.     

Contents of Volume 29

Volume Contents

Contents of Volume 29     

The sources of metal contents in the shelf sediments from the Marmara Sea, Turkey

The shelf area is the largest morphological unit of the Marmara Sea and is subjected to increasing population, urbanization, and industrial activities. Metal contents (Al, Fe, Mn, Cu, Pb, Zn, Ni, Cr, Co and Hg) of the surface sediments from the shelf areas of the Marmara Sea generally do not indicate shelf-wide pollution. The variability of the metal contents of the shelf sediments is mainly governed by the geochemical differences in the northern and southern hinterlands. Northern shelf sediments contain lower values compared to those of the southern shelf, where higher Ni, Cr, Pb, Cu and Zn are derived from the rock formations and mineralized zones. However, besides from the natural high background in the southern shelf, some anthropogenic influences are evident from EF values of Pb, Zn and Cu, and also from their high mobility in the semi-isolated bay sediments. Anthropogenic influences are found to be limited at the confluence of Istanbul Strait in the northern shelf. However, suspended sediments along the shallow parts of the northern shelf were found to be enriched in Pb and Hg and to a lesser degree in Zn, reflecting anthropogenic inputs from Istanbul Metropolitan and possibly from the Black Sea via the Istanbul Strait.     

Water absorption process effect on strength of Ayazini tuff,such as the uniaxial compressive strength (UCS), flexural strength and freeze and thaw effect

Tuffs have been used as a construction material possibly since ancient times. In Afyonkarahisar, Turkey, there are numerous buildings constructed by tuff. Tuff has been a local construction material, during the Roman, Seljuk and Ottoman periods. Even though tuffs have relatively low durability and low strength values compared to marble, etc., they have survived with no major deterioration failures on many historical buildings. It has also been preferred because of its high porous texture, lightweight and easy shaping and process properties in the building sector. Naturally, it would be easily affected by water and humidity because of its porous structure. However, having this kind of structure leads to poor durability properties due to keeping water in it. The main objective of this study was to evaluate the physical and mechanical properties of the tuff quarried from the region and possible water effect, which may lead to degradation of its strength and durability of the material, thereby shortening the life span of the building structure used. Samples, which were tested after exposing to water and the freeze and thaw effects, were measured at a certain time. In this study, uniaxial compressive strength and flexural strength tests were conducted on test samples. The test results indicate that water may deteriorate the tuff’s strength properties and durability of the materials in due time.